Group 2 Flashcards

1
Q

What is the trend in melting points in group 2

A

Decreases

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2
Q

Why does melting point decrease as you go down the group

A

Delocalised electrons further away from nucleus
Strength of metallic bonds decrease
So it’s easier to break them

Mg is built different

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3
Q

What is the trend in solubility with hydroxides

A

It increases

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4
Q

What is the use of Mg(OH)2

A

It is an antacid (indigestion tablets)

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5
Q

What do we use magnesium hydroxide instead of barium hydroxide in antacids

A

Magnesium hydroxide is sparingly soluble, therefore it won’t affect the ph of the stomach, but barium hydroxide would

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6
Q

What is the trend of solubilities in group two with sulfates

A

It decrease

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7
Q

What is the barium sulfate used for

A

Barium meal is used in X-Rays so we can see the digestive tract properly. Barium is a large atom so it can absorb the x-rays

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8
Q

Barium sulfate is toxic, so why do we use it in X-Rays

A

Barium sulfate is insoluble, so it will pass through and it won’t be absorbed by the body

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9
Q

What is the use of calcium hydroxide

A

It use as slaked lime which neutralises the acidic soils. It is cheap to use

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10
Q

Write a general reaction for group two metals and steam

A

M + H20(g) -> M0 +H2

M being group 2 metal

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11
Q

Write a general equation for the reaction with group two and water

A

M + H20(l) -> M(OH)2 + H2

M being a group 2 metal

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12
Q

What is the full electron configuration of Calcium

A

1s2, 2s2, 2p6, 3s2, 4s2, 3p6

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13
Q

State and explain the trend in the first ionisation energies of the elements in Group 2 from magnesium to barium.

Exam question

A
  1. decreases

why?
1. shielding increases, as does atomic radius this means that less energy is required to remove electrons

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14
Q

What is another use of barium that’s not in imaging

A

Barium chloride can be a test for sulfates

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15
Q

How can you test for sulfates

A

Add HCL and add barium chloride

If positive a white ppt will form

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16
Q

What is a positive result for sulfates

A

A white precipitate

17
Q

Why do we had HCL then barium chloride

A

To remove any carbonates which could give us a false positive

18
Q

What is the trend reactivity in group 2

A

It increases

19
Q

Solutions of barium hydroxide are used in the titration of weak acids.

State why magnesium hydroxide solution could not be used for this purpose.

Exam question

A

Magnesium hydroxide is insoluble

20
Q

Give the formula of a Group 2 metal hydroxide used in agriculture.

Exam question

A

Ca(OH)2

21
Q

Give the formula of the least soluble hydroxide of the Group 2 metals from Mg to Ba

Exam question

A

Mg(OH)2

22
Q

Explain why calcium has a higher melting point than strontium.

A

In calcium delocalised electrons closer to positive nucleus

Or cations are smaller

For mark 2

Ça has a stronger attraction from the positive metal ions to the delocalised electrons

23
Q

Acidified barium chloride solution is used as a reagent to test for sulfate ions.

State why sulfuric acid should not be used to acidify the barium chloride.

Exam question

A

Contains sulfate ions

Or

Will form a white precipitate