Atoms Flashcards

1
Q

What experiments in the nineteenth century supported the atomic hypothesis of matter?

A

Experiments on electric discharge through gases conducted by J. J. Thomson in 1897 revealed negatively charged constituents (electrons) in atoms.

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2
Q

What was J. J. Thomson’s proposed model of the atom, and when was it proposed?

A

Thomson’s plum pudding model, proposed in 1898, suggested that atoms contain positively charged material with electrons embedded throughout like seeds in a watermelon.

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3
Q

How did the spectrum of light emitted by rarefied gases differ from that emitted by condensed matter or dense gases?

A

Light emitted by rarefied gases exhibited discrete wavelengths, appearing as a series of bright lines, whereas condensed matter emitted electromagnetic radiation with a continuous distribution of several wavelengths.

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4
Q

What relationship was established between the internal structure of an atom and the spectrum of radiation emitted by it?

A

Each element was associated with a characteristic spectrum of radiation, implying an intimate relationship between an atom’s internal structure and its emitted spectrum.

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5
Q

Describe Ernst Rutherford’s contribution to atomic structure theory.

A

Rutherford proposed the planetary model of the atom, also known as the nuclear model, in 1911. He suggested that atoms consist of a dense nucleus containing the entire positive charge and most of the mass, with electrons orbiting around it.

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6
Q

What experiment led to the development of Rutherford’s planetary model of the atom?

A

The scattering of alpha particles by atoms, proposed by Rutherford in 1906 and later performed by Hans Geiger and Ernst Marsden around 1911, led to the development of Rutherford’s model.

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7
Q

Who was Ernst Rutherford?

A

Ernst Rutherford was a New Zealand-born British physicist known for his pioneering work on radioactive radiation.

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8
Q

What did Ernst Rutherford discover about radioactive radiation?

A

Rutherford discovered alpha-rays and beta-rays, contributing significantly to the understanding of radioactive decay.

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9
Q

Who did Ernst Rutherford collaborate with, and what was their contribution?

A

Rutherford collaborated with Frederick Soddy to create the modern theory of radioactivity, a significant advancement in the field.

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10
Q

What did Rutherford study regarding thorium, and what did he discover?

A

Rutherford studied the ‘emanation’ of thorium and discovered a new noble gas, an isotope of radon, now known as thoron.

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11
Q

What important discovery did Rutherford make regarding the atomic nucleus?

A

By scattering alpha-rays from metal foils, Rutherford discovered the atomic nucleus, which led to the proposal of the planetary model of the atom.

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12
Q

What estimation did Rutherford provide in his studies?

A

Rutherford estimated the approximate size of the nucleus, a significant contribution to the understanding of atomic structure.

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13
Q

What experiment did H. Geiger and E. Marsden perform in 1911, as suggested by Ernst Rutherford?

A

H. Geiger and E. Marsden directed a beam of 5.5 MeV alpha particles emitted from a 214Bi radioactive source at a thin metal foil made of gold.

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14
Q

Describe the setup of the experiment conducted by H. Geiger and E. Marsden.

A

The alpha particles emitted by the radioactive source were collimated into a narrow beam by passing through lead bricks. This beam was directed at a thin foil of gold with a thickness of 2.1 × 10^–7 m. The scattered alpha particles were observed through a rotatable detector consisting of a zinc sulfide screen and a microscope.

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15
Q

How were the scattered alpha particles observed in the experiment?

A

The scattered alpha particles, upon striking the screen, produced brief light flashes or scintillations, which were observed through a microscope.

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16
Q

What did the distribution of the number of scattered particles allow researchers to study?

A

The distribution of the number of scattered particles allowed researchers to study the scattering angle as a function of the angle of scattering.

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17
Q

What was the significance of the agreement between experimental data and theoretical prediction in Rutherford’s experiment?

A

The agreement between experimental data and theoretical prediction supported the hypothesis of the nuclear atom, leading to Rutherford’s discovery of the nucleus.

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18
Q

Describe Rutherford’s nuclear model of the atom.

A

In Rutherford’s nuclear model, the entire positive charge and most of the mass of the atom are concentrated in a small, dense nucleus, while electrons orbit around the nucleus at a distance.

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19
Q

What did Rutherford’s experiments suggest about the size of the nucleus compared to the size of the atom?

A

Rutherford’s experiments suggested that the nucleus is about 10^–15 m to 10^–14 m in size, whereas the size of an atom is about 10^–10 m, making the nucleus significantly smaller.

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20
Q

What was the assumption made about the scattering of alpha particles in the gold foil?

A

It was assumed that alpha particles would suffer not more than one scattering during their passage through the thin gold foil.

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21
Q

What forces were involved in computing the trajectory of an alpha particle in Rutherford’s experiment?

A

The trajectory of an alpha particle was computed using Newton’s second law of motion and Coulomb’s law for the electrostatic force of repulsion between the alpha particle and the positively charged nucleus.

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22
Q

How does the impact parameter affect the trajectory of an alpha particle?

A

The trajectory of an alpha particle depends on the impact parameter, which is the perpendicular distance of the initial velocity vector of the alpha particle from the center of the nucleus. A smaller impact parameter results in a larger scattering angle, while a larger impact parameter leads to a smaller deflection.

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23
Q

What is the characteristic spectrum emitted by each element when excited at low pressure?

A

Each element emits a characteristic spectrum of radiation, known as an emission line spectrum, when excited at low pressure.

24
Q

How is an emission line spectrum defined?

A

An emission line spectrum consists of bright lines on a dark background and contains specific wavelengths emitted by an atomic gas or vapor when excited.

25
Q

How can emission line spectra be utilized for identification purposes?

A

The emission line spectrum of a material serves as a unique “fingerprint” for identifying the gas or element.

26
Q

What is observed when white light passes through a gas and is analyzed using a spectrometer?

A

When white light passes through a gas and is analyzed using a spectrometer, dark lines are observed in the spectrum.

27
Q

How do the dark lines observed in the spectrum correspond to the emission line spectrum of the gas?

A

The dark lines in the spectrum correspond precisely to the wavelengths found in the emission line spectrum of the gas, forming what is known as the absorption spectrum of the material of the gas.

28
Q

What did Rutherford’s model of the atom propose?

A

Rutherford’s model proposed that the atom consists of a central nucleus surrounded by revolving electrons, similar to a sun-planet system.

29
Q

What force holds the planetary system together, and what force holds the nucleus-electron system together?

A

The planetary system is held together by gravitational force, while the nucleus-electron system is held together by the Coulomb’s Law of force.

30
Q

According to classical electromagnetic theory, what happens to an accelerating charged particle?

A

According to classical electromagnetic theory, an accelerating charged particle emits radiation in the form of electromagnetic waves.

31
Q

Why can’t Rutherford’s model of the atom be stable according to classical electromagnetic theory?

A

According to classical electromagnetic theory, the energy of an accelerating electron should continuously decrease, causing it to spiral inward and eventually fall into the nucleus, making such an atom unstable.

32
Q

What were the modifications made by Niels Bohr to Rutherford’s atomic model?

A

Niels Bohr modified Rutherford’s model by incorporating the ideas of quantum hypothesis, introducing the concept of stable orbits and quantized angular momentum.

33
Q

What are the three postulates of Bohr’s atomic model?

A

The three postulates of Bohr’s atomic model are:
(i) An electron in an atom can revolve in certain stable orbits without emitting radiant energy.
(ii) The angular momentum of the electron in its orbit is quantized, where it is an integral multiple of h/2π (Planck’s constant divided by 2π).
(iii) Electrons can transition between orbits, emitting or absorbing photons with energies corresponding to the energy difference between the initial and final states.

34
Q

How is the radius of the nth possible orbit in Bohr’s model calculated?

A

The radius of the nth possible orbit in Bohr’s model is calculated using the formula: rn = n^2h^2/4π^2m2^2Eo

35
Q

What is the expression for the total energy of an electron in the stationary states of a hydrogen atom according to Bohr’s model?

A

The total energy of an electron in the stationary states of a hydrogen atom is given by En = -2.18 x 10^-18/n2 joules or En = 13.6/n2 eV.

36
Q

What is the significance of the negative sign in the total energy expression of an electron in Bohr’s model?

A

The negative sign indicates that the electron is bound to the nucleus in an atom, and energy is required to remove it to a distance infinitely far away from the nucleus.

37
Q

What is the significance of the term “ground state” in Bohr’s atomic model?

A

The ground state is the lowest energy state of an atom, where the electron occupies the orbit closest to the nucleus. It serves as a reference point for comparing the energies of other excited states.

38
Q

What is the ionization energy of a hydrogen atom according to Bohr’s model?

A

The ionization energy of a hydrogen atom, predicted by Bohr’s model, is 13.6 eV, which is the minimum energy required to remove the electron from the ground state to a distance infinitely far away from the nucleus.

39
Q

How does an atom transition between different energy states in Bohr’s model?

A

An atom transitions between different energy states by absorbing or emitting photons. When an electron moves from a higher energy state to a lower one, a photon is emitted with energy equal to the energy difference between the initial and final states.

40
Q

What does the energy level diagram represent in Bohr’s model?

A

The energy level diagram represents the energy states of a hydrogen atom, where each level corresponds to a specific energy level labeled by the principal quantum number (n).

41
Q

How are the energy levels distributed in the energy level diagram of a hydrogen atom according to Bohr’s model?

A

In Bohr’s model, the energy levels of a hydrogen atom become closer together as the principal quantum number (n) increases, indicating that the energy spacing between levels decreases with increasing distance from the nucleus.

42
Q

What does the energy level diagram show for the highest energy state in Bohr’s model?

A

The highest energy state in Bohr’s model corresponds to when the electron is completely removed from the nucleus and is at rest, represented by an energy of 0 eV.

43
Q

How do the energies of excited states change as the principal quantum number (n) increases?

A

As the principal quantum number (n) increases, the energies of excited states decrease, meaning that less energy is required to excite the electron to higher energy levels farther from the nucleus.

44
Q

Who was Niels Henrik David Bohr?

A

Niels Henrik David Bohr was a Danish physicist.

45
Q

What did Niels Bohr explain regarding the spectrum of the hydrogen atom?

A

Niels Bohr explained the spectrum of the hydrogen atom based on quantum ideas.

46
Q

What model of the nucleus did Niels Bohr propose for the theory of nuclear fission?

A

Niels Bohr proposed the liquid-drop model of the nucleus for the theory of nuclear fission.

47
Q

What contribution did Niels Bohr make to quantum mechanics?

A

Niels Bohr contributed to the clarification of conceptual problems in quantum mechanics.

48
Q

What is the complementary principle proposed by Niels Bohr?

A

Niels Bohr proposed the complementary principle to clarify conceptual problems in quantum mechanics.

49
Q

What is Bohr’s second postulate in his model of the atom, and why is it considered puzzling?

A

Bohr’s second postulate states that the angular momentum of the electron orbiting around the nucleus is quantized, with values that are integral multiples of h/2π. This is puzzling because it raises the question of why angular momentum should have only those specific values.

50
Q

How did Louis de Broglie explain the puzzling aspect of Bohr’s second postulate?

A

Louis de Broglie explained that the electron in its circular orbit, as proposed by Bohr, must be seen as a particle wave. He argued that particle waves, similar to waves on a string, can lead to standing waves under resonant conditions, thereby explaining the quantization of angular momentum.

51
Q

What did C. J. Davisson and L. H. Germer experimentally verify in 1927, related to de Broglie’s hypothesis?

A

C. J. Davisson and L. H. Germer experimentally verified the wave nature of electrons, supporting de Broglie’s hypothesis that material particles, such as electrons, also exhibit wave-like behavior.

52
Q

How did de Broglie relate the electron’s circular orbit to a standing wave?

A

De Broglie related the electron’s circular orbit to a standing wave by considering the electron as a particle wave analogous to waves on a string. He explained that only resonant standing waves can persist, leading to the quantization of angular momentum.

53
Q

What is the quantum condition proposed by Bohr for the angular momentum of the orbiting electron?

A

The quantum condition proposed by Bohr states that the angular momentum of the orbiting electron is quantized and is given by the equation mvnrn = nh/2π, where m i the mass of the electron, vn is its velocity in the nth orbit, rn is the radius of the nth orbit, and n is an integer.

54
Q

What are some limitations of Bohr’s model of the atom?

A

Some limitations of Bohr’s model include its applicability only to hydrogenic atoms, its inability to be extended to atoms with more than one electron, and its failure to account for the relative intensities of spectral lines in the emission spectrum of hydrogen.

55
Q

Why is Bohr’s model unable to explain the relative intensities of spectral lines in the emission spectrum of hydrogen?

A

Bohr’s model is unable to explain the relative intensities of spectral lines because it does not account for the varying probabilities of different electron transitions, leading to some transitions being more favored than others, resulting in intensity variations in the spectrum.