Coaching: Day 1 Concepts Flashcards

1
Q

Iodine vapor forms iodine crystals when it touches a cold surface. What is the reverse of the process being described?

A

sublimation

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2
Q

The person’s sense of smell and taste depend on specific biochemic receptors present in a person’s nose and mouth. In 2004, a Nobel Prize was given to the researchers who established this fact and identified the type of organic compound associated with the sense of smell and taste. The chemical identified was;

A

rhodopsin

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3
Q

The distance of the Earth to the most remote normal galaxy is calculated to be:

A

2x10^22 m

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4
Q

Determine the oxidation number of Chromium in CrF6 3+.

A

3

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5
Q

Fatty acid such as lauric acid and palmitic acid and oleic acid are long unbranched carboxylic acids consisting of 12 to 20 carbon atoms. Which type of fatty acid should people avoid ingesting, saturated or unsaturated and why?

A

Saturated, because the risk of cardiovascular disease is increased

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6
Q

A voltaic cell is represented by the following equation:
Fe(s) + Zn^2+ (aq) → Fe^2+(aq) + Zn(s)
Which electrode is the anode and which electrode is the cathode?

A

Anode = Fe and Cathode = Zn

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7
Q

What other particle is formed in the fusion of two protons to yield deuterium?

A

positron

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8
Q

Which isotope is produced when Polonium-216 decays by emitting an alpha particle followed by two beta particles?

A

Polonium-212

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9
Q

Process of breaking down a large isotope into smaller isotopes.

A

nuclear fission

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10
Q

In a dehydration reaction where water is lost, an organic compound C3H8O reacts with concentrated phosphoric acid and a product is formed. This product rapidly decolorizes a solution of bromine in tetrachloromethane. What is this product?

A

Propene

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11
Q

An adiabatic process is one in which the system under investigation is thermally isolated so that there is no exchange of heat with the surroundings. Thus, the work done on a closed system in an adiabatic process is _____.

A

Equal to the increase in internal energy of the system

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12
Q

State Le Chatelier’s Principle.

A

Le Chatelier’s principle states that when a stress is placed on a system in equilibrium, the system tends to change in a way that relieves the stress.

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13
Q

The ion that would be isoelectronic with the noble gas xenon is:

A

Iodine

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14
Q

If radon-222 disintegrates to a stable condition by emitting three alpha emissions and two beta emission, determine the stable nucleus formed.

A

210Pb82

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15
Q

These compounds are formed by the reaction of acids with alcohols.

A

Esters

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16
Q

To which subatomic particle does each statement refer to a.) has a positive charge; b.) is found outside of the nucleus; c.) has the smallest mass; d.) has a negative charge?

A

proton, electron, electron, and
electron

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17
Q

What is the Clapeyron Equation?

A

It postulates that if the temperature and pressure are both change in such a way as to keep the chemical potentials of two phases equal to each other, the rates of change are given by the equation.

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18
Q

Which would make more efficient cold compress, ethanol or methanol?

A

Methanol

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19
Q

As a result of the Aykhal Crystal Denotation in 1974 (in the former Soviet Union), cesium-137 was measured (in 1993) in the soil concentration of 2x104 Bq/kg soil. If the background concentration of 137Cs is 0.5 Bq/kg soil, how many years will it take before the concentration of 137Cs reaches background levels? The decay of radionuclide occurs by a first-order reaction. Half-life is 30 years.

A

459 years

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20
Q

Name the major physiologically active substances that comes from: bark of the willow tree, the pituitary gland, the sap of the poppy and the belladenna plant.

A

Salicin, beta-endomorphin, opium, atropine

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21
Q

Draw the condensed and skeletal structures of diethyl ether which is used by most doctors and hospitals as an anesthetic during operations.

A

CH3CH2OCH2CH3 (longest sa choices)

22
Q

The element neon was discovered in 1898 by:

A

Travers and Ramsay

23
Q

Given the following data for Marikina River and Pasig River, determine the best combination of plant and location to conserve the environment.

A

Plant B in Marikina River

24
Q

What is the buckyball?

A

A fullerene

25
Q

If high octane gasoline with density 0.71 is used by a BMW on NLEX to travel to Tarlac 125 mi away and a gas mileage of 19.75 mi/gal estimate the quantity in kg of carbon dioxide produced.

A

52 kg

26
Q

Glutamic acid is used as one of the reagents for a standard to check the BOD test. Determine the theoretical oxygen of 150 ppm of glutamic acid.

A

212 ppm

27
Q

A solution of cation gives a crimson red flame. This flame test is a confirmatory test for:

A

Sr^2+

28
Q

What is the color of nickel chloride?

A

yellow

29
Q

Substances whose solutions change color due to changes in pH.

A

Indicator

30
Q

It is an organic reaction that converts an alcohol into an alkyl chlorine using triphenylphosphine and carbon tetrachloride.

A

Appel reaction

31
Q

It is the major component of lecithin.

A

Phosphatidylcholine

32
Q

Polymer used in bullet proof vest

A

Linear Polyethylene

33
Q

Author of Octet Rule

A

Gilbert Lewis

34
Q

Which of the following indicators is used in EDTA titration?

A

all of these

35
Q

The theory of resonance was developed by __ in order to further explain the bonding structures of molecules or ions not covered by the Lewis Octet rule.

A

Linus Pauling

36
Q

Taurine, a Beta amino acid belongs to the acidic group of:

A

–SO2OH

37
Q

In a standard chemical reaction, rate is governed by the relationship rate=pze-E/RT, where p and z refer to the probability that reacting molecules make a favorable encounter. To increase the probability of reaction, enzymes are employed. Based on the above equation, if E is the activation energy, which is more favorable and why? A lower or higher E?

A

Lower E so that a proton can be donated or stolen for the reactants leading to better catalyst

38
Q

The coexistence curve where the plot of pressure versus temperature along which the two phases coexist was shown by Clausius-Clapeyron. What did Clausius postulate?

A

The Clapeyron equation was simplified by assuming that the vapor obeys the ideal gas law and by neglecting the molar volume of the liquid VL in comparison with the molar volume of the gas VG.

39
Q

What is the significance of colligative property in physical chemistry?

A

It refers to the freezing point depression, boiling point elevation, osmotic pressure and lowering of the vapor pressure by a nonvolatile solute

40
Q

In the collision theory of chemical kinetics, it is suggested that reaction rate is governed by the relationship rate=Pze-E/RT. What can an enzyme do to the activation energy of the reaction E?

A

Enzymes provide an alternative reaction pathway in lowering the energy level of the reaction

41
Q

Identify the organic compounds in the following
equation: CH3CH(OH)CH2CHO → CH3CH=CH + H2O

A

carbonyl aldehyde; cis or trans-isomer

42
Q

In the study of fats and lipids, determine which of the two triglycerides has a higher melting point?
Substance A containing only lauric acid and glycerol, or substance B-containing only stearic acid and glycerol

A

B-containing only stearic acid and glycerol

43
Q

What is the theory in two or three dimensional collision to be applied when playing billiard balls and in order to sink the target ball in the corner pocket?

A

Where two equal masses undergo a glancing elastic collision

44
Q

When a thorium-230 atom undergoes alpha
decay, the products of the reaction are
usually:

A

Radium and an alpha particle

45
Q

When travelling at NLEX at 80mph, a stopped car in front causes you to suddenly skid to stop. What happened to the kinetic energy of the moving car?

A

All of it transferred to the road and surroundings

46
Q

Are reversible processes frictionless? Why?

A

Because when reversed, retraces its forward path and restores the initial state of the system and surroundings

47
Q

What is the Nujol Mull in organic chemical reactions?

A

It is a mass spectrum technique and is obtained by grinding up a solid which is mixed with mineral oil to form a suspension for IR spectroscopy

48
Q

Molecular formula of DNA molecule

A

C15H31N3O13P2

49
Q

Determine the volume in mL of 1mol of pure ethyl alcohol.

A

58 mL

50
Q

Define the relationship between the number of electrons in the valence shell and the
number of covalent
bonds it forms:
1. Carbon
2. Nitrogen
3. Oxygen
4. Hydrogen

A

C = 4 electrons, 4 bonds; N = 5 electrons, 3 bonds; O = 6 electrons, 2 bonds; H = 2 electrons, 2 bonds