Chapter 8- The Gas Phase Flashcards

1
Q

Gas pressure units

A

1atm = 760mmHg = 760 torr = 101.325 kPa

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2
Q

Ideal gas law

A

PV = nRT

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3
Q

Solving for density

A

Density = m/V = PM/RT

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4
Q

Number of L that 1mol of a gas at STP takes up

A

22.4L

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5
Q

Combined gas law

A

PV/T = PV/T

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6
Q

Calculate a change in volume

A

V2 = V1 (P1/P2)(T2/T1)

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7
Q

Density

A

Density = mass/V

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8
Q

Molar mass calculation

A

M = (density at STP) (22.4)

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9
Q

Avogadros principle

A

n1/V1 = n2/V2

*as the number of moles of gas increases, the volume increases in direct proportion

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10
Q

Boyles law (must be isothermal)

A

P1V1 = P2V2

*volume and pressure are inversely related

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11
Q

Charles law (must have constant pressure)

A

V1/T1 = V2/T2

*volume and temperature are directly related

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12
Q

Gay-lussacs law (constant volume)

A

P1/T1 = P2/T2

*pressure and volume are directly proportional

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13
Q

Partial pressure calculation

A

(Moles gas A/total moles of gas) (total pressure)

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14
Q

Vapor pressure

A

Pressure exerted by evaporated particles above the surface of a liquid

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15
Q

What does increasing partial pressure of a gas do to the solubility?

A

Increases

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16
Q

Evaporation and condensation equation

A

Vapor pressure from evaporated molecules forces some of the gas back into the liquid phase until equilibrium is reached b/w evap. and cond.

17
Q

Average molecular speed of gas particles

A

KE = (3/2)kBT

kB- 1.38 x 10^-23
T- temperature

18
Q

Almost impossible to find speed of individual gas molecule. What’s one way to determine an average speed?

A

Root-mean-square speed (Urms)

squareroot [3RT/M]
*higher temp =faster and larger molecules =slower

19
Q

Isothermal and isobaric conditions. Equation for rates at which two gases diffuse

A

r1/r2 = Squareroot [M2/M1]

20
Q

Diffusion

A

When gases mix with one another (high to low concentration)

21
Q

Effusion

A

When a gas moves the ought a small hole under pressure.

22
Q

Ideal gas law including density

A

T = (PM)/ (densityR)

23
Q

When to use what R-value?

A

.082 LatmmolK

8.314 JmolK