chem eqb Flashcards

1
Q

The value of KC is changed by change in temperature because

A

Equilibrium position shift without any substance being added or removed
In a reversible reaction, change in temperature, change the equilibrium position. So KC depend upon temperature.

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2
Q

Which sparingly soluble salt solution will be unsaturated?

A

Ksp > ionic product

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3
Q

A beaker contains a saturated solution of potassium Perchlorate. When potassium chloride (KCl) is added to this solution, some of the potassium Perchlorate is precipitated. It means that

A

KCl is a stronger electrolyte as compared with KClO4
Strong electrolyte (KCl) will suppress the ionization of weak electrolyte (KClO4)

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4
Q

Solubility product of BaCl2 is 4×10-9. Its solubility would be

A

BaCl­2 ⇌ Ba+2 + 2Cl–
Ksp = [Ba+2][Cl–]2 = (S)(2S)2 = 4S3
4 × 10-9 = 4S3
S3 = 1×10‑9
S = 1×10-3

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5
Q

The relationship between Kp and Kc is given by

A

Kp = Kc (RT)∆n
∆n = np – nR
delta n is an exponent

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6
Q

human blood maintains its pH between

A

7.3 -7.4

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7
Q

theoretical yeild is calculated using

A

mass of limiting reactant

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8
Q

if Qc is greater than Kc, this implies

A

reaction will reverse to achieve eqb

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9
Q

Relationship bw Qp and Qv

A

Qp = Qv + nRT

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10
Q

the value of ionic product of water at 25 C is

A

1 x 10^-14 mol2 dm-6

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11
Q

Two electrons cannot occupy a single orbital when degenerate orbitals are available is a statement of:

A

Hund’s rule

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