2.1.1-Atomic structure and isotopes Flashcards
(27 cards)
relative isotopic mass
mass of an isotope compared to 1/12th of mass of an atom of carbon-12
relative atomic mass-Ar
weighted mean mass of an atom of an isotope compared to 1/12th of mass of an atom of carbon-12
what does the weighted mean mass take into account
-mass of each isotope
-percentage abundance of each isotope
-so number in periodic table
relative molecular mass use
in covalent molecules
relative formula mass
for ionic compounds and other giant structures
how to calculate relative molecular or formula masses
adding all the Mr’s
isotopes
atoms of the same element with the same number of electrons and protons but different number of neutrons and different masses
describe why isotopes have similar chemical properties
-have same number of electrons in their shells
-as an atom of that element and their arrangement is same
what is the standard element that all elements are compared to
carbon-12
use of mass spectrometer
to determine the relative isotopic masses and relative abundances of isotopes
relative molecular mass-Mr
the mean mass of a molecule compared to 1/12th of mass of an atom of carbon-12
Atom economy for each reaction type
addition reaction -100 percent
substitution -less
elimination-less
decomposition reaction
one reactant broken apart into multiple reactions
detector in mass spectrometry
-electric or photographic detection methods
how are percentage abundances in isotopes found w mass spectrometer
1-sample placed in mass spec,vapourised to form +ve ions
2-ions accelerated-heavier move more slowly and difficult to detect so ions of different isotopes separated
3-ions detected as a mass to charge ratio-m/z
greater the abundance he greater the signal
How to calculate number of protons neutrons and electrons for neutral atoms and ions?
neutral atoms
number of elec=number of protons
number of neutrons =mass number - atomic number
ions
number of electrons less than number of protons-+
number of electrons more than number of protons- -
charges affect ions
how to get moles of unkown chemical
mole ratio
how to work out relative formula or molecular mass?
add up all the mass numbers
limiting reagent vs excess reagent
limiting reagent
-limits maximum/theoretical amount of product that can form
-is the reacttant totally used up in a reaction
excess reagent
-has some left over after reaction
mass number and atomic number
mass number = number of protons and neutrons
atomic number= number of protons
solute and solvent
solute-substance being dissolved
solvent-dissolved in most commonly H2O
state equation for hydrated salt CuSO4 .5 H2O being heated
CuSO4 .5 H2O ———- CuSO4 + 5H2O
-when hydrated salts are heated,the water driven off and compound left is referred to as the anhydrous salt
state why group 0 do not form ions
-noble gases are non metals
-already have full outer energy level which other atoms strive to have.
what does mass spectrometer consist of
ion source
analyser
detector