Chapter 3&4- Atomic Structure Flashcards

1
Q

What is an element?

A

An element is a substance that cannot be broken down into similar substances by chemical means

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2
Q

What is a triad?

A

A group of 3 elements that have similar chemical properties in which the middle is the average atomic weight of the others

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3
Q

What are Newlands octaves?

A

Arrangements of elements in which the first and eighth element have similar properties

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4
Q

What does Mendeleev’s Periodic Law state?

A

When elements are arranged in order of increasing atomic {weight}, then properties of elements occur periodically.

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5
Q

What is the Modern Periodic Law?

A

When elements are arranged in order of increasing atomic {number}, properties of elements recur periodically

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6
Q

What are the 3 key differences between Mendeleev’s Periodic Table and the Modern Periodic Table?

A
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7
Q

Define the “Atomic number” of an atom

A

Number of protons in the nucleus of an atom

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8
Q

Define the “Mass number” of an atom

A

Number of protons + neutrons in the nucleus of an atom

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9
Q

Define the term “isotope”

A

Atoms of the same element which have a different mass number due to different quantities of neutrons

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10
Q

Define “Relative Atomic Mass”

A

The average mass numbers of the isotopes of an element.

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11
Q

How does a mass spectrometer work? (5 stages)

A
  1. Vaporisation
  2. Ionisation
  3. Acceleration
  4. Separation
  5. Detection
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12
Q

What is an energy level?

A

An energy level is the fixed energy value that an electron in an atom may have

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13
Q

What is the ground state of an atom?

A

The ground state of an atom is one in which the electrons occupy the lowest available energy level

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14
Q

What is the excited state of an atom?

A

The excited state of an atom is one in which electrons occupy higher energy levels than those available in the ground state

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15
Q

What is the principal of mass spectrometry?

A

Charged particles moving in a magnetic field are deflected to different extents according to their masses and are separated accordingly

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16
Q

What is an orbital?

A

An orbital is a region in space within which there is a high probability of finding an electron

17
Q

What is a sublevel?

A

A sublevel is a subdivision of a main energy level and consists of one or more orbitals of the same energy

18
Q

What does an electronic configuration do?

A

Show the arrangement of electrons in an atom of an element

19
Q

What are the names of the first 10 sublevels?
and how many electrons can they hold each?

A
20
Q

What are the exceptions to the rules of electronic configuration?

A

Chromium which ends in 4s1, 3d5 (rather than 4s2 3d4)
Cobalt which ends in 4s1, 3d10 (rather than 4s2 3d9)

21
Q

Define the Aufbau Principal

A

Electrons always occupy the lowest available energy level in its ground state

22
Q

What is Hund’s rule of maximum multiplicity?

A

When two or more orbitals of equal energy are available, the electrons occupy them singly before filling them in pairs.

23
Q

What is Pauli’s Exclusion Principle?

A

No more than 2 electrons may occupy the same orbital and they must have opposite spin

24
Q

What does Heisenberg’s Uncertainty Principal state?

A

It is impossible to measure at the same time both the velocity and the position of an electron