Ceramics 1 Flashcards

1
Q

Types of Ceramics

A

<p>Ceramic
Glasses
Glass-ceramics</p>

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2
Q

Ceramic definition

A

<p>Refractory polycrystalline compound

| </p>

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3
Q

Ceramic properties

A
<p>Usually inorganic
Highly inert
Hard and brittle
High compressive strength, low tensile
Generally good insulators
Good tribological props.
</p>
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4
Q

Natural ceramic composites

A

<p>Bones, teeth, shells

| Hard tissues</p>

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5
Q

Ceramic structures

A

<p>Crystalline
Semi-crystalline
Amorphous</p>

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6
Q

Ceramic examples<

A
<p>Alumina
Bioglass
Ca Phosphates
Hydroxyapatite
Ca3 Phosphate</p>
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7
Q

Bioactivity

A

<p>allows material to form a bond with living tissue

| stimulates healing by responding as if it were a natural tissue</p>

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8
Q

Bioinert

A

<p>Not bonded
Relative movement (articulation)
Fibrous layer</p>

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9
Q

Porous inert

A

<p>Tissue ingrowth
Fixation
Reduced movement</p>

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10
Q

Surface reactive

A

<p>Chemical bonds
Slow degradation
Induces bone formation</p>

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11
Q

Resorb-able

A

<p>Degrades</p>

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12
Q

Ceramic processing

A
<p>Cast or Plasma spraying
Liquid-phase sintering
Solid-state sintering
Glass-ceramic
Glass</p>
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13
Q

Ceramic Strengthening

A

For ceramics: to prevent fracture or inhibit crack propagation
They fracture easily under tension

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14
Q

Polishing

A

Etch and Fire polish
Smaller grains
Eliminate flaws

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15
Q

Annealing

A

eliminate residual stress

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16
Q

Ion exchange

A

Intro of bigger cations within structure

17
Q

Porosity

A

3% porosity = 10x decrease in strength

18
Q

Alumina (Type 1)

A
Aluminum oxides
Nearly inert crystalline ceramic
Bioinert
Small grain and porosity = higher strength
Stress shielding problems
High hardness, low wear
19
Q

Alumina Applications

A

Orthopedics (heads, bone screws/plates

Dental crowns and bridges

20
Q

Type 2

A

Structural bridge or scaffold for bone formation

21
Q

Type 3

A

Bioactive glasses and glass-ceramics

Direct chemical bonding

22
Q

Glass (3)

A

inorganic melt cooled to solid w/o crystallization
Amorphous solid
Brittle

23
Q

Glass-ceramic

A

Polycrystalline solid

Stimulatory effect on bone

24
Q

Ca-Phosphate (3,4)

A
Naturally occurring (bone)
Poor mechanical behavior
Porosity determines: Tensile/Compressive strength and fatigue resistance
25
Q

Hydrolysis

A

degradation that increases with a decreasing Ca/P ratio

  1. 0 = quick
  2. 43 = 3-4 months
26
Q

Ca-P Apps.

A
Bone grafting
Non-major load bearing parts
Powders
Coatings
Bone fillers (temporary)
27
Q

Plasma Spraying Ca-P

A

most employed method for ceramic coating

28
Q

Resorbable Ca-P Biodegradation factors

A

Physiochemical dissolution
Physical disintegration
Biological factors

29
Q

Ca-P bone cements

A

Req. to be injectable and moldable

Drug delivery

30
Q

Hydroxyapatite (HA)

A

Bioactive and osteoconductive