U2 S3- Period 3 Elements Flashcards

1
Q

sodium reaction with cold water

A

2Na + 2H2O —> 2NaOH + H2

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2
Q

Sodium reaction with cold water observation

A
1-Vigorously 
2-molten ball on surface
3-effervescence 
4-H2 gas
5-NaOH (strong alkaline solution)
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3
Q

Magnesium reaction with cold water

A

Mg + 2H2O –> MgO + H2

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4
Q

Magnesium reaction with cold water observation

A

1- reacts very slowly

2-Mg(OH)2 (weak alkaline))

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5
Q

why is the solution of Mg(OH)2 weakly alkaline

A
  • Mg(OH)2 is not very soluble in water

- so few OH- ions produced

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6
Q

Magnesium reacts faster with

A

1-steam

2-more kinetic energy to form MgO

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7
Q

Magnesium reaction with steam

A

Mg + H2O –> MgO + H2

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8
Q

Period 3 reactions with air and rate

A
2Na + 1/2O2 --> Na2O  VIGOUROUS
Mg + 1/2O2 --> MgO  VIGOROUS
2Al + 1 1/2O2 --> Al2O3 SLOW
Si + O2 --> SiO2 SLOW
P4 + SO2 --> P4O10 SPONTANEOUSLY COMBUSTS
S + O2 --> SO2  BURNS STEADILY
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9
Q

Na and O2 colour flame

A

2Na + 1/2O2 –> Na2O YELLOW + WHITE PTT

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10
Q

Mg and O2 colour flame

A

Mg + 1/2O2 –> MgO BRILLIANT WHITE + WHITE PTT

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11
Q

Al and O2 colour flame

A

2Al + 1 1/2O2 –> Al2O3 N/A + WHITE PTT

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12
Q

Si and O2 colour flame

A

Si + O2 –> SiO2 N/A + WHITE PTT

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13
Q

P and o2 colour flame

A

P4 + SO2 –> P4O10 BRILLIANT WHITE + WHITE PTT

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14
Q

s and O2 colour flame

A

S + O2 –> SO2 BLUE + COLOURLESS GAS (SO2)

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15
Q

Catalyst with SO2 + 1/2O2 –> SO3

A

-vanadium (V2O5)

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16
Q

amphoteric

A

has properties of acid and base

17
Q

Melting points of Na2O, MgO, Al2O3

A

1- Giant ionic lattices

2-strong forces of electrostatic attraction between positive ions and e-

18
Q

Why is the melting point of MgO higher than Na2O

A

1- Mg2+ attract O2- more strong electrostatic attraction
than the 2 na+ attracted to O2-
2-more energy required to break ionic bonds

19
Q

why is Al2O3 melting point lower than expected

A

1- Al3+ ions distort the oxygen’s electron cloud making it partially ionic and partially covalent

20
Q

SiO2 melting point

A

1-Macromolecular/Giant covalent
2-Strong covalent bonds
3-lots of E required to break
4-High MP

21
Q

melting points of P4O10 and SO3

A

1-simple molecular/compounds
2-molecules attracted by weak IMF VDWS and induced dipole-dipole
3-Low MP

22
Q

Reactions of Na2O and MgO with water

A

Na2O + H2O –> 2NaOH

MgO + H2O –> Mg(OH)2

23
Q

why is NaOH strongly alkaline and Mg(OH)2 weakly alkaline

A
NaOH= more soluble in water Na+ and OH- easier to dissociate into almost completely
Mg(OH)= less soluble in water Mg2+ and OH- harder to dissociate into  slightly
24
Q

SiO2 reactions with water

A

1-SiO2 macromolecular / giant covalent

2-insoluble in water

25
Q

Al2O3 reactions with water

A

1-partially ionic and partially covalent due to Al3+ ions distorting the electron charge cloud
2-insoluble in water

26
Q

P4O10, SO3, SO2 reactions with water

A

P4O10 + 6H2O –> 4H3PO4
SO2 + H2O –> H2SO3
SO3 + H2O –>H2SO4

27
Q

dissociation of H3PO4, H2SO3, H2SO4

A

H3PO4 –> 3H+ + PO43-
H2SO3 –> 2H+ + SO32-
H2SO4 –> 2H+ + SO42-

28
Q

Neutralisation reaction

A

ACID + BASE –> SALT + WATER

29
Q

Na2O and MgO reactions with acid and bases

A

-Na2O + MgO are basic so neutralise acids

30
Q

Al2O3 reactions with acid and bases

A

amphoteric neutralises both acids or bases

31
Q

P4H10, SO3, SO2 with acids and bases

A

acidic so neutralise bases