2.HT Atomic and Molecular Spectroscopy Flashcards
1
Q
- what is the equation of the energy of electromagnetic radiation
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2
Q
- what is the equation for the speed of electromagnetic radiation
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3
Q
- what is the equation relating the speed to the permittivity and permeability of free space
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4
Q
- what is the equation for the energy of photons
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5
Q
- what is the equation for the linear momentum of photons
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6
Q
- what is the equation for the (spin) angular momentum of photons
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7
Q
- what are the units of wavelength
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8
Q
- what are the units of frequency
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9
Q
- what are the units of energy
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10
Q
- what are the units of wavenumber
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11
Q
- define the Born Oppenheimer approximation
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12
Q
- define Boltzman’s Law?
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13
Q
- write the equation for stimulated absorption and its associated rate
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14
Q
- define Planck’s Law
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15
Q
- write the equation for stimulated emission and its associated rate
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16
Q
- write the equation for spontaneous emission and its associated rate
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17
Q
- derive the Einstein coefficients
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18
Q
- what are the three conditions for non-zero transition probability
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19
Q
- define the transition dipole moments
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20
Q
- define the dipole moment operator
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21
Q
- write an expression for the transition intensity related to transition dipole moment
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22
Q
- define the Einstein coefficient B21
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23
Q
- define Fermi’s Golden Rule
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24
Q
- what is the Hamiltonian for single-electron atom
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25
Q
- what is the equation for the energy of a single-electron atom
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26
Q
- draw the Grotrian diagram for H-atom
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27
Q
- what are the selection rules that apply to single-electron atom
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28
Q
- what is the equation for the wavenumber of a transition in a single-electron atom
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29
Q
- explain the origin of the angular momentum selection rule
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30
Q
- what is the Hamiltonian for multiple-electron atom
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31
Q
- what is the Orbital Approximation
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32
Q
- what are the issues with the Orbital approximation
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33
Q
* SPECTRA OF ALKALI METALS*
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34
Q
- draw the Grotrian diagram for Na atom and include any relevant selection rules
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35
Q
- what is ns –> np transition called
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36
Q
- what is np –> ns transition called
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37
Q
- what is nd –> np transition called
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38
Q
- what is nf –> nd transition called
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39
Q
- what is the equation for the energy of energy of a multiple-electron atom
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40
Q
- what is spin-orbit coupling
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41
Q
*** derive an expression for the energy of spin-orbit coupled
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42
Q
- draw the fine structure splitting for 2P level system
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43
Q
- what is the selection rule on j transitions for multiple-electron atom
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44
Q
- what is the degeneracy of the j states
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45
Q
- what is the general form of atomic term symbol
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46
Q
- how does Russel-Saunders Coupling work
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47
Q
- define the Pauli principle
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48
Q
- what does the Pauli principle mean for the symmetry of fermions with respect to exchange
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49
Q
- what does the Pauli principle mean for the symmetry of bosons with respect to exchange
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50
Q
- draw the spin states of singlet spin wavefunction
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51
Q
- draw the spin states of triplet spin wavefunction
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52
Q
- what is meant by electron correlation
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53
Q
- what is Hund’s first rule and how does it link to Fermi hole/heap concept
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54
Q
- what causes the degeneracy of singlet and triplet spin states to be lifted
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55
Q
- draw the Grotrian diagram for He and the relevant selection rules
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56
Q
- draw the configuration, terms, levels and states of unsnap configuration
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57
Q
** MICROSTATE TABLES **
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58
Q
- define Hund’s rules for ground states
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59
Q
- what are the assumptions of Hund’s rules
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