3.2 Alkanes Flashcards

1
Q

What is petroleum?

A

A mixture of Alkane hydrocarbons that can be separated by fractional distillation

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2
Q

What is cracking?

A

The process of breaking non useful Alkane hydrocarbons into shorter hydrocarbons by breaking c-c bonds.

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3
Q

What is thermal cracking?

A

Cracking produced at high temperatures and high pressures (1000c; 70Å)
Lots of Alkenes are produced

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4
Q

What is catalytic cracking?

A

Cracking using a zeolite catalyst (very high surface area), and a slight pressure and high temperature (500c)
Creates aromatic compounds and motor fuel Alkanes

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5
Q

What are the benefits of catalytic cracking?

A

Lower pressure is cheaper and safer
Lower temperature is cheaper
Speeds up the reaction and saves time

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6
Q

What are the benefits of thermal cracking?

A

Produces more Alkenes and polymer Alkenes.

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7
Q

What is complete combustion of Alkanes?

A

When an Alkane is burned in excess and sufficient amount of oxygen to produce carbon dioxide and water.

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8
Q

What is incomplete combustion of Alkanes?

A

Alkanes burned in a shortage of supply of oxygen or when the Alkane is in excess. This produced carbon monoxide and water and/or traces of carbon

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9
Q

Why is carbon monoxide a pollutant?

A

It is toxic to the body as it replaces oxygen on haemaglobin in the blood stream

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10
Q

How is carbon dioxide a pollutant?

A

It is a green house gas which absorbs infra red and emit some of the energy back to earth, heating the surface.

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11
Q

How is carbon a pollutant?

A

It blackens buildings, causes respiratory issues, and global dimming

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12
Q

What is SO2 or sulfur dioxide?

A

In impure fuels there are traces of sulfur. When burned these oxidise and the compound can cause acid rain when dissolved in the moisture.

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13
Q

How can we remove sulfur dioxide?

A

This is called desulfurisation. Flu gases mix with an alkaline slurry and forms a harmless salt

ie) CaO + SO2. -> CaSO3

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14
Q

How are NO, NO2 and other similar nitrous oxides, pollutants?

A

Reaction of N2 in impure fuels with O2 at high temperatures (in engines and furnaces) form these compound which then can cause acid rain when dissolved by the moisture.

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15
Q

What are catalytic converters?

A

They have large surface areas and are coated in materials to trap the pollutants.

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16
Q

Chlorination of Alkanes:

What is initiation?

A

Cl2 –UV–> 2Cl•

17
Q

Chlorination of Alkanes:

What is propagation?

A

Cl• + CH4 –> •CH3 + HCl

•CH3 + Cl2 –> CH3Cl + Cl•

18
Q

Chlorination of Alkanes:

What is substitution?

A

In Cl2 excess all H can be replaced
CH4 + Cl2 -> CH3Cl + HCl

CH3Cl + Cl2 -> CH2Cl2 + HCl

CH2Cl2 + Cl2 -> CHCl3 + HCl

CHCl3 + Cl2 -> CCl4 + HCl

19
Q

Chlorination of Alkanes:

What is termination?

A
  • CH3 + Cl• -> CH3Cl
  • CH3 + •CH3 -> C2H6

Cl• + Cl• -> Cl2

Two radicals can recombine

20
Q

What are Alkanes?

A

Saturated hydrocarbons with the general formula of CnH2n+2