thermochemistry/ calrometry Flashcards

1
Q

what is thermochemistry?

A

study of the role of heat in physical & chemical changes.

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2
Q

what is enthalpy?

A
  • heat
  • sum of kinetic & chemical energies for a system
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3
Q

what’s a system?

A

the thing your working with

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4
Q

what is temperature?

A

measure of a system’s kinetic energy

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5
Q

what is kinetic?

A

energy of motion

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6
Q

Q=mc deltaT
things to remember..?

A

q- quantity of kinetic energy (J)
m- mass in g
c- specific heat capacity (J/g°C)
delta- change/ difference in
t- temperature

mass n capacity must always be +

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7
Q

what is specific heat capacity?

A

how much energy it takes to heat something

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8
Q

what is endothermic?
use to determine system

A

-energy absorbed
-Q>0; TF>To
- increase in temp

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9
Q

what is exothermic?
use to determine system

A

-energy released
-Q<0;TF<To
-decrease in temp

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10
Q

what is chemical potential energy?

A

energy stores in chemical bonds
cannot be measured directly

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11
Q

deltaH=ndeltaHm

A

deltaH- enthalpy change (kJ)
n- # of moles (mol)
deltaHm- molar enthalpy of change (kj/mol)

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12
Q

what is fusion?

A

melting
(solid to liquid state)
endo

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13
Q

what is evaporation/vaporizing?

A

boiling
(liquid to gas state)
endo

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14
Q

what is sublimation?

A

dry ice-solid CO2
solid to gas state
endothermic

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15
Q

what is solidification?

A

freezing
(liquid to solid state)
exo

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16
Q

what is condensation?

A

rain
gas to liquid state
exo

17
Q

what is deposition?

A

gas to solid state
exothermic

18
Q

what’s a complex enthalpy change?

A

changes in energy involving kinetic & potential energy
(heating curve)

19
Q

what’s deltaEk?

A

kinetic energy

20
Q

what’s deltaEp?

A

potential energy

21
Q

what is calorimetry?

A

chemical potential energy, cannot he measure directly

22
Q

-Qexo=Qendo
(Qendo + Qexo=0)

A

Qendo + Qexo = 0
mcdeltaT + mcdeltaT = 0