4.6 Chemical Analysis Flashcards
(43 cards)
Test for hydrogen?
SQUEAKY POP TEST
METHOD: 1. Collect a sample of gas in a test tube
2. Attempt to ignite the gas using a lit splint.
RESULT: Squeaky pop sound
-Combustion of H2
-Sound caused by hot gas rushing out of test tube
Test for oxygen?
GLOWING SPLINT TEST
METHOD: 1. Collect a sample of gas in a test tube
2. Place a glowing splint into the tube
RESULT: The splint relights
-Combustion of wood in the splint
-Relights because pure O2 is more concentrated than the 02 in normal air
-Wood in splint combusts faster
Test for water? For the presence of H20
COPPER SULFATE TEST
METHOD: 1. Add anhydrous copper sulfate
RESULT: Changes from white —>blue
Test for water? For purity of H20
MEASURE ITS BOILING POINT & COMPARE IT TO 100C
METHOD: 1. Measure its boiling point
RESULT: Closer to 100c = more pure
Test for Carbon Dioxide?
LIMEWATER TEST
METHOD: 1. Bubble a sample of gas through limewater
RESULT: White precipitate forms (turns cloudy)
-Limewater=saturated calcium hydroxide
-Forms white ppt of calcium carbonate when it reacts with CO2
Test for chlorine?
DAMP BLUE LITMUS TEST
METHOD: 1. Place damp blue litmus paper in a sample of gas
RESULT: Turns white (bleaches)
-Cl2= good bleaching agent
Test for ammonia?
DAMP RED LITMUS TEST
METHOD: 1. Place damp red litmus paper in a sample of gas
RESULT: Turns blue
What are cations?
-Positive Ions
Li (+), Na (+), K (+), Ca (2+), Cu (2+), Fe (2+), Fe (3+), NH4 (+)
What type of flame is used in a flame test?
Non luminous (blue) Bunsen flame
How do you conduct a flame test?
- -Dip a piece of nichrome/ platinum wire into HCL
-These wires don’t colour the flame & the acid cleans the wire - -Dip the wire into a sample of solid or solution
-This causes some of the sample to stick onto the wire - -Place the tip of the wire into a non-luminous Bunsen flame
Red Flame (metal cation)
Li+
Yellow (metal cation)
Na+
Lilac flame (metal cation)
K+
Orange-red Flame (metal cation)
Ca2+
Blue-green flame (metal cation)
Cu2+
Blue-green flame (metal cation)
Cu2+
What do we use sodium hydroxide (NaOH) to test for?
Cu2+, Fe2+, Fe3+
How do you conduct a sodium hydroxide test?
- Dissolve the sample in water
- Add a free drops of NaOH(aq)
What are the results for the sodium hydroxide test? Ppt colour, ppt formula & Metal cation
Blue- Cu(OH)2- Cu2+
Green- Fe(OH)2- Fe2+
Brown- Fe(OH)3- Fe3+
Write an ionic equation that shows the formation of the ppt (Cu2+)
Cu2+(aq) + 2OH- (aq) —> Cu(OH)2(s)
What is used to test for ammonium (NH4+) ions?
Sodium hydroxide (NaOH)
How do you conduct an Ammonium Test?
- Dissolve the sample in water
- Add some NaOH(aq) & warm it
- Test the gas evolved with damp red litmus paper i.e. The Ammonia Test
If NH4+ ions are present in the original sample, the litmus paper will turn…
Blue
What is the balanced equation for the ammonium test?
NH4+ (aq) (sample containing NH4+) + OH-(aq) —> NH3(g) (test with damp red litmus paper) + H2O(l)