3.4 - Acids, bases and salts Flashcards
(22 cards)
Acid
H+ donor
Acids dissolve and then donate H+ ions into the water, causing a solution to have a pH less than 7 - acidic
Alkali
OH- donor
Alkalis dissolve and then donate OH- ions into the water, causing a solution to have a pH more than 7 - alkaline
Base
H+ acceptor
Bases dissolve and then accept H+ ions from the H2O molecules, but when an H2O molecule loses an H+ ion, what’s leftover is an OH- ion - this causes the solution to have a pH more than 7 - alkaline
Difference between acidic/alkaline and acid/alkali
Acid or alkali refer to substances in terms of ions
Acidic or alkaline describes a solution in terms of pH
Common acids
- Hydrochloric acid - HCl
- Nitric acid - HNO3
- Sulphuric acid - H2SO4
- Phosphoric acid - H3PO4
- Carbonic acid - H2CO3
Common alkalis
- Sodium hydroxide - NaOH
- Potassium hydroxide - KOH
- Ammonium hydroxide - NH4OH
- (all soluble metal hydroxides)
Common bases
- Ammonia - NH3
- (all metal oxides)
- (all metal hydroxides)
Polyatomic ion definition
An ion that contains more than one atom
Acid and base reaction
Acid + base —> salt + water
Reaction between zinc oxide and sulphuric acid
Zinc oxide + sulphuric acid —> zinc sulphate + water
Observations in an acid and base reaction
The base disappears as it is used up in the reaction
If the salt is soluble, it dissolves in the water to form a salt solution
Ammonia and acid reaction
Ammonia + acid —> ammonium salt
Reaction between ammonia and hydrochloric acid
Ammonia + hydrochloric acid —> ammonium chloride
What are solubility rules used for
To determine if a salt is soluble in water or not
Solubility rules - soluble
- all group 1 and ammonium salts
- all nitrates
- most halides (except silver and lead halides)
- most sulphates (except lead, barium and calcium sulphate)
Solubility rules - insoluble
- silver halides, lead halides
- lead, barium and calcium sulphate
- oxides, hydroxides and carbonates
Making soluble salts method
- Heat the acid
- Add the base
- Filter excess base
Making insoluble salts method
- Filter out salt precipitate
- Rinse with water
- Pat dry with filter paper
Crystallisation method
- Heat salt solution
- Allow solution to cool
- Filter out crystals
- Pat dry with filter paper
Titration method
- Perform titration to measure volume of acid and alkali that neutralise each other
- Use phenolphthalein
- Pink —> colourless
- Swirl continuously
Acid and carbonate reaction
Acid + carbonate —> salt + water + carbon dioxide
Observations in an acid and carbonate reaction
Carbonate disappears as it is used up in the reaction
Fizzing as a gas (carbon dioxide) is produced
If the salt is soluble, it dissolves into the water to form a salt solution