2. bonding and structure (as) Flashcards

(44 cards)

1
Q

ionic bonding

A

strong electrostatic attraction between oppositely charged ions

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2
Q

ionic bonding involves

A

the transfer of electrons from a metallic element to a non metallic element

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3
Q

ionic solids structure

A

ions in a lattice are arranged in a regular repeating pattern

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4
Q

ionic radius def

A

measure of the size of an ion

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5
Q

ionic radii increases with
ionic radii decreases with

A

increasing negative charge
increasing positive charge

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6
Q

negative ions formed by

A

atoms gaining electrons

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7
Q

isoelectronic ions

A

ions that have the same electronic configuration

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8
Q

the type of lattice formed depends on

A

the sizes of positive and negative ions which are arranged in alternating fashion

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9
Q

why are most ionic compounds are solids at room temp

A

there isn’t enough energy to overcome the strong electrostatic forces of attraction between oppositely charged ions that make up the lattice

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10
Q

ionic compounds require to melt

A

high temperatures required to make an ionic compound melt or boil

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11
Q

electrical conductivity of ionic compounds

A

in solid they cannot conduct electricity

but molten or aqueous ions they have ions that can move and carry charge

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12
Q

things that affect the strength of an ionic bond

A

ionic charge
ionic radii increases

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13
Q

ionic charges affects ionic bond how

A

greater charge of ion stronger the ionic bond ,, higher mp/bp

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14
Q

ionic radii explain how it affects ionic bond

A

smaller ions can be packed closer together than larger ions electrostatic attraction gets weaker with distance ,, small, closely packed ions have stronger ionic bonding

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15
Q

what happens to ionic radii down a group

A

ionic radii increases

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16
Q

what happens when isoelectronic ions ionic radii as atomic number increases

A

ionic radii decreases

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17
Q

physical properties of ionic compounds

A
  • high mps-
  • soluble in water but not in non polar solvents
  • don’t conduct electricity when solid
  • brittle
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18
Q

migration of ions evidence for charged particles

A
  • copper (II) chromate (VI) solution is green on a piece of filter paper
  • cathode- filter paper is blue because copper ions- pos ions
  • anode- filter paper is yellow because of chromate ions- neg ions
19
Q

covalent bonds

A

strong electrostatic attraction between two positive nuclei and the shared electrons in the bond

20
Q

bond length

A

distance between the attractive and repulsive forces that balance each other between two nuclei

21
Q

relation between bond enthalpy and bond length

A

the greater the bond enthalpy the shorter the bond

22
Q

dative covalent bonding

A

one atom donates both electrons to a bond

23
Q

structure of diamond and silicon (IV) dioxide

A

each carbon atom bonded to 4 other and silicon is similar but has oxygen atoms between silicon

24
Q

properties of giant structure w covalent bonds

A

high mp
hard
good thermal conductors
insoluble-
can’t conduct electricity-

25
why can graphite conduct electricity
3 carbon atoms covalently bonded ,, one free electron ,, carry charge
26
graphene structure
- sheet of graphite - joined together hexagonal - one atom thick - two dimensional - conducts electricity - strong - transparent - light
27
metallic bonding
positive metal ions electrostatically attracted to the delocalised negative electrons forming a lattice of closely packed ions in a sea of delocalised electrons
28
metals structure
- high melting point - malleable/ ductile - good thermal conductors- - good electrical conductors- - insoluble
29
what affects metallic bond
- number of electrons - size of metal ions - charge of metal ions
30
electronegativity def
the ability of an atom to attract the bonding electrons in a covalent bond
31
most electronegative element
fluorine
32
do ionic compounds have high mp? and why
strong attraction between ions
33
are ionic compounds soluble and why
soluble in water but not non polar solvents-tells you that particles are charges ions pulled apart by polar molecules like water
34
do ionic compounds conduct electricity
- don’t conduct electricity when solid- ions not free to move
35
are ionic compounds brittle and why
yes they are brittle bcs if layers pulled same charged ions could be above each other ,, repulsion would be strong
36
does giant structure w covalent bond have high mp + explain
require a lot of energy to break bonds
37
giant structure w covalent bond hard+ explain
strong bonds through lattice
38
is giant structure w covalent bond good thermal conductors + explain
vibrations travel easily through lattice
39
are giant structure w covalent bond insoluble + explain
covalent bonds are more attracted to their neighbours in lattice than solvent molecules. don’t have ions bcs insoluble in polar solvents
40
does giant structure w covalent bond conduct electricity + explain
no charged ions/ free electrons
41
does metal structure have high melting point + explain
- strong metallic bonds
41
is metal structure malleable/ ductile + explain
metal ions can slide over each other without disrupting attraction between pos ions + e
42
is metal structure a good thermal conductors/electrical conductors + explain
delocalised e can pass KE to each other
43
is metal structure insoluble + explain
strength of metallic bonds