2. Structure And Bonding Flashcards

(50 cards)

1
Q

What are the three different types of bonding in compounds?

A

Ionic, covalent and metallic

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2
Q

Between which particles does ionic bonding occur?

A

Between a metal and a non-metal, e.g. sodium chloride

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3
Q

Between which particles does covalent bonding occur?

A

Between 2 non-metal atoms which share pairs of electrons

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4
Q

Between which particles does metallic bonding occur?

A

Between metal atoms and in alloys

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5
Q

How is a metallic bond formed?

A

By the attraction between positively charged metal ions and the sea of delocalised electrons that are free to move throughout the structure

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6
Q

How does ionic bonding work?

A

Positive and negative ions are formed when a metal reacts with a non-metal and transfers electrons, the oppositely charged ions are strongly attracted to each other, forming ionic bonds

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7
Q

How are ionic compounds arranged?

A

In giant ionic lattices

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8
Q

How can ionic bonding be shown as a diagram?

A

Using a dot and cross diagram

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9
Q

What are the forces between ions called?

A

Electrostatic forces

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10
Q

How do the forces between ions act and what does this mean?

A

The electrostatic forces act in all directions and are very strong meaning the ions are held together very tightly

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11
Q

Why do ionic compounds have high melting and boiling points?

A

There are many strong ionic bonds to break which requires a lot of energy as to separate the ions you have to overcome the electrostatic forces of attraction acting in all directions and

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12
Q

What are the advantages and disadvantages of using 3D models to represent ionic compounds?

2D & 3D Space filling models? BBC Bitesize

A

Advantages:
Provides a clear and spatial representation of ions, easier to understand

Disadvantages:
Can be complex, doesn’t show electron transfer, doesn’t show how the next layer of ions is arranged

BBC Bitesize - 3D space-filling model shows lots of free space between ions which there isn’t

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13
Q

What are the advantages and disadvantages of using the ball and stick model to represent ionic compounds?

A

Advantages:
Shows the arrangement of ions in a larger section of the crystal

Disadvantages:
Does not accurately show the distances between ions which leads to misinterpretations of the relative sizes of ions, using sticks for bonds is misleading as the forces of attraction acting in all directions

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14
Q

Can ionic compounds conduct electricity?

A

If it is a liquid or has dissolved in water to form an aqueous solution

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15
Q

How does metallic bonding work?

A

The electrons from the outer shells of metal atoms are delocalised and free to move throughout the structure, and the sharing of these delocalised electrons results in strong metallic bonding

  • The metallic bond is the attraction between the positive metal particles and negative delocalised electrons
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16
Q

Why can metals conduct electricity?

A

Their delocalised electrons carry charge throughout the metal

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17
Q

Why are metals good conductors of thermal energy?

A

Their delocalised electrons transfer energy

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18
Q

Why do metals have high melting and boiling points?

A

The metallic bonding in the giant structure of a metals is very strong and large amounts of energy is needed to overcome the metallic bonds

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19
Q

Why are metals malleable and ductile?

A

In pure metals, the atoms are arranged in neat layers, so when a force is applied the layers if metal atoms can slide over each other

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20
Q

Why are alloys harder than pure metals?

A

They are harder than pure metals as there are different sizes of atoms and the bigger atoms disrupt the layers of a pure metal, meaning more energy needs to be applied for the layers to slide over each other

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21
Q

What is covalent bonding?

A

When non-metal atoms share pairs of electrons

22
Q

What are the forces between molecules in covalent structures?

A

Weak intermolecular forces

23
Q

How strong are covalent bonds?

24
Q

What are the different types of covalent bonds?

A

Single covalent bonds where the bond contains one pair of electrons

Double covalent bonds where the bond contains two pairs of electrons and so on

25
What are giant covalent structures?
Substances that consist of a large network of atoms connected by strong covalent bonds
26
What are 3 features of giant covalent structures?
- They have very high melting and boiling points - They are insoluble in water - They are hard and do not conduct electricity (EXCEPT GRAPHITE)
27
What are simple covalent structures?
Small molecules joined by covalent bonds. The individual molecules are held together by weaker intermolecular forces and therefore have lower melting and boiling points
28
What are diamond and graphite?
Different forms of carbon
29
What is the structure of diamond?
A giant covalent structure where each carbon atoms is joined to 4 other carbon atoms and has no free electrons
30
What does the structure of diamond mean?
Diamond is very hard, has a very high melting point and does not conduct electricity
31
What is the structure of graphite?
- A giant covalent structure where each carbon atoms forms 3 covalent bonds with other carbon atoms - The carbon atoms form layers of hexagonal rings - There are no covalent bonds between the layers - There is one delocalised electron from each atom
32
What are some properties of graphite and why?
- Can conduct electricity as it has delocalised electrons - The layers can slide over each other as the forces between layers are weak. This makes graphite slippery so can be used as a lubricant
33
What are some limitations of the particle model?
- Doesn’t show forces - Particles are not spheres in reality - The spheres look solid which they are not in reality
34
If the bonds between particles are stronger, what does this mean for the melting and boiling points?
They are higher
35
What happens when ionic compounds are put in water?
They dissolve and the ions are free to move throughout the water - can now conduct electricity
36
What happens when simple molecules boil/melt?
The weak intermolecular forces break, not the covalent bonds
37
Do simple molecular compounds conduct electricity? Why?
They do not conduct electricity as they have no charged particles that can carry charge
38
What are some examples of simple molecular substances?
Water, Carbon Dioxide, methane
39
Is graphite soft or hard? Why?
Soft as the layers can slide over each other
40
What is graphene?
A single layer of graphite
41
What are some properties of graphene and what does this mean?
- Has a very high melting point - Is very strong - Is flexible Can be used in electronics - in batteries to allow for a longer lifespan and higher capacity and make them flexible - in touchscreens as well as less resistance than current material
42
What are fullerenes?
Molecules of carbon atoms with hollow shapes
43
What is Buckminsterfullerene?
A spherical molecule made up of 60 carbon atoms joined with strong - Chemical symbol of C60 covalent bonds - Slippery and has a low melting point
44
What are nanotubes?
Carbon nanotubes are cylindrical fullerenes with a very high length to diameter ratio - They are very small - They are good conductors of heat and electricity - They have a high tensile strength
45
What are graphite, diamond, fullerenes?
Allotropes of carbon
46
What are polymers?
Structures that have very long molecules in which the atoms are joined by string covalent bonds in long chains
47
What are some uses of nano particles?
- In sun cream: nano particles help to reflect UV rays from the skin - Deodorants: nano particles clog the sweat glands to stop sweating - In electronics: decrease weight and power consumption
48
How do you calculate the surface area to volume ratio?
Surface area / volume
49
Why can nanoparticles be used as catalysts?
They have a large surface area to volume ratio
50
What are some risks of using nanoparticles?
They might catalysts reactions that are harmful Toxic substances could bind to them as they have such a large surface area to volume ratio and then harming health if the nanoparticles do get into the body E.g. hazard of using silver nanoparticles to the environment if it is used in wound dressings the nanoparticles could kill useful bacteria in the environment when dressings are thrown away