15. Periodic Table Flashcards

(45 cards)

1
Q

What trend is observed for atomic radius across Period 3?

A

Decreases

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Why does atomic radius decrease across Period 3?

A

Increasing nuclear charge with constant shielding

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Why is argon’s atomic radius excluded in comparisons?

A

Argon is monoatomic with minimal electron cloud overlap

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

How do anions compare in size to cations?

A

Anions are larger

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Why do cations in Period 3 decrease in ionic radius?

A

Increasing nuclear charge in isoelectronic ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Why are anions larger than their parent atoms?

A

Greater inter-electronic repulsion

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What general trend is observed in 1st ionisation energy across Period 3?

A

Increases

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Why does ionisation energy increase across the period?

A

Increasing nuclear charge with constant shielding

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Which element in Period 3 has a lower than expected ionisation energy?

A

Aluminium

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Why is sulfur’s ionisation energy lower than expected?

A

Electron-electron repulsion in the 3p orbital

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

What happens to electronegativity across Period 3?

A

Increases

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Why does electronegativity increase across the period?

A

Increased nuclear charge without increased shielding

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Why do metals in Period 3 have high melting points?

A

Strong metallic bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Which element in Period 3 has the highest melting point?

A

Silicon

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Why does Si have the highest melting point?

A

Giant molecular structure with strong covalent bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Which elements in Period 3 conduct electricity?

A

Na, Mg, Al

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

Why do metals conduct electricity?

A

Delocalized electrons act as mobile charge carriers

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

Which oxides in Period 3 are ionic?

A

Na2O, MgO, Al2O3

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

Why does Al2O3 have covalent character?

A

High charge density of Al3+

20
Q

What kind of structure does SiO2 have?

A

Giant molecular structure

21
Q

What type of bonding is present in P4O10 and SO3?

22
Q

What does Na2O form when it reacts with water?

23
Q

Which oxide in Period 3 is amphoteric?

24
Q

Why is SiO2 insoluble in water?

A

Strong covalent bonds

25
How does the acid-base nature of oxides change across Period 3?
From basic to acidic
26
Which oxide is amphoteric in nature?
Al2O3
27
What does SiO2 form when it reacts with NaOH?
Na2SiO3
28
What is the bonding nature of NaCl and MgCl2?
Ionic
29
Why is AlCl3 covalent?
Al3+ has high charge density and polarizes Cl? anion
30
What kind of structure does SiCl4 have?
Simple molecular
31
What is the pH of a NaCl solution?
Neutral (7)
32
What does AlCl3 form when dissolved in water?
Al(OH)3 and HCl
33
Why does SiCl4 react with water to form SiO2 and HCl?
Hydrolysis due to vacant 3d orbitals
34
What trend is observed in atomic radius down Group 2 and 17?
Increases
35
Why does ionisation energy decrease down Group 2 and 17?
Increased shielding and distance from nucleus
36
What happens to melting point down Group 2?
Decreases
37
Why do Group 2 elements act as reducing agents?
They lose electrons easily
38
What trend is observed in the reducing power of Group 2 elements down the group?
Increases
39
Why do Group 2 elements become more reactive as reducing agents down the group?
Weaker attraction to valence electrons due to increased shielding
40
What trend is observed in the thermal stability of Group 2 carbonates down the group?
Increases
41
Why does thermal stability increase down Group 2?
Decreasing charge density of cations
42
What happens to the oxidising power of Group 17 elements down the group?
Decreases
43
Why does oxidising power decrease down Group 17?
Weaker attraction to incoming electrons due to increased shielding
44
What happens to the thermal stability of hydrogen halides down Group 17?
Decreases
45
Why is HI the least thermally stable hydrogen halide?
Weakest H?I bond