Chemical Changes Flashcards

1
Q

What happens to a substance in terms of oxygen during oxidation and reduction

A

Oxidation a substance gains oxygen
magnesium + oxygen —> magnesium oxide
-magnesium gains oxygen so its oxidised

Reduction a substance looses oxygen
lead oxide + carbon —> lead + carbon dioxide
-lead looses oxygen so is reduced

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2
Q

What are the elements above carbon in the reactivity series starting from most reactive

A

potassium, sodium, calcium, magnesium, aluminium

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3
Q

what are the elements below carbon in the reactivity series

A

zinc, iron, tin, lead, hydrogen, copper, silver, gold, platiunum

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4
Q

what is a displacement reaction

-example

A

-when a more reactive metal displaces a less reactive metal from a solution of its salts
magnesium + copper sulfate —> copper + magnesium sulfate

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5
Q

how can elements less reactive than carbon be extracted from metal oxides (ores)

A

heating with carbon
iron oxide + carbon —> iron + carbon dioxide
-iron looses oxygen so is reduced
-carbon gain oxygen so is oxidised

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6
Q

describe oxidation and reduction in terms of electrons

-example with magnesium and oxygen

A

oxidation is loss of electrons
2Mg —> 2Mg2+ + 4e-
reduction is gain of electrons
O2 + 4e- —> 202-

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7
Q

what pH numbers make a solution

  • neutral
  • acidi
  • alkaline
A

pH 7 is neutral (green)
pH less than 7 are acidic (red)
pH more than 7 are alkaline (purple)

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8
Q

what does an acid produce when it is neutralised with a base

A

acid + metal hydroxide —> salt + water

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9
Q

what ions do acids and alkalis contain and how are they neutralised

A

Acids contain hydrogen ions H+
Alkalis contain hydroxide ions OH-
H+ + OH- —> H20
neutralised by reacting them together as they have a pH of 7 and produce water

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10
Q

What is produced when an acid reacts with metal oxides and metal carbonates

A

acid + metal oxide —> salt + water

acid + metal carbonate —> salt + water + carbon dioxide

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11
Q

How is a salt produced and what ones are produced for hydrochloric acid, nitric acid and sulphuric acid

A

a salt is produced when the hydrogen in the acid is replaced by the metal ion
hydrochloric acid produces chloride salts
nitric acid produces nitrate salts
sulphuric acid produces sulphate salts

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12
Q

what makes an acid strong or weak

A

strong acid are completely ionised (split up into ions) in water
Hydrochloric acid
HCL + aq —> H+ Cl-
weak acids only partially ionise in water
Ethanoic acid
CH3COOH + aq —> CH3COO- + H+

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13
Q

why do ionic compounds only conduct electricity when in solution or molten

A

the ions are free to move and carry their charge

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14
Q

what happens to the positively charged metal ion during electrolysis
what happens to the negatively charged ion during electrolysis

A

the positive metal ions move to the negative cathode and gain electrons to form pure metal
Pb2+ + 2e- —> Pb
the negative ions move to the positive anode and loose electrons to from a molecules (bromine) and release gas
2Br- —> Br2 + 2e-

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15
Q

where to oxidation and reduction occur during electrolysis

-half equations for copper chloride

A

oxidation occurs at the positive electrode where the negatively charged ions loose electrons
2Cl- —> CL2 + 2e-
reduction occurs at the negative electrode where positively charged ions gain electrons
Cu2+ + 2e- —> Cu

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16
Q

Why is cryolite added to aluminium oxide to form aluminum

A

cryolite lowers the melting point of the aluminium oxide meaning less energy is needed making it more cost effective

17
Q

what forms at the positive electrode during industrial electrolysis of aluminium oxide
-ionic equation

A

oxygen gas forms and reacts with carbon forming carbon dioxide which wears away the positive electrode so has to be replaced frequently
202- —> O2 + 4e-

18
Q

what forms at the negative electrode (electrolysis of aluminium)
- ionic equation

A

Aluminium

Al3+ + 3e- —> Al

19
Q

during electrolysis of aqueous solutions what is formed at the negative electrode

A

hydrogen is the metal is more reactive than hydrogen

the metal if the metal is less reactive than hydrogen

20
Q

during electrolysis of aqueous solutions what is formed at the positive electrode

A

oxygen is produced unless the solution contains halide ions

if halide ions are present then the halogen is produced