AAMC Practice Flashcards

1
Q

pH equation (given acid concentration)

A

ph = -log[H+]

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2
Q

solving log equations

A
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3
Q

determine molecular geometry: basic steps

A

determine the steric number

determine the geometry based on the number of bonds and lone pairs

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4
Q

steric number

A

the number of “electron dense areas” around a central atom

lone pairs or bonds (whether single, double, or triple)

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5
Q

molecular geometry: steric # 2, no lone pairs

A

linear

180° bond angle

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6
Q

molecular geometry: steric # 3, no lone pairs

A

trigonal planar

120° bond angle

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7
Q

molecular geometry: steric # 3, 1 lone pair

A

bent

<180° bond angle

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8
Q

molecular geometry: steric # 4, no lone pairs

A

tetrahedral

109.5° bond angle

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9
Q

molecular geometry: steric # 4, 1 lone pair

A

trigonal pyramidal

109.5° bond angle

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10
Q

molecular geometry: steric # 4, 2 lone pairs

A

bent

<109.5° bond angle

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11
Q

Boiling point

A

temperature at which the vapour pressure of the liquid equals the surface pressure

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12
Q

Red litmus paper

A

basic substance → turns blue

acidic or neutral substance → stays red

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13
Q

which ions are often responsible for colour in solution

A

complex ions containing transition metals (d block elements) are usually coloured, whereas the similar ions from non-transition metals aren’t

electrons in the lower energy d orbitals absorb visible light to move to the higher energy d orbitals

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14
Q

“carboxyl group”

A

the functional group COOH

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15
Q

carboxylic acid

A

a compound with a carboxyl group attached

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16
Q

hydrolysis

(to be hydrolyzed)

A

add water to break bonds

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17
Q

dehydration synthesis

A

bonds are formed as water is released

18
Q

Triglyceride

A
19
Q

ester

A
20
Q

how are esters formed

A

from a carboxylic and and alcohol

an ester bond is formed and a water molecule is released

21
Q

High retention factor (Rf) value = ____________

A

further distance travelled

22
Q

retention factor (Rf) formula

A
23
Q

silica gel is ________ (polar/nonpolar)

A

polar

(other polar substances ‘stick’ to it)

24
Q

mmol to mol conversion

A

1 mole = 1000 mol

25
Q

Equilibrium constant (Keq) equation

A
26
Q

equation for amount of heat gained or lost from a system

A

q = mc∆t

27
Q

isopropyl group

A
28
Q

tert butyl group

A
29
Q

atomic radii trends on periodic table

A

bottom left = largest

top right = smallest

30
Q

of protons

A

determined by atomic number

31
Q

of electrons

A

= atomic number

(same as # of protons)

32
Q

of neutrons

A

= atomic mass - # of protons

(atomic mass = protons + neutrons)

33
Q

ionic bonds usually occur between… (2)

A

metals and nonmetals

usually between elements on the far left and far right of the periodic table

34
Q

wedge and dash to chair conformation

wedge = _______ (up/down)

dash = _______ (up/down)

A

wedge = UP

dash = DOWN

35
Q

Metals are on the _____ (left/right) of the periodic table
Nonmetals are on the _____ (left/right) of the periodic table

A

Metals are on the LEFT of the periodic table
Nonmetals are on the RIGHT of the periodic table

36
Q

electronegativity differences and bond type

A
37
Q

Electronegativity trends in periodic table

A
38
Q

Graphite is composed of which element?

A

carbon

39
Q

negative delta S meaning

A

entropy decreases

40
Q

positive delta S meaning

A

entropy increases

41
Q

Gibb’s Free energy equation

A
42
Q

2 characteristics of ideal gases

A

molecules have no intermolecular forces and occupy no volume