Week 4 - energy and metabolism Flashcards

1
Q

Kinetic energy

A

Energy of motion/ movement associated w/ movement of organisms cells or organelles

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2
Q

potential energy

A

energy, stored, available to do work due to structure or location.

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3
Q

chemical energy

A

type of potential energy → available for release in a chemical reaction

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4
Q

chemical bonds

A
  • molecules like glucose and triglyceride → store energy in their bonds
  • to release the energy, the cell breaks the bonds
  • if the cell cannot capture the energy being released, it wil be lost as heat
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5
Q

heat/ thermal energy

A

type of kinetic enrgy - associated w/ random movement of atoms or molecules

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6
Q

First law of thermodynamics

A
  • law of conservation of energy,
  • energy cannot be created or destroyed
  • can be transformed from one type to another
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7
Q

Second law - thermodynamics

A

transfer or transformation of energy from one form to another. inc entropy or degree of disorder of a system

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8
Q

chemical reactions - endogenic

A
  • requires an input of energy
  • the chief currency of all cells use their energy transactions in adenosine triphosphate (ATP_
  • cells store and release energy in bonds of ATP
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9
Q

Endergonic

A

reactions that form bonds to build molecules require energy input

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10
Q

Exergonic

A
  • reactions that break bonds to release energy stored in bonds
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11
Q

chemical reactions - spontaneous

A

SPONTANEOUS CHEMICAL REACTIONS REQUIRE ACTIVATION ENERGY TO BE OVER COME OR REDUCED

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12
Q

activation energy

A
  • INITIAL INPUT OF ENERGY TO START REACTION
  • allows molecules to get close enough to case bod rearrangement → can not achieve state where bonds are stretch

2 ways to overcome: LARGE AMOUNTS OF HEAT or using ENZYMES to lower activation energy

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13
Q

enzyme

A

protein that acts as a catalyst → speeds up a chemical

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14
Q

substrate

A
  • molecules that bind to the enzymes active siite , where chemical reaction occurs.
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15
Q

enzyme-substrate eg.

A
  1. substrate, sucrose, consists of glucose & fructose bond together
  2. substrate binds to the active site of the enzyme, forming an enzyme substrate complex
  3. the binding of the substrate & enzyme places stress on the glucose- fructose bond & bond breaks
  4. products are released & enzyme is free to bind w/ other substrates
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16
Q

energy - cellular level

A
  • subtances are modified, small molecules are combined to generate larger macromolecules & vise versa
  • CELLULAR RESPIRATION extracts energy stored in fuel molecule → cells use this to perform various works
17
Q

chemical reactions - metabolism

A
  • building complex molecules out of simple parts (monomers) forms new chemical bonds
  • break complex molecules into simple parts break apart like chemical bonds → energy out
18
Q

ATP cycles

A
  • ATP is a renewable resource that is regenerated by addition of a phosphategroup to adenosine diphosphate ADP
  • the energy to phosphorylate ADP comes form catabolic reactions in the cell.
  • the chemical potential energy ‘ temporarily’ stored in ATP drives cellular work
19
Q

ATP and coupling

A
  • cells manage energy resources by ENERGY COUPING the use of an exergonic process to drive an endergonic one
  • most energy couping in cells is mediated by ATP
20
Q

competitivity

A

competitive: blocks access point to active site

non-competetive: changes shape of active site

21
Q

enzymes - optimum temperature

A

CHANGES RATE OF MOLECULAR MOTION

  • inc temp inc. molecular motion → inc. rate of catalyst
  • OPTIMUM TEMP: temp at which the enzyme has the highest rate of catalysis
  • dec temp. decreases molecular movement →decreases rate of catalysis
22
Q

enzymes - temperature

A

CAUSES CHANGE IN SHAPE OF ENZYME

  • changes above optimum temp will affect enzyme structure
  • can no longer bind to sunstrate and catalyse a reaction
  • if temp increases and is too high, will cause enzyme to denature
23
Q

enzymes - pH

A

in basic enviro: acidic side chains could donate protons
in acidic enviro: basic side chains could accept protons

both events will change shape of enzyme → making it less able to bind w/ substrate, less able to catalyse reaction

24
Q

free energy (delta G + metabolism

A
  • Free energy: energy that can be used to do work when chemical bonds are bropken
  • chemical reactions break some bonds in the reactant and form new ones in products
  • in some reactions the products contain less free energy than reactants & release excess energy
25
Q

Free energy - reactions

A
G = H-TS
g: gibbs free energy (thermodynamic function used )to describe ability of a system to undergo change
H: enthalpy
T: temp
S: entropy

a reaction can only occur spontaneously if the change in G for a given reaction is negative