Chapter 17.1 Flashcards

0
Q

Define heat

How does it flow and what is used to measure it

A

Sum total of the KE of all particles in a sample of matter

Flows from [high] to [low]

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1
Q

Define thermochemistry and give another name for it

A

The study of heat changes that accompany chemical rxns and physical changes
Thermodynamics

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2
Q

Describe a calorimeter and how it works

A

Contains h2o in an insulated vessel
Rxn occurs in a known mass of h2o
Heat absorbed or released by h2o = that absorbed or released by rxn
Data is t showing heT changes

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3
Q

Describe temperature and it’s units

A

Measures the average KE of particles in a sample of matter
Unit in joules which is the metric unit of heat or NRG
1J=kg m2/sec2

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4
Q

Define specific heat symbol and unit

A

Amount if heT NRG required to raise t of a substance by 1 c or K
Symbol is Cp
Units joules /g c

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5
Q

What has the highest specific heat and give an example

A

H2o

4.18 j/g c

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6
Q

Define heat capacity what are the three things it depends on

A

The ability of a material to absorb heat

  1. Material changing of T
  2. The mass
  3. Size if the change in t
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7
Q

Specific heat equation and variables

A
Cp= q/(m)change of T
Cp= specific heat 
Q heat ab/re. J
M mass g
T. K
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8
Q

What’s another name for heat of rxn and define it

A

Enthalpy
The amount if heat absorbed or released in a chemical rxn or the difference in heat btw the stored NRG if the reactants and that if the products

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9
Q

What are the two possible values for enthalpy

A

Exothermic -heat released; feels hot
Change in H is beget ice as heat is lost
Reactants have a higher heat content than products

Endothermic - heat absorbed feels cold
Change in H is positive as heat is gained
Products have higher heat content

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10
Q

How do you calc enthalpy

A

ChangeH= Hproducts - Hreactants

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11
Q

When ChangeH is a high negative value…

A

Stable compound is forming spontaneously, vigorously
Large amounts of NRG released as products form
This is most common b/c reactants gain stability

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12
Q

When ChangeH is positive or low negative

A

Unstable compound may form and may decompose violently

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13
Q

Define heat of combustion

A

Heat released by the complete combustion of 1 mol of a substance

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