Kinetics Flashcards

1
Q

formula for reaction rate

A

The change in concentration/ amount of a reactant or product over time

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2
Q

Give the formula for the rate of reaction

A

Amount of reactant used or product formed/ time

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3
Q

Do particles react every time they collide?

A

No

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4
Q

What conditions allow particles to react and what theory is this called?

A

• They must collide in the right direction, and need to be facing the right way
• Collide with a certain minimum amount of kinetic energy
• Collision theory

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5
Q

What is activation energy

A

The minimum amount of kinetic energy that particles need to react

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6
Q

How does a reaction start?

A

By breaking bonds

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7
Q

How do particles receive extra energy

A

By heating them

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8
Q

Do molecules in a gas all have the same amount of energy?

A

No

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9
Q

What is variation of energy of particles in a gas

A

• Some molecules move slowly, don’t have much kinetic energy
• Most molecules are moving at a moderate speed, their energies are somewhere in the middle
• Some have loads of energy

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10
Q

What is the graph for representing number of moles of gas over different kinetic energies

A

Maxwell-Boltzmann distribution

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11
Q

The area under the maxwell-Boltzmann distribution curve is called what?

A

The total number of molecules

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12
Q

What does the peak of the curve represent?

A

The most probable energy. Emp

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13
Q

Where can the mean average energy of all the molecules be found in the graph

A

To the right of the peak

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14
Q

Why does the curve start at (0,0)

A

Because no molecules have zero energy

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15
Q

Why is there an area called Ea

A

Because some molecules have more than the activation energy, tgeee are the only ones that can react

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16
Q

List the factors that increase the rate of reaction

A

• Increasing temperature
• Increasing concentration
• Increasing pressure
• Catalysts

17
Q

How does increasing the temperature, increase the rate of reaction

A

• More particles have kinetic energy
• And will move faster
• Greater proportion will have the activation energy
•Changes the shape of the maxwell-Boltzmann curve, pushes it further to the right
• Collide more often
• Small increases in temperature can lead to quite large increases in reaction rates

18
Q

Define a catalyst

A

A substance that increases the rate of a reaction by providing an alternative reaction pathway with a lower activation energy. The catalyst is chemically unchanged at the end of the reaction but do take part in the reactions

19
Q

Only work on a single reaction

A

Catalysts

20
Q

How do catalysts save money in the industrial process?

A

Allow you to make the product faster at a lower temperature

21
Q

How can you measure the rate of reaction

A

How fats the reactants are used up or how fats products are formed

22
Q

What three ways are there to measure a reaction rate

A

• Timing how long it takes for a precipitate to form
• Measuring a decrease in mass
• Measuring the volume of gas given off

23
Q

How do you measure the amount of gas given off

A

• Using a gas syringe
• Accurate
• Measure the volume of gas being produced

24
Q

How do you measure a decrease in mass?

A

• Product must be a gas
• Measure formation using a mass balance
• As gas is given off, the reaction mixture decreases
• Done on a fine cupboard
• Accurate

25
Q

Give an example of measuring reaction rates

A

The reaction between sodium thiosulphate and hydrochloride acid

26
Q

What is the purpose of this reaction example?

A

To demonstrate the effect of increasing temperature on reaction rates

27
Q

Give 2examples of dependent/controlled variables in this reaction

A

• The depth of the liquid
• the concentration of solutions

28
Q

What is the effect of increasing the concentration and the pressure of a reaction

A

• Increases rate of reaction
• Particles will be closer to each other
• They’ll collide more often
• Frequent successful collisions means more chances they they will react

29
Q

Explain why an increase in temperature increases the rate at which this gas decomposes

A

• An increase in the number of particles with activation energy
• More successful collisions at a given time