reaction rates Flashcards
reaction to happen
reactions must collide in correct orientation with minimum kinetic energy
rate of reaction
change of conc/ amount of reactant or product per unit of time
rate
amount of reactant used or product made divided by time
boltzmon temp
particles have more ke when heated so a larger proportion of molecules have energy greater than activation energy
curve shifts right and a lower peak
area under curve beyond activation energy increases
Temperature
as temp increases particles move around more and collide more often
faster more collisions and more energetic collisions
small incr in temp
large incr in rate
pressure
pressure increases the rate of reaction increases
particles are closer together and collide more often
more frequent collisions and a higher change of reaction
conc
conc increases the rate of reaction increases
particles are closer together so collide more often
more frequent collisions and a higher chance of reaction
catalysts
make products faster and a lower temperature required for a reaction
heterogeneous catalyst
different phase or state to reactants
increased surface area of heterogeneous so, increases rate of reaction
more particles can react with catalyst at the same time
homogenous
same phase as reactants usually a gas in gas reactants
form intermediate species by reactants combining with catalysts which react to form products
catalyst reform again
why use catalyst
lower the temp needed for a reaction to proceed so less money spent and less co2 produced
change the properties of products
catalyst environmental benefits
lower temp and pressure required so reduce energy and co2 produced
less waste eg instead of producing product via 5 steps 2 steps needed instead
catalytic converters
in cars reduce pollution levels
made from rhodium platinum and palladium alloy
2co+2no 2co2 +N2
how can rate be measured in experiments
how long it takes for precipate to form but its difficult to know when exactly the cross disappears
volume of gas produced using gas syringe over period of time
amount of mass lost
place reaction on balance and measure the mass lost of gas