Organic Synthesis Reactions Flashcards

1
Q

primary amine –> N-substituted amide

A

acyl chloride

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

bromoalkane –> primary amine

A

NH3
reflux

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

alkane –> bromoalkane

A

Br2
UV light

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

alkene –> alkane

A

Ni catalyst
150 degrees and pressure

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

alkene –> dibromoalkane

A

HBr
20 degrees

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

alkene –> dibromoalkane

A

HBr
20 degrees

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

secondary bromoalkane –> secoondary alcohol

A

NaOH
reflux

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

bromoalkane –> primary alcohol

A

NaOH
reflux

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

alkene –> primary alcohol

A

H3PO4 catalyst
steam
300 degrees

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

primary alcohol –> alkene

A

conc. H2SO4
170 degrees and pressure

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

secondary alcohol –> ketone

A

K2Cr2O7
H2SO4
reflux

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

primary alcohol –> aldehyde

A

K2Cr2O7
H2SO4
heat then distil

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

ketone –> cyanohydrin

A

HCN

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

aldehyde –> cyanohydrin

A

HCN

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

aldehyde –> carboxylic acid

A

K2Cr2O7
H2SO4
reflux

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

primary amide –> carboxylic acid

A

H+ heat

17
Q

carboxylic acid –> ester

A

alcohol
H+ catalyst
reflux

18
Q

ester –> carboxylic acid

A

H+
reflux

19
Q

acyl chloride –> ester

A

alcohol

20
Q

benzene –> nitrobenzene
(NITRIFICATION)

A

H2SO4
HNO3
55 degrees

21
Q

sulfonation of benzene

A

fuming H2SO4
40 degrees

22
Q

acylation of benzene

A

RCOCl
AlCl3 catalyst
reflux

23
Q

alkylation of benzene

A

RCl
AlCl3 catalyst
reflux

24
Q

benzene –> chlorobenzene
(CHLORINATION)

A

Cl2
AlCl3 catalyst
warm

25
Q

phenol –> phenylethanoate

A

CH3COCl
20 degrees

26
Q

phenol –> sodium phenoxide

A

NaOH
20 degrees

27
Q

aminobenzene –> benzenediazonium chloride

A

HNO2/HCl
less than 5 degrees

28
Q

benzenediazonium chloride – yellow/orange azo compound

A

phenol
NaOH
less than 5 degrees