2 Flashcards
(16 cards)
BV oxidation me kya Hota hai
MCPBA ketone ko Ester me change krta hai
DMDO USES WHEN
Ketone or alkene given ek sath
Then it only oxidised alkene means not show BVO
But with mcpba oxidised both
How to prepare DMDO
KhSO5 + acetone
S–Ylide type
2
Soft
Hard
Soft wala bada hai to
Neeche se attack karega
MCPBA small hai ya large
Small hai to epoxidation uper( axially) hoga
C==O ko c==c me kaise change kre
C==C ko c==o me kaise change kre
Witting reagent
Oonolysis
What is dihydroxidation
Formation of diol
S ylide wala kya wo sabhi alkene ko cyclo propane ring Bana Pata Hai
Bikul nhi
Ye kewal alpa beta unsaturated alkene ko he banana hai
Trans diol banana ke liye kya karte hai
Epoxidation then hydrolysis
Cis diol banana ke liye koine sa reagent use karte hai
OSO4,KMnO4
Hydrogen bonding koine sa atom paneled karta haai
N>O>F
TMEDA
Tetra methyl ethane di amine
It a base
And chelating solvent
OSO4=
OSO4+TMEDA=
No hydrogen bonding
Hydrogen bonding occur
m CPBA KIS SOLVEVNT ME HYDROGEN BONDING DIKATA HAI AUR KISME NHI
DCM (CH2CI2) ME DIKATA HAI
ETHER ME NO
Ether paneled he hydrogen bonding kar leta hai oh group se isliye
Agr Na in liquid. NH3 aur solvent aisa ho jo Polar protic ho to
H+ available Hota hai