2.1 Flashcards

1
Q

Initial rate of reaction

A

The change in concentration of a reactant or product per unit time at the start of the reaction when t=0

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2
Q

Order with respect to reactant

A

The power which the concentration of the reactant is raised in the equation

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3
Q

Rate constant,K

A

The constant that links the rate of reaction with the concentrations of the reactants raised to the powers of their orders in the rate equation.

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4
Q

Half-life

A

The time taken for the concentration of the reactant to reduce by half

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5
Q

The rate-determining step

A

The slowest step in the reaction mechanism of a multi-step reaction

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6
Q

An intermediate

A

A species formed in one step of a multi-step reaction that is used up in a subsequent step, and is not seen as either a reactant or a product of the overall equation.

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7
Q

Rate of reaction

A

The change in concentration of a reactant or a product per unit time.

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8
Q

A dynamic equilibrium

A

Happens in a closed system when the rate of the forward reaction is equal to the rate of the reverse reaction.

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9
Q

A homologous equilibrium

A

An equilibrium in which all the species making up the reactants and products are in the same physical state

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10
Q

A heterogenous equilibrium

A

An equilibrium where the species making up the reactants and products are in different physical states

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11
Q

A Brønsted-Lowry base

A

Is a proton, H+, acceptor

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12
Q

A Brønsted-Lowry acid

A

Is a proton,H+, donor

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13
Q

An alkali

A

A base that dissolve in water forming OH- ions

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14
Q

Neutralisation

A

A chemical reaction where an acid and base react together to produce a salt and water

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15
Q

An acid-base pair

A

A pair of two species that transform into each other by gain or loss of a proton

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16
Q

A strong acid

A

An acid that completely dissociates in solution

17
Q

A weak acid

A

An acid that partially dissociates in solution

18
Q

A buffer solution

A

A mixture that minimises pH changes on addition of small amounts of acid or base

19
Q

The equivalence point

A

The point in a titration at which the volume of one solution had reacted exactly with the volume if the second solution

20
Q

The end point

A

The point in a titration when there are equal concentrations of the weak acid and conjugate base base forms of the indicator

21
Q

The standard enthalpy change of neutralisation

A

The energy change that accompanies the neutralisation of an aqueous acid by an aqueous base to form one mole of H2O under standard conditions