3 - Redox I Flashcards
What is an oxidation number?
A representation of how oxidised/reduced an element becomes in a reaction, telling you how many electrons have been lost/gained.
What is oxidation?
LOSS of electrons - oxidation number INCREASES
What is reduction?
GAIN of electrons - oxidation number DECREASES
What are the rules of oxidation numbers?
- An unconvinced element’s oxidation number is always 0.
- In a neutral compound, the sum of all the oxidation numbers is 0.
- Simple monoatomic ions have oxidation numbers that are the same as their charges.
- In compounds, the oxidation number is the same as the overall charge of the ion.
- For G1/2, the oxidation number is the same as the group number.
What is hydrogen’s oxidation number and are there any exceptions to this?
+1
-1 in metal hydrides (because the oxidation number = the ion charge)
What is the oxidation number of Fluorine and are there any exceptions to this?
-1
No exceptions
What is the oxidation number of oxygen and are there any exceptions to this?
-2
-1 in peroxides because neutral compounds = 0
Positive with F as F is more electronegative than O
What are the oxidation numbers of Cl, Br and I - are there any exceptions to this?
All -1
Cl: positive with O or F
Br: positive with O, F or Cl
I: positive with O, F, Cl or Br
What does the Roman numeral in Copper (II) Sulphate indicate?
Copper’s oxidation number is +2.
What is are oxidising and reducing agents?
- Oxidising: GAINS electrons, becoming reduced as a result (decreasing oxidation number) - NON-METALS
- Reducing: LOSES electrons, becoming oxidised as a result (increasing oxidation number) - METALS
What is a redox reaction?
When oxidation and reductio occur simultaneously within a reaction.
What is a disproportionation reaction?
A redox reaction where a single species is simultaneously oxidised and reduced.
When creating full equations from half equations, what steps must you take?
- ) Balance everything EXCEPT for O and H
- ) Balance for O by adding H2O
- ) Balance for H by adding H+
- ) Balance charge using e-