3.4- ELECTRONEGATIVITY- BOND POLARITY IN COVALENT BONDS Flashcards

(35 cards)

1
Q

What are the forces that hold atoms together all about?

A

attraction of positive charges to negative charges

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2
Q

What happens in ionic bonding? (transfer)

A

complete transfer of electrons from one atom to another

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3
Q

Are the electrons always evenly spread out in a covalent bond?

A

no

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4
Q

When are the electrons not evenly spread out in a covalent bond?

A

when one of the atoms is better at attracting electrons than the other one

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5
Q

What is the atom that is better at attracting the electrons than the other atom in a covalent bond said to be?

A

more electronegative

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6
Q

What is the definition of electronegativity?

A

power of an atom to attract the electron density in a covalent bond towards itself

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7
Q

What is the term electron density often used to describe?

A

way the negative charge is distributed in a molecule

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8
Q

What is used as a measure of electronegativity?

A

Pauling scale

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9
Q

What does the Pauling scale run from?

A

0 to 4

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10
Q

What does a greater number on the Pauling scale mean?

A

more electronegative the atom

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11
Q

What number does the noble gases have on the Pauling scale?

A

no number

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12
Q

Why do the noble gases not have a number on the Pauling scale?

A

generally they do not form covalent bonds

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13
Q

What does electronegativity depend on? (3)

A

nuclear charge

distance between nucleus and outer shell electrons

shielding of nuclear charge by electrons in inner shells

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14
Q

What happens to electronegativity as the size of the atom decreases?

A

smaller the atom, greater the electronegativity

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15
Q

Why does electronegativity increase as the size of the atom is smaller?

A

closer the nucleus is to the shared outer main level electrons

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16
Q

What happens to electronegativity the larger the nuclear charge?

A

greater the electronegativity

17
Q

How does electronegativity change going up a group?

18
Q

Why does electronegativity increase going up a group?

A

less shielding by electrons in inner shells

19
Q

How does electronegativity change going across a period?

20
Q

Why does electronegativity increase going across a group? (3)

A

nuclear charge increases

number of inner main levels remain the same

atoms become smaller

21
Q

Where are the more electronegative atoms found on the periodic table?

A

top right-hand corner (ignoring noble gases)

22
Q

What are the most electronegative atoms? (4)

A

fluorine

oxygen

nitrogen

chlorine

23
Q

What is polarity about?

A

unequal sharing of electrons between atoms bonded together covalently

24
Q

What is polarity the property of?

A

property of the bond

25
How must the electrons in a bond between atoms that are the same be shared?
must be shared equally between the atoms
26
Why must the electron be shared equally in a bond between atoms that are the same?
both atoms have exactly the same electronegativity
27
What is the polarity of the bond between two of the same atoms like?
non-polar
28
How will the electrons be shared in a covalent bond between two atoms of different electronegativity?
electrons would not be shared equally between the atoms
29
How is the electron cloud described to be when the atoms have different electronegativities in the bond?
distorted
30
What relative charge would the atom with a higher electronegativity have?
relatively negative
31
What relative charge would the atom with a lower electronegativity have?
relatively positive
32
What is the polarity of the bond between atoms who have different electronegativities?
polar
33
What is the polarity of the bond like the greater the difference in electronegativity?
the more polar the covalent bond
34
How can you say a covalent bond has some ionic characters?
it may be going some way towards the separation of the atoms into charged ions
35
Is it possible to have ionic bonds with covalent characters?
yes