2nd Year Liquids and Vapours/Entropy/Second Law Flashcards

1
Q

Compressed Liquid =

A

Liquid below Tsat

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2
Q

Superheated Liquid =

A

Gas above Tsat

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3
Q

Wet Vapour

A

Mix of gas and liquid at Tsat

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4
Q

Dryness fraction

A

Quality can be found using interpolation between “Sat g” and “Sat f” values

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5
Q

V =

A

mv

Useful in questions

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6
Q

Can I use the perfect Gas Laws?

A

HELLA NO!

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7
Q

Second Law:

A

Entropy will always increase

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8
Q

Thermal efficiency =

A

W net / Qin
or
1 - Q(out)/Q(in)

Will always be less than 1

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9
Q

Calculte Entropy :

A

ΔS = Q/T

T in Kelvin!

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10
Q

What is entropy?

A

Referred to as “measure of chaos”

ΔS will always be positive

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11
Q

Zeroth Law:

A

If 2 systems are in equilibrium with a third, then they are also in equilibrium with eachother

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12
Q

Third Law:

A

Entropy of a perfect crystal at 0 Kelvin is 0.

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13
Q

Δs =

A

Cv Ln(T2/T1) + R Ln(V2/V1)

Cp Ln(T2/T1) - R ln(P2/P1)

Cp Ln(V2/V1) + Cv Ln (P2/P1)

These can be manipulated for easy equations at const T,P,V

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14
Q

Expansion Process

Isentropic Efficiency =

A

Actual Work out / Ideal Work out

Work Transfer decreases as Δs increases

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15
Q

Compression Process

Isentropic Efficiency =

A

Ideal Work in/ Actual Work in

Work consumed decreases as Δs increases

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16
Q

How to find q? (from T and S)

A

Area under a T-s Diagram

Remember T in Kelvin!