1.6 The Periodic Table Flashcards

1
Q

Who is the scientist who published his periodic table in 1869 and what did he do for elements that weren’t discovered at that time?

A

Mendeleev - he left gaps in order that similar elements would fall in the same vertical column.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What is a group and a period?

A

Group- a vertical columns in the Periodic Table.

Period- a horizontal rows in the Periodic Table.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What are the differences between Mendeleev’s Table and the Modern Periodic Table?

A

Mendeleev’s Table:
-Elements arranged in order of atomic weight
-No noble gases
-Gaps were left for undiscovered elements
-No block of transition elements
-Actinides and Lanthanides not present

Modern Periodic Table:
-Elements arranged in order of atomic number
-Noble gases added
-No gaps (now know all elements)
-A block of transition elements
-Actinides and Lanthanides present

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What is the definition of an element?

A

An element is a substance that consists of only one kind of atom. Elements cannot be broken down into anything simpler by chemical means.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

What are the three physical states of elements?

A

Solid, liquid or gas

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

What do these names given to these changes of state mean? : melting, freezing, evaporation, condensation, sublimation and reverse sublimation.

A

Melting- solid to liquid
Freezing- liquid to solid
Evaporation- liquid to gas
Condensation- gas to liquid
Sublimation- solid to gas
Reverse sublimation- gas to solid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

How can you find out the period and group an element is in due to its electronic structure?

A

Period- the period number is the number of electron shells

Group- the group number is the number of electrons in the outer shell

e.g. Sodium has the electronic figure 2,8,1
-this means sodium is in group 1 and period 3

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Describe groups 1,2,7,0 and the transition metals

A

Group 1- the alkali metals are a group of highly reactive metals.
Group 2- the alkaline earth metals are a group of reactive metals.
Group 7- the halogens are a group of reactive non-metals
Group 0- the noble gases are a group of unreactive non- metals
The transition metals are a block of metals between Group 2 and Group 3

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Describe the trends in groups 1,2,7 and 0

A

Group 1- as we move down group one, the reactivity increases and the melting and boiling points decrease
Group 2- as we move down group two, the reactivity increases and the melting and boiling points decrease (not as reactive as Group 1)
Group 7- as we move down group seven the reactivity decreases and melting and boiling points increase
Group 0- the noble gases elements are unreactive since they have 8 electrons in their outermost shell and so do not need to react to achieve a stable electron structure. As we move down the group the density of the gases increases.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Describe the trends as you move left —> right across period 3

A
  1. The number of outer shell electrons increases by 1 each time.
  2. Each time you start a period; you start a new electron shell.
  3. Elements go from metals to non-metals. Silicon is in between and is called a semi-metal or metalloid.
  4. Melting/Boiling Points increase to the middle of the Period then decrease again. They are lowest on the right.
  5. All elements except argon react with oxygen to form oxides.
  6. Metal oxides are basic
    Non-metal oxides are acidic
    Aluminium oxide is both acidic and
    basic
    It is called an amphoteric oxide.
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

What are the safety considerations for reacting alkali metals with water?

A
  • Do not handle the metals- use forceps/gloves this prevents the metals reacting with your hands.
  • Wear safety glasses- to prevent eye damage for the metals or the products of the reactions.
  • Use a safety screen and stand back - prevents metal hitting your skin if it explodes.
  • Use small quantities of the metals - reduces explosive risk.
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

What are the general observations when alkali metals react with water?

A

Floats; moves on surface; bubbles of gas; metal gets smaller and disappears; heat produced and colourless solution left.

Note: Na and K also melt; only K burns

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Why are the alkali metals stored in oil and what happens to the reaction of the alkali metals with water as you descend the group?

A

-To prevent contact with moisture and oxygen in the air which they would react.
-The alkali metals react more vigorously with water as the group is descended.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Describe the appearance of lithium, sodium and potassium

A
  • Fresh surface is silvery grey with metallic lustre (shiny).
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Why does the reactivity of Group 1 metals increase as you move down the group?

A

-When a Group 1 atom reacts it loses an electron from its outer shell to form a positive ion with a full outer shell.
-Going down the group the atoms get bigger due to there being more shells of electrons. As a result, the outer electron is further away from the positive charge of the nucleus. This means that the outer negative electron is less strongly attracted to the positive nucleus, and so easier to lose. The easier the electron is to lose, the more reactive the alkali metal.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Describe the appearance of Group 1 compounds

A

Most Group 1 compounds are white and dissolve in water to give colourless solutions.

17
Q

What is the state and colour of fluorine, chlorine, bromine and iodine at room temperature?

A

Fluorine- pale yellow gas
Chlorine- pale green gas
Bromine- red-brown liquid
Iodine- grey-black solid

18
Q

What is the definition of sublimation?

A

Sublimation is the change from solid to gas on heating and from gas to solid on cooling, without passing through the liquid state.

19
Q

What is the test for chlorine?

A

Chlorine gas changes damp universal indicator paper from pale green to red and then bleached it (turns white). It turns damp blue litmus paper to red and then bleached it white.

20
Q

What is the equation for the formation of chlorine water and how is chlorine used in the treatment of drinking water?

A
  • Cl2 (g) + H2O (l) —> HCl (aq) + HCIO (aq)
  • A minimal amount of chlorine is added, to kill any bacteria, and so sterilise the water making it safe to drink.
21
Q

What are the conclusions to the displacement reactions of Group 7?

A

-Chlorine is able to displace both bromine and iodine from their compounds.
-Bromine is able to displace iodine.
-Iodine cannot displace any of the halogens above it from their compounds.

22
Q

What happens when halogen atoms react?

A

Atoms of Group 7 are reactive non-metals. They all have seven electrons in their outer shell and need to gain one electron to gain a full outer shell. When they gain an electron, they form a negative ion with a stable electron configuration.

23
Q

Why does the reactivity of the halogens decrease as you move down the group?

A

The outer shell is further from the attraction of the positive nucleus so it is more difficult to attract the incoming electron.

24
Q

What is the appearance and trend in boiling points for the noble gases?

A

Appearance- they are all colourless gases.

Trend in boiling points- increase in boiling points because of the strength of the van der Waal’s forces increases.

25
Q

What are the differences in melting point, density, reactivity with water, formation of ions and colour of compounds in the alkali metals and the transition metals?

A

Alkali metals:
Melting point- low
Density- low
Reactivity with water- very reactive with cold water producing a metal hydroxide and hydrogen.
Formation of ions: react to form 1+ ions.
Colour of compounds: form white compounds e.g. sodium chloride is white.

Transition metals:
Melting point- high (except mercury)
Density- high
Reactivity with water- low reactivity: iron rusts. Some react with steam producing a metal oxide and hydrogen.
Formation of ions: react to form ions with different charges.
Colour of compounds: form coloured compounds e.g. hydrated copper (II) sulfate is blue.

26
Q

What are the observations for the experiment to investigate the colours of copper compounds?

A

Heating copper (II) carbonate- the green solid turns, with gentle heating, to a black solid (copper (II) oxide).
Addition of dilute sulfuric acid- the black solid reacts on warming forming a clear blue solution.
Appearance after evaporation- blue crystalline solid (hydrated copper (II) sulfate).

27
Q

What are the balanced chemical equations for the heating of copper (II) carbonate and the addition of dilute sulfuric acid?

A

Heating copper (II) carbonate: CuCO3 (s) —> CuO (s) + CO2 (g)

Addition of dilute sulfuric acid: CuO (s) + H2SO4 (aq)
—> CuSO4 (aq) + H2O (l)

28
Q

What are the conclusions to the experiment to investigate the colours of copper compounds?

A

Copper (II) compounds are coloured. They are normally blue, green or black. If blue hydrated copper (II) sulfate crystals are heated they change to anhydrous copper (II) sulfate which is a white powder.