6. Microstructure Flashcards

1
Q

What is optical microscopy?

A

Looking at metals through a microscrope.

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2
Q

How do you reveal the microstructure?

A

THREE STEPS:
1) Polish material to mirror finish (i.e. remove macroscopic defects)

2) Use an etching agent that preferentially attacks defects or different phases
3) Let light scatter differently on different planes to reveal different arrangements.

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3
Q

Why does the etchant preferentially attack defects?

A

Defects are where the bond strength between atoms is weakest.

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4
Q

What does the etchant tend to attack preferentially?

A

Attacks different phases, different planes (which is rare) and grain boundaries.

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5
Q

Why is etching an art?

A

It’s really trial and error. There’s no science to it.

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6
Q

Can optical microscopy catch point and line defects?

A

Nope. Too small. Easier to do through electron microscopy.

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7
Q

MICROSTRUCTURE DESCRIPTIONS

A

Yay!

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8
Q

How can you describe the number of phases?

A

Color, size, shape, location

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9
Q

What are the ways you can describe a phase?

A

Color, size, distribution, shape, Volume fraction

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10
Q

What is the matrix phase?

A

The matrix which is either

1) the continuous phase (not broken up into globules)
2) the largest in volume

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11
Q

How can you quantify grain size?

A

The Heyn lineal intercept method! Length of line divided by number of intercepts.

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12
Q

What are the five possible types of grains you can see?

A
Cylindrical
Equiaxed
Lenticular
Lamellar
needle
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13
Q

What are the differences between the 3D and 2D versions of these shapes?

A

Cylinders can look like ellipses of different shape

Equiaxed looks like octagons.

lanellar will look like parallelograms or rectangles

Lenticular will look like ellipses

Needle

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14
Q

What do dendritic structures look like?

A

They can look really weird. Often circles

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15
Q

LEC 3-26

A

Yay!

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16
Q

What resolution does optical microscopy give you?

And electron microscopy?

A

Micrometer scale

Nanometer! Electon wavelegnth = 0.008nm when operated at 20kV

17
Q

Electron diffraction giiives…?

A

Crystallography!

18
Q

What are the advantages and disadvantages of SEM?

A

ADV:

  • nanometer resolution
  • Reveals crystallographic structure
  • doesn’t require etching
  • Can reveal point defects

DISADV:

  • expensive
  • takes hours
19
Q

What are characteristic X-rays?

A

X-rays emitted when an electron drops from a higher orbit to a lower orbit.

These orbit drops happen during SEM, when an electron is ejected by the electron bombardment

20
Q

What are composition maps?

A

Maps generated from scanning electron microscopes - they reveal the composition of a material

21
Q

What sort of information can you acquire from composition maps?

A

Location of material (i.e. if they’re along grain boundaries)

Matrix phases vs continuous phases

If a material is in solid solution

22
Q

How does TEM work?

A

You prepare a nanometer thick specimen, beam electrons at it, and look at the electrons transmitted.

23
Q

What are the possible magnification scales of TEM?

A

20-100k typically

but 500-1000k possibly

24
Q

Which electrons reveal crystallography and defects?

A

The forward scattered electrons

25
Q

What are the benefits and drawbacks to a million volt TEM?

A

PROS:
- Increased resolution and penetration

CONS

  • High capital expenditure
  • High operation costs
  • High operating difficulties
26
Q

What is dislocation density and the two ways to calculate it?

A

1) The total length per unit volume of dislocations

2) The number of dislocation intercepts for a given cross-section

27
Q

What is 3D atom probe tomography?

A

An atom imaging method where you look at time of flight. Good way for finding precipitates.