topic 1/11 Flashcards

1
Q

why do elements/compounds in a mixture retain their individual properties?

A

they are not chemically bonded together

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2
Q

explain the difference between a homogeneous and a heterogeneous mixture

A

Heterogeneous mixtures have visually distinguishable components, while homogeneous mixtures appear uniform throughout.

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3
Q

define a mole

A

a fixed number of particles referring to the amount, n, of substance

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4
Q

units for molar mass

A

g/mol

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5
Q

define molar mass

A

the ratio between the mass and the amount of substance (measured in moles)

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6
Q

difference between empirical and molecular formulae of compounds

A

simplest ratio vs actual number of atoms present in a molecule

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7
Q

what are standard temperature and pressure?

A

0 degrees celsius (273K) and 100kPa

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8
Q

what is true at standard temperature and pressure?

A

the molar volume of an ideal gas is 22.7 dm3/mol

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9
Q

give the equation for molar volume, as well as its usual value

A

volume (dm3)/ moles. 22.7

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10
Q

give the equation for the molar volume of an ideal gas and its usual value

A

22.7= vol/mol

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11
Q

what does 1 mol of gas contain?

A

6.02x10^23 atoms or molecules of the gas

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12
Q

state Avogadro’s law

A

equal volumes of any gas measured at the same temperature and pressure contain the same number of molecules

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13
Q

law for volume vs pressure

A

p=1/v
p1v1=p2v2

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14
Q

law for volume vs temperature

A

v is proportional to t (in K)
v1/t1=v2/t2

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15
Q

law for pressure vs temperature

A

p is proportional to t
p1/t1=p2/t2

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16
Q

combined gas law

A

p1v1/t1= p2v2/t2

17
Q

ideal gas equation and units

A

pV=nRT
Pa for pressure
m3 for volume
K for temperature
R is the gas constant

18
Q

describe the assumptions behind the kinetic theory of gases (5)

A
  • The gas molecules are moving very fast and randomly
  • The molecules hardly have any volume
  • The gas molecules do not attract or repel each other (no intermolecular forces)
  • No kinetic energy is lost when the gas molecules collide with each other (elastic collisions)
  • The temperature of the gas is directly proportional to the average kinetic energy of the molecules
19
Q

gases that follow the kinetic theory of gases are called

A

ideal gases

20
Q

why do gases deviate from ideal behaviour at higher temperatures and pressures?

A

Assumptions about volume:
The kinetic theory assumes that the volume the actual gas molecules themselves take up is tiny compared to the volume the gas occupies in a container and can be ignored
This is broadly true for gases at normal conditions, but becomes increasingly inaccurate at low temperatures and high pressures
At these conditions the gas molecules are very close together, so the fraction of space taken up by the molecules is substantial compared to the total volume

Assumptions about attractive forces:
Another assumption about gases is that when gas molecules are far apart there is very little interaction between the molecules
As the gas molecules become closer to each other intermolecular forces cause attraction between molecules
This reduces the number of collisions with the walls of the container
The pressure is less than expected by the ideal gas equation

21
Q

what is a standard solution?

A

one of a known concentration

22
Q

what is the molar concentration of a solution determined by?

A

the amount of solute (moles) and the volume of the solution

23
Q

define qualitative data

A

includes all non-numerical information obtained from observations, NOT from measurement

24
Q

define quantitative data

A

are obtained from measurements, and are always associated with random errors/uncertainties, determined by the apparatus and by human limitations such as reaction times.

25
Q

define accuracy

A

the closeness of the agreement between the result of a measurement compared with the true/literature value

26
Q

define precision

A

precision is the closeness of the agreement between different test measurements of the same quantity obtained by applying the same experimental procedure under the same conditions.

27
Q

formula for percentage uncertainty

A

absolute uncertainty/measured. value x100

28
Q

describe a random error

A

due to uncertainties associated with the apparatus used to make measurements/ by human limitations (ie reaction times) . cannot be eliminated

29
Q

describe a systematic error

A

due to faults in procedure or experimental design and cause a deviation in a particular direction. can be corrected/reduced

30
Q

when quantities with uncertainties are added or subtracted,

A

the absolute uncertainties are added

31
Q

when multiplying or dividing quantities with uncertainties,

A

percentage uncertainties should be added

32
Q

what is absolute uncertainty?

A

the margin of uncertainty associated with the result from a given measurement, ΔA

33
Q

what is relative uncertainty?

A

the ratio comparing the size of the absolute uncertainty to the size of the measured experimental result (A)

34
Q

give the equation for relative uncertainty

A

absolute uncertainty/measured experimental result

35
Q

ascorbic acid is C6H8O6; how many moles of carbon are there in 1 mol of ascorbic acid?

A

6

36
Q

relationship between volume and moles

A

v1/n1=v2/n2

37
Q

relationship between concentration and volume

A

C1V1=C2V2