Lipids 2 Flashcards

1
Q

Simple lipids are … And …

A

Triacylglycerol
Waxes

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Wax composition + examples

A

Monohydric alcohol+ fatty acid
Bee wax&raquo_space; palmitic acid C16+ myricyl alcohol C30
Cholesteryl ester» lanolin(animal fur+ skin enhancement)
Vitamin A (retinol)
Vitamin D (calciferol)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Triacyl glycerols composition
Glycerol general + bonded to..

A

3 fatty acids+ 1 glycerol
Glycerol> odourless, colourless,sweet,miscible in water
R1> saturated fatty acid
R2>unsaturated
R3>either

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Physical properties of TAGs

A

Yellow colour due to cartenoids
Colourless and odourless
Insoluble in water
Soluble in fats

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Chemical properties of simple lipids

A

Rancidity
Hydrogenation/hardening (from USFA to SFA)margarine

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Rancidity
What
Types

A

Development of bad odor in fats due to exposure of high temperature moisture ,humidity and metals that act as catalysts.
Hydrolytic» butter
Oxidative» oils

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Difference bet hydrolytic and oxidative

A

Hydrolytic» high temp release of short chain fatty acids due to bond breaking by lipase enzyme

Oxidative»oxidation of USFA to produce peroxides causing the chains to be broken, bad odour and bitter taste

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Protecting from rancidity

A

Addition of antioxidants like vitamin E and phenols, decreasing rate of rancidity and protect from oxidation

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Compound lipids classification

A

Acc to Alcohol
Phosphoglycerides
Sphingomylein

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Phosphoglycerides are broken down by…

A

Phospholipases

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Parent group of phophoglycerides

A

Phosphatidic acid
Glycerol+ saturated+ unsaturated+ phosphoric acid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Lecithin

A

Phosphatidic+ choline
Cell membrane of brain/liver/lung
Lipotropic factor, preventing fatty liver
Forms cholesterol ester

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Cephalin

A

Phosphatidic acid+ ethanol amine

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Phosphatydlserine

A

Phosphatidic acid+ serine

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Phosphatdyl glycerol

A

Phosphatidic acid+ glycerol

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Phospholinositol

A

Phosphatidic acid+ inositol
Secondary messenger in intracellular signal transduction

17
Q

Diphosphatydlglycerol also is…

A

Cardiolipin
2 Phosphatidic acid+ glycerol in between
Inner mitochondrial membrane

18
Q

Plasmalogens

A

Ether phospholipid
Glycerol+ fatty alcohol+ fatty acid+ R group(choline or ethanolamine)
Cardiovascular system/ nervous system
Decrease= Alzheimer’s

19
Q

Acid + alcohol
Alcohol+ alcohol

A

Ester
Ether

20
Q

Why snake venom causes hemolysis

A

Lecithinase enzyme
That converts phospholipids to lysophospholipids(+fatty acid)
Lecithin> lysolecithin by phospjolipase

21
Q

Sphingomylein alcohol

A

Sphingosine/ sphingol
18C

22
Q

What is ceramide

A

Sphingol+ fatty acid

23
Q

Sphingomylein

A

Ceramide+ phosphocholine

24
Q

Phospholipid functions 8

A

PAF, platelet activating factor
Eicosanoids synthesis
Micelles in water
Emulsifying factors
Hydrotropic subs, prevent cholesterol deposits/ gall stones
Bilayer of membrane
Lipoproteins
Lung surfactant

25
Q

Lung surfactant

A

Dipalmitoyl-lecithin: sphingomyelin
Ratio is important to prevent respiratory distress disorder in premature infants

26
Q

Glycolipids

A

Ceramide+ carbon radical

27
Q

Types of glycolipids

A

Cerebrosides»galactose/glucose
Sulpholipids» cerebroside+ sulphate on C3
Gangliosides»ceramide+ complex carb(mixture of glucose/galactose/NANA+ 18C fatty acids(oleic/stearic))

28
Q

Cerebrosides

A

Brain tissue, presence of 24C fatty acids
Cerebronic acid/ nervonic acid/ lignoceric acid

29
Q

Importance of glycolipids

A

Brain tissue
Mylein sheath
Cell membrane of RBCs
Cell membrane receptors(hormones/ external stimuli)
Recognition Properties