1.1 Atomic Structure Flashcards

(41 cards)

1
Q

All elements are made up of…

A

Atoms

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2
Q

3 types of sub-atomic particle and their charges.

A

Protons +1
Electrons -1
Neutrons 0

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3
Q

Most of the mass of an atom is concentrated in the….

A

Nucleus

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4
Q

Mass number

A

The total number of protons and neutrons in the nucleus of an atom.

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5
Q

Atomic (proton) number

A

The number of protons in the nucleus of an atoms.

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6
Q

All atoms of the same element have the same number of….

A

protons

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7
Q

Atoms form ions by….

A

Gaining or losing electrons.

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8
Q

What is an isotope?

A

Atoms with the same number of proton but a different number of neutrons.

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9
Q

What is Dalton’s model

A

Atoms are solid spheres and different spheres make up different elements

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10
Q

What is Thomson’s model?

A

Atoms were a large positively charged ‘pudding’ with electrons stuck on them.

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11
Q

What is Rutherford’s model?

A

A tiny positively charged nucleus surrounded by a cloud of negative electrons. Most of the atom is empty space.

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12
Q

What is Bohr’s model?

A

Electrons exist in fixed orbits or shells.
Each shell has a fixed energy.
When an electron moves between shell radiation is absorbed or emitted.
The radiation will have a fixed frequency.

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13
Q

What is Ar

A

Relative atomic mass - the average mass of an element on a scale where carbon 12 is exactly 12

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14
Q

What is relative isotopic mass

A

The mass of an atom of an isotope on a scale where carbon 12 is exactly 12

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15
Q

What is Mr

A

Relative molecular mass - the average mass of a molecule on a scale where carbon 12 is exactly 12.

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16
Q

How do you find the Mr of a molecule.

A

Add up all the Ar values for all the elements in the molecule

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17
Q

Calculate the Mr of C2H6O

A

(2x12.0) + (6x1.0) + (1x16.0) = 46.0

18
Q

What is relative formula mass

A

The average mass of a formula unit on a scale where an atom of carbon 12 is exactly 12

19
Q

Calculate the relative formula mass od CaF2

A

40.1 + (2x19.0) = 78.1

20
Q

Describe how a mass spectrometer works.

A

Ionisation - Sample is dissolved in a polar solvent and pushed through a nozzel at high pressure with a high voltage applied causing the particles to lose an electron.
Acceleration - Positive ions are accelerated by an electric field. Ions with a lower masses are accelerated more than heavier ones
Ion drift - Ions enter a region with non electric field. Those which are heavier drift slower
Detection - Ions hit a detector plate where they gain an electron producing a current. The strength of this current shows relative abundance.

21
Q

The further a shell is from the nucleus…

A

the higher it energy level

22
Q

Shells are divided up into

23
Q

What are the names of each sub-shell

24
Q

What are orbitals

A

Regions where there is a 95% chance of finding an electron. Each orbital can contain up to 2 electrons.

25
How many electrons can the s level hold?
2
26
How many electrons can the p level hold?
6
27
How many electrons can the d level hold?
10
28
How many electrons can the f level hold?
14
29
What sub-shells does the 1st shell contain?
s
30
What sub-shells does the 2nd shell contain?
s,p
31
What sub-shells does the 3rd shell contain?
s,p,d
32
What sub-shells does the 4th shell contain?
s,p,d,f
33
Electron configuration rules
1) electrons fill up the lowest energy level first 2) electrons fill orbitals in a sub-shell singly before they start sharing 3) for ions in the s and p blocks add or remove electrons from the highest occupied energy level
34
What do copper and chromium do?
They donate one of their 4s electrons to the 3d sub shell
35
Full configuration of copper
1s2 2s2 2p6 3s2 3p6 3d10 4s1
36
What is the s block
Group 1 and 2 elements
37
What is the p block
group 5,6 and 7 elements
38
What is the d block
Transition metals
39
What is first ionisation energy
The energy required to remove 1 electron from each atom in one mole of gaseous atoms to from 1 mole of gaseous 1+ ions
40
What does it mean if there is a high first ionisation energy
There is high attraction between the electron and the nucleus.
41
Factor affect first ionisation energy.
Nuclear charge - more protons increase that charge in the nucleus which increases attraction Distance from nucleus - Attraction decreases as distance increases Shielding - As the number of electrons between the outermost electron and nucleus increases the attraction decreases