chem eqb Flashcards
The value of KC is changed by change in temperature because
Equilibrium position shift without any substance being added or removed
In a reversible reaction, change in temperature, change the equilibrium position. So KC depend upon temperature.
Which sparingly soluble salt solution will be unsaturated?
Ksp > ionic product
A beaker contains a saturated solution of potassium Perchlorate. When potassium chloride (KCl) is added to this solution, some of the potassium Perchlorate is precipitated. It means that
KCl is a stronger electrolyte as compared with KClO4
Strong electrolyte (KCl) will suppress the ionization of weak electrolyte (KClO4)
Solubility product of BaCl2 is 4×10-9. Its solubility would be
BaCl2 ⇌ Ba+2 + 2Cl–
Ksp = [Ba+2][Cl–]2 = (S)(2S)2 = 4S3
4 × 10-9 = 4S3
S3 = 1×10‑9
S = 1×10-3
The relationship between Kp and Kc is given by
Kp = Kc (RT)∆n
∆n = np – nR
delta n is an exponent
human blood maintains its pH between
7.3 -7.4
theoretical yeild is calculated using
mass of limiting reactant
if Qc is greater than Kc, this implies
reaction will reverse to achieve eqb
Relationship bw Qp and Qv
Qp = Qv + nRT
the value of ionic product of water at 25 C is
1 x 10^-14 mol2 dm-6
Two electrons cannot occupy a single orbital when degenerate orbitals are available is a statement of:
Hund’s rule