1.4 Bonding Flashcards

(41 cards)

1
Q

what is ionic bonding

A

an electrostatic attraction between oppositley charged ions

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2
Q

what is an ionic crystal

A

-lattice of ions
-held together by electrostatic attraction of oppositely charged ions

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3
Q

Why do ionic compounds have high melting points

A
  • strong electrostatic attraction between oppositely charged ions require lots of energy to break
  • therefore they have high melting points
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4
Q

What is a covalent bond

A
  • involves the sharing of electron pairs between atoms
  • forms due to electrostatic attraction between the positive nuclei of the bonded atoms and the negative electrons which are between the two nuclei
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5
Q
A
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6
Q

What is ionic bonding found between

A

non-metal + metal

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7
Q

What is ionic bonding found between

A

non-metal + metal

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8
Q

What is covalent bonding found between

A

non metal + non-metal

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9
Q

What is metallic bonding found between

A

metal + metal

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10
Q

why are metals conductive?

A

due to the sea of delocalised electrons

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11
Q

what is the point of chemical bonding

A

chemical bonding occurs for atoms to get a stable electron configuration

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12
Q

define a chemical bond

A

a chemical bond is an electrostatic force of attraction between elements with a positive and negative charge

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13
Q

giant covalent

A

high melting point

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14
Q

simple covalent

A

low melting point (small molecules)

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15
Q

how to drawn ionic bonding

A

dot and cross diagram

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16
Q

how to draw covalent bonding

A

dot and cross diagram but with overlapping orbital

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17
Q

Why is a covalent bond formed

A

By sharing a pair of electrons (each electron donates an electron each to the shared pair)

18
Q

What is bond polarity

A

separation of electric charge along a bond.
polar bonds occur when electrons in the bond are not shared equally

20
Q

Electronegativity

A

The ability of an atom to attract the shared pair of electrons (electron density) in a covalent bond towards itself

21
Q

Factors that affect Electronegativity

A
  • nuclear charge
  • atomic radius
  • shielding
22
Q

Electronegativity trend across a group:

A
  • increases across a group
23
Q

Electronegativity down a period

A
  • Decreases down a period
24
Q

What properties cause a dipole bond to form

A

The electronegativities of the elements are different

25
What bond occurs when there is no dipole?
pure covalent
26
what bond occurs when there is a dipole?
polar covalent
27
where will delta- go?
The more electronegative
28
where will delta+ go?
The least electronegative
29
What is a temporary dipole
an uneven distribution of electrons, making one half of the molecule more negatively charged than the other
30
What is a permanent dipole
- when 2 covalently bonded atoms have different electronegativities, forming a polar bond. This causes a delta- and delta+ region
31
What is an induced dipole
created when electron distribution around a molecule is influenced by a charged particle
32
Compare the bond character in a covalent bond and ionic bond
covalent bond - electrons equally shared between atoms, no overall charge ionic bond - complete transfer of electrons between atoms to produce ions will full charges
33
what type of intermolecular forces are there
- Temporary dipole - Permanent dipole - Hydrogen bonding
34
35
what is a dipole
A molecule with 2 different charges
36
hydrogen bonding
permanent dipole-dipole but occurs when a H is bonded to: - fluorine - oxygen - nitrogen
37
Strength of intermolecular forces:
h-bonding > permanent dipole-dipole > van der Waals' this means that H-bonding has a higher boiling point.
38
what is a lone pair of electrons
a pair of electrons in a valence shell that are no involved in bonding
39
What happens to boiling points across a group
they increase
40
why do boiling point increase across a group
- number of electron increase - strength of intermolecular forces increase (more electrons = greater strength)
41
why are boiling points of Group 4 hydrides lower than hydrides of Groups 5, 6 and 7
5, 6 and 7 are more likely to have dipole-dipole