3: Intermediate Materials Flashcards

1
Q

What is the purpose of the ‘intermediates’ process?

A

To convert raw fibres (and matrices if prepregs) into workable materials: mats, fabrics and prepregs

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2
Q

What affect does increasing the number of processing stages have on costs?

A

Costs increase

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3
Q

Bundle (multiple filaments) sizes are measured in “hex”. Define 1 hex

A

1 gram per kilometre (1g/1000m)

If aligned: Glass-roving, Carbon-tow
If twisted: Yarn

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4
Q

What are some advantages of using yarn fibre bundles compared to aligned bundles?

A

-Reduced risk of bundle falling apart and fibre breakage
-More circular cross-section

However, reduces axial properties and costs more

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5
Q

List some properties of fibre mats

A

-Flat sheets (usually glass fibres)
-Chopped or continuous fibres
-Polymer binded (to stabilise the mat structure)
-Random fibre orientation, resulting in isotropic properties (however directionality can be induced during design)
-Common matrices used are: Polyester or epoxy
-Fibre volume fraction <40%
-Low cost
-High industrial application

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6
Q

Describe the manufacture process of chopped strand mat (CSM)

A

-Fibre strands are chopped and deposited on a conveyer belt at a defined rate
-Polymer binder is sprayed onto the mat
-The binder is soluble in styrene
-Processed in hand laminating

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7
Q

Describe the manufacture process of continuous filament mat (CFM)

A

-Similar process to CSM, however molten glass is deposited instead of chopped matting
-Continuous fibres form loops
-Processed using hand laminating or liquid composite moulding

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8
Q

What are some advantages CFM offers compared to CSM?

A

-Better formability
-Washing resistance

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9
Q

List some properties of textile reinforcements

A

-Patterned fibre arrangement (architecture)
-Filaments arranged into tows (micro level)
-Tows arranged into fabric architecture (meso level)
-Homogenised effective properties of textile sheet (macro level)
-Fibre volume fractions >50%
-Anisotropic due to tow alignment (usually orthotropic)

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10
Q

Define a “unit cell”

A

-The smallest repetitive unit allowing a macroscopic textile patch to be generated through translation along weft and warp directions
-Analysis of a unit cell fabric is sufficient to determine material properties

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11
Q

Describe the “weaving process”

A

-A longitudinal warp yarn is raised/lowered to form gaps (in predefined patterns)
-A transverse weft yarn is drawn through the gaps and inserted over/under the warp yarns
-The weft yarn is pushed against the fell of the fabric by a reed
-The process repeats forming a woven fabric

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12
Q

List some common weave architectures

A

-Plain weave: 1x1 (high crimp, stable fabric)
-Twill weaves: 2x2, 3x1, ect…
-Satin weaves: 5x1, 4x1, 8x1 (low crimp, improved mechanical properties)
-Unidirectional weaves (unbalanced in yarn size and spacing)

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13
Q

What is crimp and what are some material by-products of it?

A

The “waviness” of the yarns (cohesion of yarn layers when high levels of interlacing)
-Through thickness properties increase
-In-plane properties decrease (compared to straight fibres)
-crimp proclivity varies with weave architecture

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14
Q

How do woven fabrics usually deform and what effect of material properties does this have?

A

Mainly in shear (fabric shear is known as “drape”)
-The yarn crossover points act as junctions, therefore both volume fraction and fibre orientation are affected (both depend on shear angle “alpha”)

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15
Q

Describe the purpose and properties of spread tow fabrics

A

-To improve mechanical properties due to a reduction in crimp at smaller thicknesses
-More expensive due to additional processing

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16
Q

Explain the manufacture process of Non-Crimp Fabrics (NFC)

A

Continuous process:
-Layers of aligned tows are laid up on a flat bed at defined orientations (eg. 45, 90, ect)
-Needle bars at the end of the bed stitch layers together with a sewing thread
-Layers are stitched together

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17
Q

What are the properties of knitted fabrics?

A

-Same knot pattern for fibre fabrics as knitting
-Better at fitting moulds
-Decreased mechanical properties

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18
Q

What is the test for how far a fabric can shear before wrinkling?

A

Picture frame shear test

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19
Q

What is the test for how easily fabric layers slide relative to each other or tool surface?

A

Fabric friction test

20
Q

What is the test for what compaction pressure is required to achieve a specified fibre volume fraction?

A

Fabric compression test

21
Q

Explain the picture frame shear test

A

-Shear frame mounted on a universal testing machine
-Cruciform specimen clamped in the frame
-Cross-head moves upwards at a constant speed
-Measure cross-head displacement and force at the load cell
-Works for bi-directional fabrics, yarns aligned with sides of frame (doesn’t work for multiaxial fabrics or random mats)

22
Q

Explain the Fabric Friction Test

A

-Aluminium table attached to universal testing machine
-Brick-shaped steel sled with defined mass connected to a cross-head via fishing line and “no friction” pulley
-Fabric layer is bonded to the sled/table or both
-Pull sled at constant speed
-Record pulling force and displacement to calculate the COF

23
Q

Explain the Fabric Compression Test

A

-Fabric specimen sandwiched between two flat steel compression plates
-top plate is adjusted to ensure the plates are parallel
-Compression force and Gap between the plates are measured
-Vf plotted against compaction pressure

Vf=mass/(densityareameasured height)
compaction pressure=Fc/A

24
Q

Explain a typical Thermoset Prepreg material

A

-Unidirectional tape or fabric pre-impregnated with partially cured (B-stage) resin system
-Usually carbon fibre & epoxy resin
-Limited storage life, so stored at low temps to minimise cure (-18 degrees)
-Able to conform to highly geometrically complex parts (when laid by hand, then autoclave cured)
-Can produce large low geometrically complex parts (when manufactured with ATL)

25
Q

What are advantages of a Thermoset Prepreg material?

A

-Resin/fibre content can be accurately controlled during manufacture
-High fibre contents can be achieved
-Void content is low (good for mechanical properties), very few gaps

26
Q

What is the main disadvantages of a Thermoset Prepreg material?

A

-Material cost is high

27
Q

Explain the Solvent Dip thermoset prepreg production process

A

Solvent dip process:
-Solvent added to resin to reduce viscosity
-Dry reinforcement is dipped in solvent/resin mixture for impregnation
-Solvent is evaporated in a drying oven
-Protective backing film is applied to the prepreg sheet

28
Q

Explain the Hot Melt thermoset prepreg production process

A

Hot melt process:
-Dry reinforcement is deposited onto a backing film
-Continuous resin film is produced from liquid resin
-Resin film is deposited onto the dry reinforcement
-Heat and pressure is applied to impregnate the dry reinforcement with liquified resin
-Top backing film is applied and prepreg sheet is rolled up

29
Q

What are the differences between the Hot Melt and Solvent Dip processes?

A

Hot Melt:
-No additional solvent required
-resin viscosity is higher than solvent process

Solvent Dip:
-Emission of volatiles
-Additional cost for solvent

30
Q

Explain a typical Thermoplastic Prepreg material

A

-Usually flat organosheets or continuous tapes with unidirectional reinforcement
-Reinforcement is fully impregnated and consolidated
-Low void content
-Unlimited storage life at room temperature
-Non-sticky surface (no backing films required)
-Sheets/Tapes cannot be formed at room temperature (stiff)
-Heat above matrix Tm to mould

31
Q

Explain the Thermoplastic Prepreg Production process

A

-Dry reinforcement is sandwiched between 2 polymer sheets
-Fed through a heater zone, thermoplastic melts
-High compaction pressure (due to high viscosity of molten polymer) impregnates reinforcement with molten polymer
-Composite solidifies in cooling zone and cut/rolled into sheets/tapes

32
Q

Explain Commingled yarns

A

-Manufactured thermoplastic filaments (spinning of molten polymer) are integrated into the fabric tows
-Unlimited storage life, and formable at room temperature
-Thermoplastic filaments melt when heated and the matrix redistributes between the reinforcement fibres

33
Q

What are suitable processes for Thermoplastic prepreg applications?

A

-Compression moulding
-Automated thermoplastic tape placement

34
Q

State a typical Bulk Moulding Compound (BMC) formulation by weight percentage

A

Resin: 0.22
Catalyst: 0.003
Mould release: 0.017
Pigment: 0.03
Filler: 0.53
Fibre: 0.2

35
Q

What are typical properties of a Bulk Moulding Compound (BMC)?

A

-Matrix based thermoset resin reinforced with discontinuous fibres
-Usually polyester resin with glass fibre reinforcement
-Storage life limited (due to thermoset component)
-Fibre volume fraction is typically low
-Fibre length ~5mm-10mm
-Low cost

36
Q

How are Bulk Moulding Compounds (BMC) manufactured?

A

-Fibres, resin and other components are mixed in a z blade mixer
-Fibres are pre-chopped
-Filler added to increase viscosity of liquid compound
-Resin is added in bulk or as a ‘varnish’

Processed using (both apply head to induce resin cure):
-Compression moulding
-Thermoset injection moulding

37
Q

State some applications of Bulk Moulding Compounds (BMC)

A

-Electrical (switch & breaker housing)
-Industrial (pump casings for chemical and food handling)
-Sport (Golf club heads)
-Automotive (water pumps, chain & rocker covers, manifolds)

38
Q

What are typical properties of a Sheet Moulding Compounds (SMC)?

A

-Matrix based on thermoset resin reinforced with discontinuous fibres
-Usually polyester resin with glass fibre reinforcement
-Limited storage life (thermoset)
-Similar to prepreg but for less demanding applications
-Longer fibres than BMC (~25mm-50mm)
-Higher volume fraction than BMC
-Fibres mainly oriented in-plane

39
Q

State a typical Sheet Moulding Compound (SMC) formulation by weight percentage

A

Polyester resin (matrix): 31%
Thermoplastic resin (reduce shrinkage): 5%
Organic peroxide (catalyst): 0.3%
Zinc stearate (mould release agent): 1%
Magnesium oxide (thickener): 2%
Glass fibre (reinforcement fibres): 30%
Calcium carbonate (filler): 31%

40
Q

Explain the Sheet Moulding Compounds (SMC) production process

A

-Chopped dry fibres are deposited on a layer of resin paste (contains all components)
-Covered with another layer of resin paste
-Compaction pressure impregnates the reinforcement with molten polymer
-Fibre orientation is limited to in-plane

41
Q

What are Sheet Moulding Compounds (SMC) applications and the handling process?

A

-Automotive body panels

-Starts as a wet slurry, thickening agents are added
-Typically process in compression moulding
-Heat is applied to induce resin cure
-Suitable for high volume applications

42
Q

What are typical properties of a Thermoplastic Compounds?

A

-Pellets containing discontinuous fibres
-Unlimited storage life at rtp (thermoplastic)
-Standard (short) fibre: <5mm, random orientations, compounded in an extruder
-Long fibre thermoplastics: >10mm, fibres aligned with pellet axis, higher Vf, made by hot melt impregnation of rovings/tows
-Fibre length reduces due to breakage during pellet processing

43
Q

Explain the Standard Thermoplastic Pellet Production process

A

-Fibre and thermoplastic is chopped and fed through a heated extruder
-Extruded filament is chopped to specified lengths (<5mm) with random fibre orientations

44
Q

Explain the Long Thermoplastic Fibre Reinforced Production process

A

-Thermoplastic pellets are fed through a heated extruder
-Impregnation die combines the dry fibre with extruded thermoplastic
-Fibres are chopped to specified lengths (>10mm) with axially aligned fibres

45
Q

What are suitable processes and applications for Thermoplastic Compounds?

A

(Heat for consolidation or injection, then cool to obtain rigid component)
Suitable processes:
-Compression moulding
-Injection moulding

Applications:
-Geometrically complex components