Chp 7 Quantum Statistics Flashcards
Grandpartition function
i.e. gibbs sum
$\mathscr{Z} = \sum_s e^{-[E(s)-\mu N(s)}/kT$
P(s)
$\frac{1}{\mathscr{Z}}e^{-[E(s) -\mu N(s)}/kT$
Thing to remmeber when summing over states
include N = 0 state so the first term is 1
Quantum statistics
Most NB application of Gibbs factors
the study of dense systems in which 2+ identital particles have a reasonable chance of wanting to occupy the same single particle state
Which formula breaks down from chap 6 and why
For system of N indistinguishable noninteracting particles
$$Z=\frac{1}{N!}Z_1^N$$
breaks down
This only works if the particles are always in DIFFERENT states.
chp 7 we focus on dense sys where can be in same state
Bosons
Particles that CAN share a state with another of the same species
Photons
integer spins (1 2 3, in units of $h/2\pi$)
Fermions
Cannot share state with another of same species
Protons neutrons
Due to Pauli Excl princ
Half integer spins (1/2 3/2)
When does it not matter if particles are femions or bosons
# available single particle states >> # particles \$\$Z_1 \ >> \ N\$\$
The average distance vbetween aprticles must be much greater than the avg de Broglie wavelength
What does the the condition on particles being bosons or fermions mattering hinge on
Condiiton dep on density of sys
temp
mass of the particels (through $v_Q$)
Which kinds of systems vioalte the condition and become liek quantum gases
Very dense (neutron star)
Very cold (liq helium)
Composed of very light paticles (e- is a metal or photons in hot oven)
Phonons (quantised units of vibrational energy in a solid)