Polymers Flashcards

1
Q

What types of reactions are condensation polymers formed in? [3]:

A
  • Dicarboxylic acids + diols
  • Dicarboxylic acids + diamines
  • Amino acids
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2
Q

What are the main types of condensation polymers?

[3]:

A
  • Polypeptides
  • Polyamides
  • Polyesters
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3
Q

Condensation Polymerisation [2]:

A
  • 2 different monomers with at least 2 functional groups react together.
  • A link is made and water is eliminated
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4
Q

What does the link in condensation polymerisation determine?

A

The polymer produced

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5
Q

When are amide links formed?

A

When dicarboxyilc acids + diamines

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6
Q

What is kevlar and what are its uses? [4]:

A
  • It’s a polyamide
  • used in bulletproof vests
  • Car tires
  • Some sports equipment
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7
Q

Why is kevlar used for its uses lol?

A

it is light weight but strong

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8
Q

What is kevlar formed from? [2]:

A
  • Benzene-1,4-dicarboxylic acid and

- 1,4-diaminobenzene

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9
Q

What is Nylon 6,6?

A

A Polyamide

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10
Q

What is Nylon 6,6 used for? [4]:

A
  • Ropes
  • Carpets
  • Clothing
  • Parachute fabric
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11
Q

What is nylon 6,6 made from? [2]:

A
  • hexandioc acid

- 1,6 diaminohexane

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12
Q

How are Polyesters formed?

A

dicarboxilic acid + diols

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13
Q

How are ester links formed?

A

When dicarboxylic acids react with diols

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14
Q

What is terylene?

A

It is a Polyester also known as PET

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15
Q

What are the uses of terylene? [3]:

A
  • Plastic bottles
  • Sheeting
  • Clothes
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16
Q

What is terylene made from? [2]:

A

benzene-1,4-dicarboxylic acid + ethane-1,2-diol

17
Q

How do you determine the monomer unit from a polymer? [2]:

A
  • Break the bond in between ester/ amide link

- Then add H and OH to each of the monomer units

18
Q

What monomers do a polyester produce? [2]:

A
  • A dicarboxylic acid

- A diol

19
Q

What monomers do a polyamide produce?

A
  • Dicarboxylic acid

- Diamide

20
Q

Addition Polymer [definition]:

A

A type of polymer formed by joining small alkenes (monomers) together

21
Q

Polarity in condensation polymers [3]:

A
  • They have polar c-o and c-n bonds
  • Makes them more rigid n stronger than addition polymers
  • Hydrogen bonds, dipole-dipole n vanderwaals forces also exist between polymer chains, making ‘em stronger
22
Q

Addition polymer examples [2]:

A
  • Poly(ethene)

- Poly alkenes in general

23
Q

What do addition polymers not do?

A

Biodegrade in landfills

24
Q

Polyalkenes are…[3]:

A
  • Saturated molecules
  • Normally non-polar so unreactive
  • Good when used in foods cus unreactive
25
Q

What are landfills useful for? [2]:

A

Disposing of plastics that are…

  • too difficult to separate
  • do not contain enough plastic to extract for profit
26
Q

Landfill disadvantages [3]:

A
  • not very sustainable
  • large amount of land needed
  • visual pollution
27
Q

Incineration [2]:

A
  • Burning plastics can release toxic fumes

- PVC produce HCl when burned

28
Q

How is HCl neutralised after incineration? [2]:

A
  • Flue gas scrubbers

- They work by firing a base at the flue gases

29
Q

What is an example of a plastic that can be remoulded?

A

poly(propene)

30
Q

Advantages of recycling plastics [4]:

A

+ It is cheaper than making from scratch
+ Less CO2 produced
+ Reduces landfill reliance
+ Preserves crude oil

31
Q

disadvantages of recycling plastics [3]:

A
  • Plastics can be contaminated
  • Difficult to remake original plastic from recycled material
  • Sorting n processing plastics expensive compared to incineration