2.1.4 - Acids Flashcards

(59 cards)

1
Q

What is the general reaction of an acid and a base?

A

Acid + Base → Salt + Water

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2
Q

What is formed when acids react with alkalis?

A

Acid + Alkali → Salt + Water

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3
Q

What is the reaction between an acid and a carbonate?

A

Acid + Carbonate → Salt + Water + CO₂

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3
Q

What is formed when acids react with metal oxide?

A

Acid + Metal Oxide → Salt + Water

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3
Q

What is formed when acids react with metal?

A

Metal + Acid → Salt + Hydrogen

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3
Q

Give an example reaction between sulfuric acid and sodium hydroxide.

A

H₂SO₄ + 2NaOH → Na₂SO₄ + 2H₂O

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3
Q

Give an example reaction between hydrochloric acid and sodium hydroxide.

A

HCl + NaOH → NaCl + H₂O

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4
Q

Give an example reaction between hydrochloric acid and sodium carbonate.

A

2HCl + Na₂CO₃ → 2NaCl + CO₂ + H₂O

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4
Q

Give an example reaction between hydrochloric acid and calcium carbonate.

A

2HCl + CaCO₃ → CaCl₂ + CO₂ + H₂O

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4
Q

What ions do alkalis release in aqueous solution?

A

Hydroxide ions (OH⁻).

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4
Q

Give examples of common alkalis.

A

Sodium hydroxide (NaOH), potassium hydroxide (KOH), aqueous ammonia (NH₃).

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4
Q

What is an alkali?

A

A base that is soluble in water, to form aqueous hydroxide ions.

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4
Q

What is meant by a proton in acid-base chemistry?

A

A hydrogen ion (H⁺), which is essentially a proton.

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5
Q

What is an acid in terms of ions?

A

A substance that releases hydrogen ions (H⁺) in aqueous solution.

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5
Q

What is the definition of an acid?

A

Proton Donor

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5
Q

What are the 3 types of bases?

A

Metal oxides, metal hydroxides, and ammonia.

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5
Q

What is the definition of a base?

A

A substance that neutralises an acid to form a salt.  Proton acceptor

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5
Q

What is the reaction of HCl with ammonia?

A

HCl + NH₃ → NH₄Cl

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5
Q

What is the reaction of HCl with ammonia?

A

HCl + NH₃ → NH₄Cl

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6
Q

What base is used to treat acid ingestion?

A

Magnesium Hydroxide

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6
Q

What is a salt?

A

A compound formed when the H⁺ of an acid is replaced by a metal ion or NH₄⁺.

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6
Q

What are examples of acids?

A

HCl, H₂SO₄, CH₃COOH

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6
Q

What is meant by complete dissociation of an acid?

A

All the acid molecules donate their protons (H⁺) in water – this is a strong acid.

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7
Q

What is meant by partial dissociation of an acid?

A

Only some of the acid molecules donate protons – this is a weak acid.

8
Which acids are strong acids?
Hydrochloric acid (HCl), sulfuric acid (H₂SO₄), nitric acid (HNO₃).
9
Which acids are weak acids?
Ethanoic acid (CH₃COOH), carbonic acid (H₂CO₃).
10
What is meant by “conjugate acid-base pairs”?
Two species that differ by a single proton (H⁺).
11
Give an example of a conjugate acid-base pair.
HCl / Cl⁻ or NH₄⁺ / NH₃.
12
What is the method for an acid-base titration?
1. Fill burette with acid, pipette alkali into conical flask. 2. Add indicator. 3. Titrate acid into alkali until endpoint is reached (colour change). 4. Repeat for concordant results.
13
What indicators are used in titration?
Phenolphthalein and methyl orange.
14
What colour change does phenolphthalein show?
Pink in alkali, colourless in acid.
15
What colour change does methyl orange show?
Yellow in alkali, red in acid.
16
Why is a white tile placed under the conical flask in titrations?
To help see the colour change more clearly.
17
How should results from a titration be recorded?
In a results table with initial and final burette readings to two decimal places.
18
What is a concordant result in titrations?
Two titres within 0.10 cm³ of each other.
19
What is the purpose of a rough titration?
To estimate where the endpoint is so future titrations are more accurate.
20
Why is only a single indicator used in titrations?
To produce a clear, sharp colour change at the endpoint.
21
What are the safety considerations during titrations?
Wear goggles and gloves, treat unknown chemicals as toxic, rinse spills.
22
What’s the correct way to calculate mean titre?
Only average concordant results (within 0.10 cm³ of each other).
22
Why do we rinse the pipette and burette before use?
To prevent contamination or dilution affecting concentration.
22
What is meant by ‘titre’?
The volume of acid required to neutralise the alkali.
23
Does rinsing with water affect titration results?
No, water does not react or affect the number of moles.
23
Why is distilled water used during titrations?
To rinse the sides of the flask, ensuring all acid and alkali react.
24
What is percentage uncertainty?
% uncertainty = (uncertainty ÷ quantity measured) × 100.
24
What is the difference between a reading and a measurement?
Reading = 1 judgement (e.g. thermometer) Measurement = 2 judgements (e.g. burette).
24
Why is it important to remove air bubbles from the burette tap?
Air bubbles can cause inaccurate readings and affect titre.
25
What are assumed uncertainties for instruments if not stated?
Analogue: ±0.5 of smallest division; Digital: ±1 in last digit.
25
How do you reduce percentage uncertainty in weighing?
Weigh larger masses or use a more precise balance.
26
How do you reduce uncertainty in titration?
Use more concentrated acid/base or larger volumes.
27
What’s a common titration question for vinegar?
Find concentration of ethanoic acid in vinegar using NaOH and titration – answer = 64.8 g dm⁻³.
28
How do you determine the % of CaCO₃ in a tablet?
React tablet with excess HCl, titrate leftover HCl with NaOH, calculate reacted acid → % CaCO₃ = 87.9%.
29
How do you identify an unknown metal in M₂CO₃?
Use titration data to find Mr → determine metal identity (e.g., K⁺).
30
How do you calculate % difference from actual value?
(Actual − Experimental) ÷ Actual × 100.
31
How do you justify if a % error is acceptable?
Compare % difference with % uncertainty of apparatus used.
32
What are amphoteric substances?
Substances that can act as acids and bases.
33
How are ammonium salts formed?
When acid reacts with aqueous ammonia.
34
What are hydrated crystals?
A crystalline structure containing water
35
What are anhydrous crystals?
A crystalline structure that contains no water
36
What does a dot formula indicate?
The amount of water present in a crystalline structure.