basic concepts of organic chem Flashcards

1
Q

What does nomenclature mean

A

The system used for naming organic compounds

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2
Q

Define empirical formula

A

The simplest whole number ratio of atoms in a molecule

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3
Q

Define molecular formula

A

The actual number of atoms of each element in a molecule

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4
Q

Define the displayed formula

A

Shows every atom and every bond in a molecule

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5
Q

Define structural formula

A

Shows the arrangement of atoms in a molecule without showing every bond

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6
Q

Define skeletal formula

A

Shows the bonds of the carbon skeleton only, with any functional groups. The hydrogen and carbon atoms aren’t shown.

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7
Q

Define homologous series

A

A homologous series is a bunch of organic compounds that have the same functional group and general formula

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8
Q

Define a functional group

A

A group of atoms responsible for characteristic reactions of a compound

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9
Q

What is an aliphatic hydrocarbon

A

Hydrocarbon with carbon atoms joined together in a straight line or branched chain, containing non-aromatic rings

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10
Q

What is an alicyclic hydrocarbon

A

Hydrocarbons arranged in non-aromatic rings with or without side chains

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11
Q

What is an aromatic hydrocarbon

A

A hydrocarbon that contains at least one benzene ring

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12
Q

What is the suffix for:

  1. No double bonds
  2. At least 1 double bond
  3. An alcohol
  4. An aldehyde
  5. A ketone
  6. A carboxylic acid
A
  1. -ane
  2. -ene
  3. -ol
  4. -al
  5. -one
  6. -oic acid
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13
Q

What is the prefix for a CH3 group

A

methyl-

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14
Q

What is the prefix for a C2H5 group

A

ethyl-

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15
Q

What is the general formula of alkanes

A

CnH2n+2

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16
Q

What is the general formula for alkenes

A

CnH2n

17
Q

What is the general formula of alcohol

A

CnH2n+1OH

18
Q

Define saturated

A

Organic compounds which only contain single bonds

19
Q

Define unsaturated

A

Organic compounds that contain at least one carbon-carbon double covalent bond

20
Q

Define structural isomerism

A

When molecules have the same molecular formula but the different structural formula

21
Q

What are the 3 ways in which structural isomers can be formed

A
  1. Alkyl groups can be in different places
  2. Functional groups can be bonded to different parts
  3. There can be different functional groups
22
Q

Define stereoisomers

A

Organic compounds with the same molecular formula but different arrangements of atoms in space

23
Q

What is E-Z isomerism and how are E and Z isomers decided?

A

E-Z isomerism is caused by the limited rotation about C=C double bonds

If the two substituents with the highest molecular mass are on the same side of the double bond, it is the Z isomer

If they are on different sides it is the E isomer

24
Q

What is Cis-Trans isomerism

A

A special type of E/Z isomerism where two substituents on each carbon atom are the same

25
Q

What is homolytic fission

A

It happens when each bonding atom receives 1 electron from the bonded pair forming 2 radicals

26
Q

What is heterolytic fission

A

When 1 bonding atom receives both electrons from the bonded pair to form ions

27
Q

Define radicals

A

Particles that have an unpaired electron which makes them very reactive