Quiz 3 Flashcards

1
Q

atoms tend to migrate from regions of…

A

high concentration to low concentration

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2
Q

Vavancy diffusion

A

atoms and vacancies exchange positions
-occur above 0 K
-applies to host and substitutional impurity atoms
-diffusion rate depends on 1. number of vacancies and 2. activation energy to exchange

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2
Q

self diffusion

A

migration of host atoms in pure metals

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3
Q

interstitial diffusion

A

small interstitials move from one interstitial position to another
-more rapid than vacancy diffusion b/c space already available

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4
Q

doping

A

diffusion of very small concentrations of atoms of an impurity (e.g. P) into semiconductor silicon

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5
Q

steady state diffusion

A

-rate of diffusion (flux) indep. of time
-Flux (J) proportional to concentration gradient
-Fick’s first law

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6
Q

non-steady state diffusion

A

-concentration is a function of time and position (depends on time and position)
-Fick’s second Law

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7
Q

Diffusion coefficient D is dependent on..

A

temperature
-D has exponential dependence on T

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8
Q

elastic deformation

A

nonpermanent, reversible (material will bounce back)
-generally valid at small deformations
-linear stress strain curve
-young’s modulus/modulus of elasticity, E
-hooke’s law

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9
Q

Plastic deformation

A

permanent and nonrecoverable
-stress strain curve is nonlinear

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10
Q

yield strength

A

stress at which noticeable plastic deformation has occured

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11
Q

tensile strength (TS)

A

max stress on engineering stress-strain curve (highest stress value)

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12
Q

ductility

A

amount of plastic deformation at failure

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13
Q

resilience

A

ability of a material to absorb energy during elastic deformation
-modulus of resilience, U_r
-U_r is area under stress strain curve until yielding

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14
Q

toughness

A

-amount of energy absorbed before fracture
- total area under stress strain curve

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15
Q

hardness

A

measure of resistance to surface plastic deformation, dents, or scratches
-large hardness means high resistance to compressive deformation, better wear properties
-small indents mean large hardness

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16
Q

stiffness

A

material’s resistance to elastic deformation

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17
Q

strength

A

a material’s resistance to plastic deformation
-yield and tensile strengths

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18
Q

slip

A

plastic deformation by dislocation motion (edge, screw, mixed)
-atomic bonds broken and reformed along slip plane as dislocation moves
-caterpillar analogy

19
Q

edge dislocation motion

A

moves in direction of shear stress tau/parallel

20
Q

screw dislocation motion

A

moves perpendicular to shear stress tau

21
Q

dislocation characteristics for metals

A

-dislocation motion relatively easy due to non-directional metallic bonding
-occurs on close packed planes in packing direction

22
Q

dislocation characteristics for ceramics (covalently bonded)

A

-relatively difficult dislocation motion due to strong covalent bonding directions
-ex. silicon, diamond

23
Q

dislocation characteristics for ceramics (ionic bonding)

A

-relatively difficult dislocation motion
-few slip systems because motion of nearby ions of like charge (+, -) restricted by electrostatic repulsive forces
-ex. NaCl, MgO

24
Q

slip system

A

-combination of slip plane and slip direction

25
Q

slip plane

A

-plane with high planar density
-Close packed plane!

26
Q

slip direction

A

-direction with high linear density
-most atoms touching
-packing direction

27
Q

FCC Slip System

A

-slip system for FCC is {111} <110>
-dislocation motion on {111} planes
-dislocation motion in <110> directions
-total of 12 independent slip systems for FCC

28
Q

When does slip occur for single crystals?

A

when resolved shear stress > critical resolved shear stress

29
Q

single crystal slip

A

parallel slip steps form on surface of single crystal
-steps result from motion of large numbers of dislocations on same slip plane
-slip steps on single crystals sometimes appear as “slip lines”
-parallel slip planes

30
Q

slip in polycrystallines materials

A

-many grains with random directions
-slip plane orientation and slip directions (lamda, phi) vary from grain to grain
-slip occurs in each grain on the most favorable slip system (largest resolved shear stress, or when resolved shear stress> Tcrss)

31
Q

before rolling polycrystalline materials

A

-grains equiaxed and randomly oriented
-properties isotropic (independent of orientation)

32
Q

-after rolling polycrystalline materials

A

-grains elongated in rolling direction
-properties become somewhat anisotropic (dependent on orientation)

33
Q

strengthening mechanisms for metals

A
  1. reduce grain size
  2. solid-soln strengthening
  3. strain hardening
34
Q

reducing grain size

A

-increases grain boundary area (barrier to dislocation motion)
-more barriers to dislocation motion
-increases yield strength, tensile strength, and hardness

35
Q

solid soln strengthening (introduce small substitutional impurities in compressive region)

A

-small substitutional impurities introduce tensile strains
-when locate above slip line for edge dislocation, partial cancellation of tensile and compressive strains

36
Q

solid soln strengthening (introduce large substitutional impurities in tensile region)

A

-when located below slip line, there is partial cancellation of compressive and tensile stresses

37
Q

strain hardening (cold working)

A

-plastically deforming metals at room temp makes them harder and stronger
-deformation: often reduction in cross-sectional area
-as %CW increases, so do yield strength, tensile strength. ductility decreases
-CW increases dislocation density. dislocation motion hindered by presence of more dislocations

38
Q

heat treating/softening/annealing

A

-heat treating cold-worked metals
-decreases TS, increases ductility (%EL)
3 stages
1. Recovery
2. Recrystallization
3. Grain growth

39
Q

recovery

A

-reduction in dislocation density
-annihilation of dislocations

40
Q

recrystallization temperature

A

temp at which deformed grains are replaced by new grains
-depends on %CW: T_r decreases with increasing %Cw
-depends on purity of metal: T_r decreases with increasing purity

41
Q

recrystallization

A

new grains form that…
-have low dislocation densities
-are small in size
-consume and replace cold-worked grains

42
Q

cold vs hot working

A

-hot working: deformation above T_r
-cold working: deformation beclow T_r

43
Q

grain growth

A

-avg. grain size increases
- small grains shrink and ultimately disappear
-large grains continue to grow

43
Q

metals with small grains

A

strong and tough at low temps

44
Q

metals with large grains

A

good creep resistance at high temps
(creep=tendency of metal to undergo slow deformation when under persistent mechanical stresses)