Temperature, Heat, and the first law of thermodynamics formulas Flashcards

1
Q

Temperature (constant-volume gas thermometer)

A

T = (273.16K) × lim gas -> 0 (p/p3)

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2
Q

Conversion of Other Temps. from Kelvin temp

A

Celsius Temp = T - 273.15

Farenheit Temp = 9/5 Celsius temp + 32

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3
Q

Thermal expansion (change in L)

A

ΔL = LαΔT

α is the coefficient of linear expansion

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4
Q

Thermal expansion (change in volume)

A

ΔV = VβΔT

β = 3α is the coefficient of volume expansion

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5
Q

Heat conversions (calories, joules. british thermal units)

A

1 cal = 3.968 × 10 ^(-3) Btu = 4.1868 J

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6
Q

relationship of temperature change with heat Q

A

Q = C (Tf - Ti)

C is the heat capacity of the object

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7
Q

Heat of an object when it has mass

A

Q = cm (Tf - Ti)

c is the specific heat of the material
molar specific heat = 6.02 × 10^(23)

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8
Q

Heat transformation

A

Q = Lm

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9
Q

Work Associated with volume Change

A

W = ∫dW = ∫p dV [ from Vi to Vf]

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10
Q

First Law of Thermodynamics

A

ΔE int = Eint,f - Eint,i = Q - W

dEint = dQ -dW

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11
Q

Application of the First Law

A

adiabatic processes:
Q = 0, ΔEint = -W

constant-volume processes:
W = 0, ΔEint = Q

cyclical processes:
ΔEint = 0, Q = W

free expansions:
Q = W = ΔEint = 0

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12
Q

Conduction of Energy (Rate)

A

Pcond = Q/t = kA [(TH - TC)/L]

TH = higher temp
TC = lower temp

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13
Q

Rate of radiation energy

A

Prad = σεAT^4

σ = 5.6704 × 10 ^(-8) W/m^2×K^4
ε is the emissivity of the object’s surface

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14
Q

Stefan-Boltzmann constant

A

σ = 5.6704 × 10 ^(-8) W/m^2×K^4

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15
Q

Rate of radiation energy absor[topm

A

Pabs = σε AT^4(env)

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