Thermodynamics & Heat Transfer Flashcards

1
Q

Thermo: Properties of Substances - Phases of a Pure Substance

Ideal gas law (formula)

A

pV = nRT

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2
Q

Thermo: Properties of Substances - Phases of a Pure Substance

What is a p-v-T diagram?

A

3D surface that predicts a substance’s phase based on the properties of presure, specific volume, and temp.

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3
Q

Thermo: Properties of Substances - Phases of a Pure Substance

What is the vapor dome?

A

The bell-shaped diving line at the liquid-vapor region.

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3
Q

Thermo: Properties of Substances - Phases of a Pure Substance

What other diagrams can be derived from a p-v-T diagram?

A

Pressur-Volume Phase Diagram (2D projection of the 3D p-v-T diagram, where one property is held constant. In this case, that is temperature.)

Vapor Dome Diagram

These are phase diagrams or equiplibrium diagrams.

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4
Q

Thermo: Properties of Substances - Phases of a Pure Substance

Define the saturated liquid line?

A

Left-hand part of the vapor dome curve that separates the liquid phase from the liquid-vapor phase.

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5
Q

Thermo: Properties of Substances - Phases of a Pure Substance

Define saturated vapor line?

A

Right-hand part of the vapor dome curve that separates the liquid-vapor phase from the vapor phase.

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6
Q

Thermo: Properties of Substances - Phases of a Pure Substance

Define isobars?

A

Lines of constant pressure.

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7
Q

Thermo: Properties of Substances - Phases of a Pure Substance

Above the vapor dome, the phase is what?

A

Gas

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8
Q

Thermo: Properties of Substances - Phases of a Pure Substance

What is the critical isobar?

A

The dividing line between liquid and gas that intersects the topmost part of the vapor dome**.

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9
Q

Thermo: Properties of Substances - Phases of a Pure Substance

What is the critical point?

A

The highest point of the vapor dome.

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10
Q

Thermo: Properties of Substances - Phases of a Pure Substance

What is the triple point?

A

A unique state at which solid, liquid, and gaseous phases can coexist.

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11
Q

Thermo: Properties of Substances - Phases of a Pure Substance

Define isotherms?

A

The lines of constant temperature.

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12
Q

Thermo: Properties of Substances - Phases of a Pure Substance

‘1. A substance is a subcooled liquid if:

A

its temperature is less than the saturation temperature corresponding to its pressure.

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13
Q

Thermo: Properties of Substances - Phases of a Pure Substance

‘2. A substance is in the liquid-vapor region if:

A

its temperature is equal to the saturation temperature corresponding to its pressure.

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14
Q

Thermo: Properties of Substances - Phases of a Pure Substance

‘3. A substance is a superheated vapor if:

A

its temperature is greater than the saturation temperature corresponding to its pressure.

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15
Q

Thermo: Properties of Substances - Phases of a Pure Substance

‘4. A substance is a subcooled liquid if:

A

its pressure is greater than the saturation pressure corresoponding to its temperature.

16
Q

Thermo: Properties of Substances - Phases of a Pure Substance

‘5. A substance is in the liquid-vapor region if:

A

its pressure is equal to the saturation pressure corresponding to its temperature.

17
Q

Thermo: Properties of Substances - Phases of a Pure Substance

‘6. A substance is a superheated vapor if:

A

its pressure is less than the saturation pressure corresponding to its temperature.

18
Q

Thermo: Properties of Substances - State Functions (Properties)

Define intensive properties?

A

Properties that are independent of the amount of a substance present.

19
Q

Thermo: Properties of Substances - State Functions (Properties)

Define extensive properties?

A

Properties that are dependent of the amount of a substance present.

20
Q

Thermo: Properties of Substances - State Functions (Properties)

Examples of intensive properties:

A

temperature, pressure, stress

21
Q

Thermo: Properties of Substances - State Functions (Properties)

Examples of extensive properties:

A

volume, strain, charge, mass

22
Q

Thermo: Properties of Substances - State Functions (Properties)

Rankine scale (formula)

A

Tf + 459.67 degrees

23
Q

Thermo: Properties of Substances - State Functions (Properties)

Kelvin scale (formula)

A

Tc + 273.15 degrees

24
Q

Thermo: Properties of Substances - State Functions (Properties)

Define enthalpy?

A

Represents the total useful energy of a substance.

25
Q

Thermo: Properties of Substances - State Functions (Properties)

Define entropy?

A

A measure of the energy that is no longer available to perform useful work within the current environment.

26
Q

Thermo: Properties of Substances - State Functions (Properties)

Formula for heat energy (Q)?

A

Q = mcΔT

27
Q

Thermo: Properties of Substances - State Functions (Properties)

Formula for quality (x)?

A

x = Mvapor / Mvapor + Mliquid

28
Q

Thermo: Properties of Substances - Ideal Gases

Another ideal gas relationship for pressure, volume, and temperature? (formula)

A

p1V1 / T1 = p2V2 / T2

29
Q

Thermo: Properties of Substances - Ideal Gases

How can you calculate the number of moles (n) of a substance?

(explanation and formula)

A

Using the mass (m) and molecular weight (MW).

n = m / MW

30
Q

Thermo: Properties of Substances - Ideal Gases

Define isentropic processes.

A

entropy is constant

31
Q

Thermo: Properties of Substances - Speed of Sound & Mach

What is a Mach number? (definition)

A

The ratio of an object’s speed to the speed of sound in the medium through which the object is traveling.