Displacement Reactions Flashcards

1
Q

what is a displacement reaction

A

a reaction in which one element replaces another element in a compound

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2
Q

what are displacement reactions called in organic chemistry

A

substitution reactions

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3
Q

what would a reaction between Mg(s) and CuSO4(aq) produce

A

Cu(s) + MgSO4(aq)

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4
Q

what would a reaction between 2Al(s) and Fe2O3(s) produce

A

2Fe(s) + Al2O3(s)

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5
Q

what are the two things both of of those reactions have in common in terms of the reactants and products

A
  • they both have a metal reacting with a compound of a different metal
  • they produce a metal and a different metal compound
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6
Q

what two things do the reactions have in common in terms of the type of reaction

A
  • they are displacement reactions
  • as a more reactive metal on the reactants side has taken the place of a less reactive metal in a compound
  • and they are redox reactions
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7
Q

what is the difference between the two reactions in term of their states

A
  • the first reaction involves the interaction of a solid and compound in an aqueous state (in an aqueous solution)
  • whereas the all the reactants and products in the second one are solids
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8
Q

what do these reactions taking place in different states imply about the differences in the energy required in order for a reaction to occur in the first place

A
  • the first reaction takes place without any energy needing to be inputted
  • whereas the second one requires a lot of energy to be supplied for a high temperature
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9
Q

where are these two reactions likely to take place

A
  • the first one is likely done in a lab

- whereas the second one is likely done for a specific purpose in industry

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10
Q

what colour changes would occur if you added magnesium to copper sulfate solution

A
  • the blue colour of the solution becomes paler
  • if an excess of Mg is added the solution would become completely colourless
  • the solid Mg changes colour from silvery to brown
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11
Q

why does the blue colour of the solution become paler as you add Mg

A
  • the Mg is displacing the Cu from the CuSO4 solution
  • leading to its concentration decreasing
  • and therefore the strength of its colour in the solution decreasing or fading
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12
Q

why does the solution become colourless if an excess of Mg is added

A
  • excess means all the Mg that can react with sulfate ions has reacted
  • meaning that all the Cu from CuSO4 has been displaced
  • this leads to the solution losing all its blue colour as no CuSO4 is present
  • making it colourless (as MgSO4 is colourless)
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13
Q

why does the solid Mg change its appearance from silvery to brown

A
  • the solid copper forming forms a layer on the surface of the solid Mg
  • causing the Mg (visible to the eye) to go brown
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14
Q

what is the ionic equation and net ionic equation for the reaction between magnesium and copper sulfate

A
  • Mg(s) + Cu(2+)(aq) + SO4(2-)(aq) = Cu(s) + Mg(2+)(aq) + SO4(2-)(aq)
  • Mg(s) + Cu(2+)(aq) = Cu(s) + Mg(2+)(aq)
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15
Q

why does this net ionic equation show that this is a redox reaction

A
  • the Mg atoms give two electrons to the Cu2+ ions
  • meaning the Mg atoms are oxidised as they lose electrons (OIL)
  • and the Cu2+ ions are reduced as they gain electrons (RIG)
  • oxidation + reduction = redox
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16
Q

what is the reaction between aluminium and iron(III) oxide used for practically

A

joining reals together by railway industries

17
Q

why isnt it effective to join rails together by welding them

A
  • the metals are good conductors of heat

- so its very hard to get the two ends of the rail hot enough for them to melt and join together

18
Q

what is the thermite method that is used instead

A
  • a mixture of aluminium and iron oxide is is put above the place where the two rails are to be joined
  • a Mg fuse is lit causing the Al + Fe3O3 reaction to occur
19
Q

what happens after the Mg fuse is lit

A
  • the reaction is so exothermic that the iron if formed as a molten metal
  • which is then poured in the gap between the two rails
  • after cooling the rails r joined together
20
Q

what is the ionic equation and net ionic equation for the reaction between Al and Fe3O3

A
  • Al(l) + 2Fe(3+)(l) + 3O(2-)(l) = 2Fe(l) + 2Al(3+)(l) + 3O(2-)(l)
  • 2Al(l) + 2Fe(3+)(l) = 2Fe(l) + 2Al(3+)(l)