Group 2 Compounds Flashcards

1
Q

roup 2 elements react with water to form…?

A

A metal Hydroxide + Hydrogen

X + 2H2O = X(OH)2 + H2

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2
Q

What does the solubility of an ion depend on in group 2?

A
the anion (negative Ion)
OH- (hydroxide) ions (singly Charged) increase solubility down group
SO4 2- (sulphate) ions (Double Charged) decrease solubility down group.
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3
Q

how soluble in Mg(OH)2 / Magnesium hydroxide

A

Sparingly Soluble

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4
Q

Are most group 2 sulphates soluble in water?

A

Yes except Barium Sulphate

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5
Q

what is the test for group 2 sulphate ons?

A

Makes use of the fact barium sulphate is insoluble. Add dilute HCl and then BaCl2 to a solution containing sulphate ions and then a white precipitate (barium sulphate) is formed.

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6
Q

How is Barium Sulphate used in Medicine?

A

Barium Meal

barium sulphate shows up on x rays so can be used to view the inside of the body.

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7
Q

Barium Sulphate is poisonous, How come it is safe to be used in the barium meal?

A

it is insoluble so can get into your blood to poison you.

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8
Q

What metal is used in the extraction of Titanium?

A

Mg

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9
Q

what happens in titanuim extraction from its ore Titanium (IV) oxide

A

Converted to Titanium (IV) Chloride by heating it with carbon in a stream of chloride gas. The Titanium Chloride is than purified by fractional distilation and reduced by Mg in a furnace at 1000C

TiCl4 + 2Mg = Ti + 2MgCl2
(g) (l) (s) (l)

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10
Q

How can sulphur dioxide be removed from flue gases?

A

reacting it with an alkali

Process called wet scrubbing

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11
Q

what compound may be used to remove SO2 from flue gases?

A
Calcium Oxide (CaO)
Calcium Carbonate (CaCO3) 

see book for more…

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12
Q

What are group 2 elements also known as?

A

Alkaline Earth Metals

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13
Q

What an Calcium Hydroxide (Ca(OH)2) be used for in agricuture?

A

to Neutralise acidic soils

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14
Q

what can Magnesium Hydroxide (Mg(OH)2)be used in in medicine?

A

Indigestion tablets as an antacid, it neutralises stomach acid.

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15
Q

One group 2 element has a first ionisation energy of 550kJ mol-1 and another 738kJ mol-1. Which would react most rapidly with water?

A

the one with First IE of 550kJ mol-1

it can be oxidised more easily.

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16
Q

Acidified barium chloride is added to solution, no precipitate is formed, what does this show?

A

there are no sulphate ions present

17
Q

Describe the trend in reactivity with water as you go down Group 2?

A

Reactivity increases

18
Q

How does the solubility of hydroxides change as you go down Group 2?

A

solubility increases as you go down

19
Q

How does the solubility of sulphates change as you go down Group 2?

A

solubility decrases

20
Q

why is barium chloride acidified before it is used to test for sulphate ions?

A

to get rid of any sulfites or carbonates that might affect the test result

21
Q

What is a Barium meal?

A

it is a suspension of Barium Sulphate that a patient takes before an X ray as it si opaque to x rays so will show up the structure of the oesophagus, stomach or intestines.

22
Q

what happens the oxidation state of group 2 elements when they react?

A

The are oxidised from 0 to 2+

the charge goes X to X2+ +2e-