3.1 Organic Chemistry Introduction Flashcards

1
Q

Define empirical formula

A

Simplest whole number ratio of atoms in a molecule

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2
Q

Define molecular formula

A

Gives the actual number of atoms of different elements in a molecule

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3
Q

Define displayed formula

A

Shows every atom and every bond in a molecule

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4
Q

Define structural formula

A

Shows arrangement of atoms in a molecule without showing every bond

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5
Q

Define skeletal formula

A

Drawn as lines with each vertex being a carbon atom. Carbon atoms not drawn, assumed each C atom has all unspecified bonds as C-H

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6
Q
A
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7
Q
A
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8
Q

Define structural isomerism

A

When molecules have the same molecular formula but different structural formula

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9
Q

What is positional isomerism?

A

Functional group is attached to the main chain at a different place

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10
Q

What is functional group isomerism?

A

Same atoms but different functional group due to a different arrangement of atoms

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11
Q

What is chain isomerism?

A

Hydrocarbon chain organised differently e.g. branched chains

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12
Q

Define stereoisomerism.

A

When molecules have the same structural and molecular formula, but different arrangement of atoms in space

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13
Q

What is E-Z isomerism and how are the E and Z isomers decided?

A

E-Z isomerism is caused by the limited rotation about C=C double bonds.

If the twp substituents with the highest molecular mass are on the same side of the double bond, it is the Z (zusammen) isomer.

If they are on different sides, it is the E (entgegen) isomer.

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