341 Exam 2 Flashcards
1
Q
Dissassociation rxn
A
2
Q
Association rxn
A
3
Q
B-H Elimination
A
Requirements:
Syncoplanar arrangement
Usually single bond btwn alpha and beta carbon
Need beta hydrogen
Need at least 2 de- (stabilizes M-C bond)
Forms a sideways bond btwn metal and double bonded carbon
Needs an open CN site
4
Q
Migratory Insertion
A
5
Q
Oxidative addition
A
6
Q
Pi acceptor ligand
A
7
Q
Trans effect
A
8
Q
trans effect
A
9
Q
LFAE
A
10
Q
Inner sphere
A
11
Q
Outer sphere
A
12
Q
How to tell inner vs oute sphere
A
Inner sphere rxns have a bridging ligand that has 2 lps to connect to both sides
13
Q
Do metalloneces follow the 18 electron rule?
A
Yes
14
Q
Wilkon’s cataylst overal rxn
A
H2 +H2CH2C (double bonded) -> Ch3CH3
15
Q
Ziegler Natta Polymerization
A
Makes polymers
