atomic structure Flashcards

1
Q

what are subatomic particles

A

A large number of subatomic particles have been discovered but among them only
electron, proton and neutron are of great importance and hence, these three are called
fundamental particles

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2
Q

discovery of electron

A
. Cathode rays were a stream of
fast moving negatively charged particles, called electrons.
The specific charge is the
ratio of charge to mass of an electron, i.e. e/m ratio of electron was found to be
same for all gases.
. Its value is=1.7x10^11 c/kg
mass of electron=9.1x10^-31
 charge on electron=1.6x10^-27
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3
Q

discovery of proton

A

These rays consist of positively
charged particles, called protons
Unlike cathode rays, their e/m value depends upon
the nature of gas taken in the tube. The e/m value is maximum for hydrogen gas.

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4
Q

neutron

A

These are the heaviest
particles of the atom.
mass of neutron =1.6x10^-27 kg
charge on neutron=0

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5
Q

Different Types of Atomic Species

A
  1. Isotopes Isotopes are the species with same atomic number but different mass
    numbers.
    2.Isobars Isobars are the species with same mass number but different atomic
    numbers
    3.Isotones Isotones are the species having same number of neutrons.
    4.Isodiaphers Isodiaphers are the species with same
    isotopic number
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6
Q

isotopic number

A

Isotopic number = mass number − 2 × atomic number

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7
Q

Thompson model of atom

A

Thomson model of an atom proposed that an atom is a sphere
of positive charges uniformly distributed, with the electrons
scattered as points throughout the sphere. This was also
known as plum pudding model.

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8
Q

limitation of Thompson model of atom

A

Thomson’s model was able to explain the overall neutrality of
the atom, but it could not satisfactorily explain the results of
scattering

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9
Q

Rutherford model of atom

A

Rutherford bombarded a thin foil of gold with high speed
positively chargedα-particles and made the following
observations and conclusions :
● Most of theα-particles passed through the foil undeflected, it
means that most of the space in atom is empty.
● Some of them were deflected, but only at small angles. This
shows that there is something positively charged at the centre.
● A very few α-particles were deflected by nearly 180°, it
means that the positively charged solid thing (called
nucleus) is very small.
● The electrons present in empty space, around the nucleus,
revolve around with a very high speed.m

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10
Q

limitation of bohrs model

A

Rutherford’s model cannot explain the stability of an atom.
When a charge is subjected to acceleration around an
opposite charge, it emits radiation continuously

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11
Q

electromagnetic spectrum

A

comic rays< x-rays < ultraviolet< visible spectrum

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12
Q

measurements

A
1pm=10^-12=m 
1Å=10^-10m 
1nm=10^-9m
1μm=10^-6m
1mm=10^-3m
1cm=10^-2m
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13
Q

frequency

A
no of waves passed from a particular spot in 1 second
v=1/t, c=speed of light
c=λx1/t=c=λxV, 
  v=c/λ
v=c x wave number
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14
Q

wave number

A

no of waves present in 1cm
wave number=1/λ
=v/c

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15
Q

planks theory

A
E=hv
h=6.626 x 10^-34 j.sec 
h=E/v
E=nhv
n=no. of quanta
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16
Q

photo electric effect

A

v= √(2hc/m)(1/λ-1/λo)

λo=max wavelength

17
Q

work function

A

=hc/λo
=hVo
Vo=c/λo

18
Q

dual nature of matter

A
λ=h/mc
λ=de-broglie wavelength 
λ=H/MV
λ=h/p
p=momentum
19
Q

relation between KE and de-broglie wavelength

A

λ=h/ √2KExM

20
Q

line spectrum of hydrogen

A

no of emmision lines=n(n-1)/2
wave no.=1/ λ=Rh(1/n^2-1/n^2)z^2
rydberg const=109677
=1.09 x 10^5

21
Q

energy of electron in nth energy level

A

Enth= -2.18x10^-18z^2/n^2 J/ATOM

22
Q

radius of an energy level

A

Rn=52.9n^2/Z pm

23
Q

velocity of a moving electron is different energy level

A

Vnth=2.16x10^6z/n m/sec

24
Q

angluar momentum of a electron

A

mvr=nh/2π