2 Flashcards

1
Q

Briefly describe the waste minimisation hierarchy

A

The options for waste management are often arranged in this hierarchical manner to reflect their desirability. The aim of the hierarchy is to extract the maximum benefits from materials whilst generating the minimum amount of waste.
The first priority is waste prevention or reduction – that is, not producing the waste in the first place. If waste is produced then this should be minimised. The next priority is maximising reuse or recycling and recovery of suitable waste materials. Once the possibility of waste prevention have been exhausted then the next option is treatment, to reduce the volume of waste, to neutralise or render the waste harmless, to extract resources in the form of products and/or energy. The final option – and least desirable - is to dispose of the waste either to the air, water or land.

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2
Q

A circular economy is one that exchanges the typical

A

A circular economy is one that exchanges the typical cycle of make, use, dispose in favour of as much reuse and recycling as possible. The longer materials and resources are in use, the more value is extracted from them. This could contribute toward reducing Europe dependence on critical materials such as cobalt, fluorspar or gallium, but also reduce overall demand by recovering the resources, nutrients or energy contained in products at the end
of their useful life.
Extending the life of products and materials
prevents the over generation of waste and recovers the full value of products. This would create new business opportunities and revenue streams, while minimising the environmental impact of mining, resource extraction, refining and manufacture.

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3
Q

Ways to achieve waste avoidance/minimisation

A

1- Product design change:
Product design with less waste
Increase product life
2- Package change:
Reusable or recyclable pack, concentrate
3- Materials change:
Substitution of less toxic materials
4- Technological change:
Improved/more efficient equipment
5- Management practices:
Good housekeeping, inventory control

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4
Q

Solid waste hazards

A
  • Human pathogens
  • Insects & rodents
  • Animal pathogens
  • Leaching
  • Odour
  • Soil pathogens
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5
Q

Sources and types of solid waste

A
  • Domestic:
    Food
    Paper
    Packaging
    Glass
    Metal
    Ashes
    Bulky household waste
    Hazardous household waste
  • Commercial:
    Food
    Paper
    Packaging
    Glass
    Metal
    Ashes
    Bulky household waste
    Hazardous household waste
  • Industrial:
    Industrial process wastes
    Metals
    Lumber
    Plastics
    Oils
    Hazardous wastes
  • Construction and demolition:
    Soil
    Concrete
    Timber
    Steel
    Plastics
    Glass
    Vegetation
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6
Q
  1. Explain duty of care with respect to solid waste.
A

Industry and other businesses have a duty of care when it comes to waste. This means that the producer’s responsibility for waste does not end at the factory gate. This duty is placed on anyone who imports, produces, carries, keeps, treats or has control of waste (this excludes domestic waste).

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7
Q

Waste management legislation

A

2008 EU Waste Framework Directive

2011 Waste (England and Wales) Regulations

2007 Environmental Permitting Regulations

2010 Industrial Emissions Directive (IED)

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8
Q

Permit authorises treatment, keeping or disposal of controlled waste in
or on specified land

A

1996 Special Waste Regulation

2005 Hazardous Waste Regulations

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9
Q

Waste minimisation hierarchy applied to solid
waste

A
  • Reduction at source: Don’t produce it in the first place!
  • Recycling/reuse: Recycling
  • Treatment: Biological, Combustion, Gasification
    Pyrolysis (With/without Energy recovery)
  • Disposal: landfill
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10
Q

Chemical and energy properties

A
  • Proximate analysis:
    Moisture content
    Volatile matter
    Fixed carbon
    Noncombustible fraction (ash)
  • Ultimate analysis
    Carbon
    Hydrogen
    Oxygen
    Nitrogen
    Sulphur
    Ash
  • Energy content MJ/kg
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11
Q

Solid waste treatment options

A

1- Recycle
2- Biological
*Composting or aerobic
*Biogas or anaerobic
* Combined aerobic and anaerobic
3- Thermal
*Combustion
*Gasification
*Pyrolysis
* Energy from waste
4- Landfill

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12
Q

Recycling example

A

Paper & cardboard
Glass
Aluminium cans
Plastics
Textiles
Batteries
Plus lots more!

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13
Q

what is Biological treatment

A

Used to treat the organic fraction of waste
Reduces volume
Valuable products/energy
Waste becomes inert

3 options:
Aerobic composting

Anaerobic to generate biogas

Combined anaerobic and aerobic

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14
Q

for Composting what are the process parameters

A
  • Temperature
  • Moisture content
  • Oxygen
  • C/N ratio
  • pH
  • Biochemical composition and texture
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15
Q

Composting systems

A

Windrow
In vessel
Aerated static pile

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16
Q

Issues with composting

A
  • Heavy metals
  • Odour
  • Sterilisation
  • Inert contaminants
17
Q

Anerobic digestion process parameters

A
  • Oxygen free
  • Stages
    *Hydrolysis
    *Acidogenisis
    *Methanogenesis

-Temperature control is important

  • Biogas can be used as a fuel
18
Q

AD examples

A

GWE Biogas Ltd
*50,000 tonnes organic waste
*Local authorities, food manufacturers
and supermarkets
*Generate 2 MW electricity for export to
grid

Staples Vegetables
- Out of spec vegetables
- Electricity used on site or exported to grid
- Excess heat used to heat offices and buildings

19
Q

Thermal treatment types or options

A
  • Incineration (combustion)
  • Gasification
  • Pyrolysis

( Waste to energy)

20
Q

Incineration process parameters

A

*Complete oxidation at high temperature

*Organic material is converted into heat, flue gas
and ash

IED sets stringent requirements:
*Minimum combustion temperature 850 C
for 2 seconds
*Specific emission limits for SO 2 , NO x , HCl,
CO, Total Organic Carbon (TOC)
*Ash to have organic carbon content < 3%

*Thermal efficiency up to 80- 90%

*Electricity generation ~ 27%

21
Q

Incineration technology

A

Moving grate (most common type)
Fixed grate
Fluidized bed
Rotary kiln

22
Q

Main factors that influence emissions from waste incinerators:

A

*Composition of the waste
*Combustion control
*Mechanical processes

23
Q

To control emissions:

A

*Combustion conditions for CO, VOCs and dioxins
*Ammonia injection for NO x
*Lime injection for SO 2 and HCl
*Carbon injection for capture of heavy metals
*Filter system for fly ash and other solids

24
Q

Gasification process parameters

A

*Thermal decomposition in the presence of a controlled amount of oxygen and/or steam
*Process occurs at high temperature (> 700 C)
*Produces syngas (carbon monoxide, hydrogen and some carbon dioxide)
*Gas can be used directly in engines to generate electricity

25
Q

Gasification equipment

A
  • moving bed gasifier
  • fluidized bed gasifier
  • entrained flow gasifier
26
Q

what is Pyrolysis

A

Thermal conversion of waste in the absence of oxygen

27
Q

what are Pyrolysis types and products

A

Three types:
-Slow
-Intermediate
- Fast
Products:
*Pyrolysis liquid
*Char
*Gas

28
Q

Landfill random facts :)

A

*Last resort
*UK running out of landfill capacity
* Most landfill sites control and collect gas

29
Q

what is our biggest waste challenge?
What can we do? as As individuals, and As engineers?

A

plastics

As individuals
*Reduce consumption
*Reuse /recycle

As engineers
*New ways to re use plastics
*Develop biodegradable plastics
*Improve plastic recycling processes
*Reduce the amount of plastic used in processes

30
Q

A farmer is interested in developing an energy from waste plant to deal with the farm’s organic waste. What are the options? What would you recommend and why?

A

There is no single correct answer to this question. You should present the options available with a short description of each, with advantages and disadvantages. Then choose and justify a process for the farm’s organic waste