Atomic Structure and the Periodic Table Flashcards

Paper 1 - C1

1
Q

What is an element?

A

All of the atoms are the same

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2
Q

What is a compound?

A

Compounds contain two or more different elements

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3
Q

What is a mixture?

A

A mixture contains two or more substances not chemically combined together

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4
Q

What is a molecule?

A

A molecule has any elements chemically combined even if its the same element e.g. ( H20, NH3, O2, Cl2, CH4)

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5
Q

What is filtration used to separate?

A

Filtration is used to separate an insoluble solid from a liquid

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6
Q

What does insoluble mean?

A

Insoluble means that the solid will not dissolve in the liquid

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7
Q

How does filtration work?

A

-First we use a filter funnel and a filter paper.
-Then we start by pouring your mixture into the filter paper.
-The liquid(filtrate) then will pass through the tiny pores in the filter paper.
-However, the solid material will be trapped as it cannot pass through the filter paper.
-Now, we have our liquid separated from our solid.

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8
Q

What is crystallisation used to separate?

A

Crystallisation is used to separate a soluble solid from a liquid.

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9
Q

What does soluble mean?

A

Soluble means that the solid will dissolve in a liquid

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10
Q

How does crystallisation work?

A

-If we leave the solution in a beaker for a few days, then the water will evaporate.
-This will leave behind crystals of the solution.
-This will change the state symbol from (aq) to (s) as the solution is no longer dissolved in water and is now a solid.

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11
Q

How can we make crystallisation faster?

A

-If we gently heat the solution to evaporate the water.
-However, we need to be careful as certain chemicals will break down if we heat them.
-Meaning it is sometimes better to allow the water to evaporate on its own.

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12
Q

What is simple distillation used to separate?

A

Simple distillation is used to separate a dissolved solid from a liquid but as a result we want to keep the liquid.

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13
Q

What are the two stages of simple distillation?

A

-First, we evaporate the liquid by heating, which will turn the liquid into a vapour.
-Next, we condense the vapour back to a liquid by cooling.

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14
Q

What do we do before we carry out simple distillation?

A

-First, we place our solution with the liquid and dissolved solid into the flask which is connected to a continuous glass tube and is surrounded by a jacket called the condenser.
-Next, make sure cold water from the tap is continuously running through the condenser so the internal glass tube is cold then the water will run into the sink.
-Make sure a thermometer is also connected to the apparatus.

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15
Q

What happens in simple distillation? And how do we carry it out?

A

-First, we start by heating our solution by using a Bunsen burner which will make the liquid start to evaporate turning into a vapour.
-Now, the vapour will rise up the glass tube.
-As the vapour passes over the thermometer, the thermometer reading increases
-Heat the solution till it boils.
-Next, the vapour passes into the condenser (which is cold because of the cold tap water) which causes the vapour to condense.
-This will make it turn back to a liquid as it passes through the condenser.
-Now we can collect the liquid in the beaker.
-At the end, we are also left with crystals of our solid in the flask.

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16
Q

What is simple distillation used for?

A

-It can be used to make sea water into drinking water.
-However, a great deal of energy is required for simple distillation.

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17
Q

What is fractional distillation used to separate?

A

Fractional distillation is used to separate a mixture of different liquids but the liquids must have different boiling points.

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18
Q

How do we set up fractional distillation?

A

-We get a flask with a mixture of different liquids with different boiling points.
-This flask is attached to a long column containing hundreds of glass beads which is called the fractionating column.
-At the top of the fractionating column, we have a thermometer.
-Then we have a condenser which is connected to the fractionating column.

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19
Q

How does fractional distillation work?

A

-We start by gently heating our mixture and our liquids will start to evaporate but the one with the lower boiling point will evaporate more easily. This will give us a mixture of different vapours.
-This mixture will make their way into the fractionating column.
-When they reach the fractionating column they will condense and drip back into the flask where the liquids will evaporate again.
-This repeated evaporation and condensation increases the amount of the lower boiling point chemical in the fractionating column.
-As the warm vapours pass up the column they reach the thermometer and the temperature on the thermometer begins to rise.
-When this temperature rises, this means that the mixture of the different vapours is passing over the thermometer.
-However, the mixture will contain more of the chemical with the lower boiling point.
-These vapours will then pass through the condenser and will turn back into a liquid but it is still a mixture of the two chemicals.
-When the temperature of the thermometer stops rising it will be the lower of the boiling points.
-At this point there is only one chemical passing through the condenser, and as the chemical condenses we can collect it in a fresh beaker.
-After a while the temperature on the thermometer begins to rise again which means again a mixture of vapours is passing through the condenser.
-This mixture will mainly contain the chemical with the higher boiling point.
-When the temperature reaches a constant temperature, we’re now collecting a relatively pure sample of the higher boiling point chemical.

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20
Q

What happens if two liquids have very similar boiling points during fractional distillation?

A

-It’s much harder to separate them.
-We might also need to carry out several rounds of fractional distillation.

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21
Q

What is a solvent?

A

A solvent is a liquid that will dissolve substances.

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22
Q

What is paper chromatography used to separate?

A

Paper chromatography allows us to separate substances based on their different solubilities.

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23
Q

How do we carry out paper chromatography?

A

-First we take a piece of chromatography paper.
-We then draw a pencil line near the bottom of the paper.
-Next we put a dot of our first colour on the pencil line.
-Next to it, we put a dot our second colour.
-We now place the bottom of the paper into a solvent.
-The solvent will now make its way up the paper.
-It dissolves the ink in the two coloured dots.
-Now the ink has carried up the paper dissolved in the solvent.
-Now if the colour has made one dot at the end of the chromatography we know that it was a pure colour but if it made more than one colour it was a mixture of two colours.

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24
Q

Why is the paper called the stationary phase?

A

Because the paper does not move.

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25
Q

Why is the solvent called the mobile phase?

A

Because the solvent moves.

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26
Q

Why does paper chromatography work?

A

Because different substances have different solubilites.

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27
Q

Why does a more soluble substance move further than a substance of less solublitiy?

A

This is because a more soluble substance is more attracted to the mobile phase (the solvent) than a less soluble substance.

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28
Q

Why do we draw our starting line in pencil?

A

This is because, the pen ink could dissolve in the solvent and move up the paper.

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29
Q

What is an electron?

A

A tiny negative particle.

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30
Q

What is the description of the Plum Pudding Model?

A

An atom is a ball of positive charge with negative electrons embedded in it.

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31
Q

What is the alpha scattering experiment?

A

-First the scientists took a piece of gold foil, gold is used as it can be hammered into very thin foil.
-The scientists then fired tiny particles (alpha particles) at the gold foil.
-Alpha particles have a positive charge.
-The scientists found that most alpha particles passed straight through the gold foil without changing direction.
-Sometimes the alpha particles were deflected, in other words it changed direction as it passed through the gold foil.
-And other times the an alpha particle simply bounced straight back off the gold foil.

32
Q

What did the alpha scattering experiment tell the scientists about atoms?

A

-The experiment told scientists the atoms are mainly empty space.
-Which told them the plum pudding model had to be wrong.
-In addition, because some of the alpha particles were deflected this told the scientists that the centre of this atom must have a positive charge.
-And, because some particles bounced back it told the scientists that the centre of an atom must contain a great deal of mass.

33
Q

What model replaced the Plum Pudding Model?

A

The Nuclear Model.

34
Q

What is the description of the Nuclear model?

A

-Most of the atom is simply empty space.
-In the centre of the atom, we have a tiny positive nucleus containing most of the mass of the atom.
-Around the edge of the atom, we have negative electrons.

35
Q

What did scientist Niels Bohr propose about electrons?

A

Niels Bohr proposed that electrons orbit the nucleus at specific distances rather than just in a general area.

36
Q

Why was Bohr’s proposal accepted?

A

It agreed with the results of experiments by other scientists.

37
Q

What do we call the orbits nowadays?

A

We call them energy levels or shells.

38
Q

What did scientists find that the positive charge in the nucleus come from?

A

That it was due to tiny positive particles called protons.

39
Q

What was James Chadwick’s discovery?

A

He discovered that the nucleus also contains neutral particles called neutrons.

40
Q

What is the radius of an atom?

A

0.1 Nanometres / 1 x 10^-10m

41
Q

What is the radius of the nucleus?

A

1 x 10^-14m

42
Q

What is the relative charge and mass of the Proton?

A

Charge: +1
Mass : 1

43
Q

What is the relative charge and mass of the Neutron?

A

Charge: 0
Mass: 1

44
Q

What is the relative charge and mass of the Electron?

A

Charge: -1
Mass: Very Small

45
Q

What is the Atomic Number?

A

The smaller number of an element which tells us the number of protons in that element.

46
Q

What is the Mass Number?

A

The bigger number of an element which tells us the number of protons and neutrons added together in that element.

47
Q

How do you work out the number of neutrons in an element?

A

You subtract the mass number with the atomic number to get the number of neutrons.

48
Q

What is an isotope?

A

Isotopes are atoms of the same element with different numbers of neutrons.

49
Q

What is an ion?

A

-Ions are atoms which have an overall charge.
-That is because ions have lost or gained electrons.
-Positive ions had lost electrons whereas negative ions have gained electrons.

50
Q

How do you calculate relative atomic mass?

A

(mass of number of isotope 1 x % abundance of isotope1)
+
(mass of number of isotope 2 x % abundance of isotope2)
—————————————————————————–
100
= Relative Atomic Mass

51
Q

What is Group 0 called?

A

The Noble Gases

52
Q

What does the word ‘Periodic’ mean?

A

Occurring at regular intervals

53
Q

What does Group 1 consist of metal wise?

A

Highly reactive metals

54
Q

What does Group 7 consist of metal wise?

A

Highly reactive non-metals

55
Q

How did Dmitri Mendeleev develop the first modern periodic table?

A

-He started by arranging all the elements in order of increasing atomic weight.
-But if he needed to, Mendeleev would switch the order of specific elements so they fitted the patterns of other elements in the same group.
-Also, Mendeleev realised that some elements had not been discovered so he left gaps in his periodic table where he thought an elements was missing.
-Mendeleev also predicted the properties of the undiscovered elements based on other elements in the same group which later those missing elements were discovered and they matched the predictions.
-As a result of this, scientists started to accept that Mendeleev’s table was correct.
-He also ordered the elements by atomic weight unlike the atomic numbers nowadays as protons were not discovered back then.

56
Q

What is the problem by ordering elements by atomic weight?

A

Elements can appear in the wrong order due to the presence of isotopes and can put elements in the wrong groups. E.g. Tellurium and Iodine.

57
Q

What group was not fully discovered when Mendeleev published his Periodic Table?

A

Group 0

58
Q

Why are the Noble Gases unreactive?

A

This is because their outer energy levels are full, and atoms are stable when their outer shell is full meaning they will not react. In addition, all Noble Gases have their outer energy levels full making them unreactive.

59
Q

Why do the boiling points of the Noble Gases increase as we go further down the group?

A

Because their relative atomic mass increases.

60
Q

What happens when metals react?

A

-When metals react, they lose electrons to achieve a full outer energy level.
-This give them the stable electronic structure of a group 0 noble gas.
-And Metals always form positive ions.

61
Q

What is Group 1 called?

A

Alkali Metals

62
Q

What happens when Lithium reacts with water?

A

-The Lithium reacts rapidly with the water and we will see effervescence or fizzing telling us that a gas is being produced.
-If universal indicator is used the water will turn purple telling us that an alkaline solution has been produced.

Lithium + Water —-> Lithium Hydroxide + Hydrogen
2Li + H₂0 —-> 2LiOH + H₂

63
Q

What happens when Sodium reacts with water?

A

-The Sodium reacts with the water and we can see a gas being produced and an alkaline solution forming.
-Sodium also reacts more rapidly with water than Lithium.

Sodium + Water —-> Sodium Hydroxide + Hydrogen
2Na + H₂0 —-> 2NaOH + H₂

64
Q

What happens when Potassium reacts with water?

A
  • The Potassium reacts with the water the reaction is extremely rapid and we can see a gas being produced and an alkaline solution forming.

Potassium+ Water —-> Potassium Hydroxide + Hydrogen
2K + H₂0 —-> 2KOH + H₂

65
Q

Why do Group 1 metals get more reactive as they go further down the group?

A

-The radius of the atoms increases as we go further down the group.
-This means there is a greater distance between the positive nucleus and the negative outer electron.
-As this distance increases the outer electron is less attracted to the positive nucleus.
-Secondly, the outer electron is repelled by electrons in the internal energy levels (shielding).
-This decreases the attraction between the nucleus and the outer electron.
-As we move down the group the elements have more electrons in the internal energy levels (Shielding increases).
-And the outer electron is less attracted to the nucleus so its easier to lose.

66
Q

What is Group 7 called?

A

The Halogens

67
Q

How are covalent bonds used with two Group 7 non-metals reacting with each other?

A

-The two atoms, overlap their outer energy levels and they share a pair of electrons.
-This will create the molecule of the element. E.g. F₂, Cl₂

68
Q

What is the Relative molecular mass?

A

It gives us an idea of the size of a molecule.

69
Q

Why does the Relative molecular mass increase as we go further down Group 7?

A

Because the molecules get bigger as we go down the group.

70
Q

What happens when halogens react with metals?

A

They form ionic compounds.

71
Q

Why do the halogens get less reactive as we move down Group 7?

A

-There is an increased distance between the nucleus and the outer electron and increased shielding of the outer electron.
-Which mean that the elements get less reactive.

72
Q

Key Fact:

A

A more reactive halogen can displace a less reactive halogen from an aqueous solution of its salt.

73
Q

(Triple only) What are the properties of the Group 1 metals?

A

-Soft Metals (can be cut with a scalpel)
-Relatively Low melting points
-Low density
-They react rapidly with oxygen, chlorine and water
-Form ions with a 1+ Charge

74
Q

(Triple only) What are the Transition Elements?

A

They are metals located in the middle of the Periodic table.

75
Q

(Triple only) What are the properties of the Transition Elements?

A

-Hard and strong metals.
-High melting points
-High density
-Much less reactive than group 1 metals e.g. with oxygen, chlorine and water
-Can form ions with different charges
-They form coloured compounds (Iron III oxide, Manganese II chloride, Chromium III chloride, Copper II sulfate)

76
Q

(Triple only) What can the Transition Elements be used for?

A

Catalysts